Clean aluminum alloys and methods for forming such alloys
A method comprises providing a molten aluminum alloy selected from the group consisting of 6000 series aluminum alloys comprises chromium (Cr) in a range of between 0.001 wt % to 0.05 wt %. The molten aluminum alloy is formed into a formed body having beta-AlFeSi particles. The formed body is solution heat treated at a temperature in a range of 1,025-1,050° F. to form a heat-treated body. The solution heat treating transforms substantially all of the beta-AlFeSi particles into alpha-AlFeSi particles such that the heat-treated body is substantially free of the beta-AlFeSi particles.
1. A method, comprising:
providing a molten aluminum alloy selected from the group consisting of 6000 series aluminum alloys comprising chromium (Cr) in a range of 0.001 wt % to 0.05 wt %;
forming the molten aluminum alloy into a formed body having beta-AlFeSi particles;
solution heat treating the formed body at a temperature in a range of 1,025-1,050° F. to form a heat-treated body, the solution heat treating transforming substantially all of the beta-AlFeSi particles into alpha-AlFeSi particles such that the heat-treated body is substantially free of the beta-AlFeSi particles;
heat aging the heat-treated body to form an aged body; and
anodizing the aged body in a mixed acid bath,
wherein the cast aluminum alloy article has a breakdown voltage of greater than 1,380 V/mil.
2. The method of claim 1 , wherein forming the molten aluminum alloy comprises centrifugally or semi-centrifugally forming the molten aluminum alloy in a mold such that the formed body is a cast body.
3. The method of claim 2 , wherein the centrifugally forming comprises rotating the mold containing molten aluminum alloy at a speed of at least about 500 rpm, and wherein the semi-centrifugally forming comprises rotating the mold containing molten aluminum alloy at a speed of less than 500 rpm.
4. The method of claim 2 , wherein the centrifugally forming comprises rotating the mold containing molten aluminum alloy at a centrifugal acceleration of at least about 30 G, and wherein the semi-centrifugally forming comprises rotating the mold containing molten aluminum alloy at a centrifugal acceleration of less than 30 G.
5. The method of claim 1 , further comprising:
hot isostatically pressing (HIP) the formed body prior to solution heat treating the formed body.
6. The method of claim 5 , wherein the hot isostatically pressing (HIP) comprises heating the formed body at a temperature in a range of 900 to 1,025° F. while applying an isostatic pressure in a range of 10 to 14 KSI.
7. The method of claim 1 , wherein the solution heat treating process comprises heating the formed body for at least about 2 hours.
8. The method of claim 1 , further comprising quenching the heat-treated body in water at a temperature of less than 100° F.
9. The method of claim 1 , wherein the heat aging step is performed at a temperature of about 300 to 400° F. for about 2 to 20 hours.
10. The method of claim 1 , wherein the providing the molten aluminum alloy comprises melting the aluminum alloy in one of an induction furnace or a gas fired furnace.
11. The method of claim 1 , wherein the aluminum alloy comprises a 6061 aluminum alloy.
12. The method of claim 1 , wherein the molten aluminum alloy comprises about 0.02-0.04 wt % Fe, 0.5-0.6 wt % Si, 0.16-0.19 wt % Cu, 1.0-1.1 wt % Mg and at least 98 wt % Al.
13. The method of claim 1 , wherein solution heat treating the formed body causes the formed body to have a T6 temper.
14. The method of claim 1 , wherein the molten aluminum alloy is a Al—Mg—Si—Cu—Cr type aluminum alloy including less than 0.04 wt % Fe and at least about 98 wt % Al.
15. The method of claim 1 , wherein the molten aluminum alloy comprises less than 0.7 wt % Fe and 0.10-0.15 wt % Sr.
16. The method of claim 1 , wherein the cast aluminum alloy article has an admittance of less than 6 μMhos.
17. The method of claim 1 , wherein the cast aluminum alloy article has a corrosion resistance of equal to or greater than 10.0 hours in 5 wt % HCl.