Dissolvable compositions and tools including particles having a reactive shell and a non-reactive core
A core-shell particle is provided, including a core particle composed of a non-reactive component, and a coating layer disposed about the core particle, the coating layer composed of reactive component. The reactive component is chemically reactive with water, acid, or base, and the non-reactive component is non-reactive with water, acid, or base. Also provided are a bulk composition composed of the core-shell particle, an article composed of the bulk composition, as well as method and system of making and using the particles, composition, and articles.
1. A bulk composition having a multiphase morphology, the bulk composition comprising:
a dissolvable continuous phase of a matrix material comprising a reactive component that is chemically reactive with neutral water, acidic water, or basic water via a chemical displacement reaction; and
a non-dissolvable discontinuous phase including a plurality of particles of a non-reactive component that are chemically unreactive with neutral water, acidic water, or basic water via a chemical displacement reaction;
wherein the plurality of particles are distributed within the matrix material;
wherein the reactive component and the non-reactive component are not galvanically reactive with each other;
wherein the matrix material is from 1 to 25 wt. % of the bulk composition, based on a total weight of the bulk composition; and
wherein the reactive component comprises graphite, K, Na, V, Li, W, Mo, Al 4 C 3 , AlP, Ba, BaH 2 , BaSe, BaSi 2 , BP, CaC 3 , CaH 2 , Ca 2 P 2 , CaSi 2 , CaC 2 , Mg 2 Si, SiS, or ZrCl 3 .
2. The bulk composition of claim 1 , wherein the reactive component reacts with water via a displacement reaction.
3. The bulk composition of claim 1 , wherein the reactive component is graphite.
4. The bulk composition of claim 1 , wherein the reactive component is a metal that comprises K, Na, V, Li, W, or Mo.
5. The bulk composition of claim 1 , wherein the non-reactive component is a ceramic, oxide, nitride, or polymer.
6. The bulk composition of claim 1 , wherein the non-reactive component is a microballoon.
7. The bulk composition of claim 1 , wherein the non-reactive component is a Titanium or an alloy thereof; Tantalum or an alloy thereof; or iron or an alloy thereof.
8. The bulk composition of claim 1 , wherein the non-reactive component is a Nickel-Chromium alloy.
9. The bulk composition of claim 1 , wherein the reactive component comprises Al 4 C 3 , AlP, Ba, BaH 2 , BaSe, BaSi 2 , BP, CaC 3 , CaH 2 , Ca 2 P 2 , CaSi 2 , CaC 2 , Mg 2 Si, SiS, or ZrCl 3 .
10. The bulk composition of claim 1 , wherein the bulk composition comprises from 1 to 25 wt. % of the reactive component, based on the total weight of the bulk composition, and wherein the bulk composition comprises from 75 to 99 wt. % of the non-reactive component based on the total weight of the bulk composition.
11. An article of manufacture comprising:
a bulk composition having a multiphase morphology, the bulk composition including a continuous phase of a matrix material comprising a reactive component that is chemically reactive with neutral water, acidic water, or basic water via a chemical displacement reaction; and a discontinuous phase including a plurality of particles of a non-reactive component that are chemically unreactive with neutral water, acidic water, or basic water via a chemical displacement reaction; wherein the plurality of particles are distributed within the matrix material; wherein the reactive component and the non-reactive component are not galvanically reactive with each other, wherein the matrix material is from 1 to 25 wt. % of the bulk composition, based on a total weight of the bulk composition, and wherein the reactive component comprises graphite, K, Na, V, Li, W, Mo, Al 4 C 3 , AlP, Ba, BaH 2 , BaSe, BaSi 2 , BP, CaC 3 , CaH 2 , Ca 2 P 2 , CaSi 2 , CaC 2 , Mg 2 Si, SiS, or ZrCl 3 .
12. The bulk composition of claim 1 , wherein the reactive component is not galvanically reactive with water, acid, or base.
13. The bulk composition of claim 1 , wherein the non-reactive component comprises Mg.
14. The article of manufacture of claim 11 , wherein the article is a downhole tool or component.
15. The article of manufacture of claim 11 , wherein a first portion of the article includes the bulk composition, and wherein a second portion of the article includes a second bulk composition, wherein the second bulk composition is different than the bulk composition, the second bulk composition having a multiphase morphology, the second bulk composition comprising a continuous phase of a matrix material comprising a reactive component; and a discontinuous phase including a plurality of particles of a non-reactive component; wherein the plurality of particles are distributed within the matrix material; and wherein the reactive component is chemically reactive with neutral water, acidic water, or basic water via a chemical displacement reaction, and the non-reactive component is chemically unreactive with neutral water, acidic water, or basic water via a chemical displacement reaction.
16. The article of manufacture of claim 11 , further comprising a substrate layer positioned between a build plate and an additively manufactured article, the substrate layer including at least one layer of the bulk composition.
17. The bulk composition of claim 1 , wherein the reactive component reacts with a base via a displacement reaction.
18. The bulk composition of claim 1 , wherein the reactive component reacts with an acid via a displacement reaction.
19. The article of manufacture of claim 11 , wherein the article is a terrestrial or aerial vehicle, an electronic component, a bullet, a billet, or a medical component.