Rubber composition for tires and pneumatic tire
Provided are a rubber composition for tires that provides a balanced improvement of snow and ice performance and abrasion resistance, and a tire including the rubber composition. The rubber composition for tires contains: a rubber component including an isoprene-based rubber and BR; silica; and a terpene-based resin having a softening point of 60-150° C., an α-pinene unit content of 65-100% by mass, a β-pinene unit content of 0-35% by mass, and a limonene unit content of 10% by mass or lower, the rubber component including, based on 100% by mass thereof, 5-80% by mass of the isoprene-based rubber and 5-80% by mass of the BR, with a combined amount of the isoprene-based rubber and the BR of 60% by mass or more, the rubber composition containing, per 100 parts by mass of the rubber component, 1-500 parts by mass of the silica and 0.1-100 parts by mass of the terpene-based resin.
1. A pneumatic tire, comprising a tread,
the tread comprising a rubber composition for tires comprising:
a rubber component comprising an isoprene-based rubber and polybutadiene rubber;
silica; and
a terpene-based resin having a softening point of 60 to 150° C., an α-pinene unit content of 65 to 100% by mass, a β-pinene unit content of 0 to 35% by mass, and a limonene unit content of 10% by mass or lower,
the rubber component comprising, based on 100% by mass thereof, 5 to 80% by mass of the isoprene-based rubber and 5 to 80% by mass of the polybutadiene rubber, with a combined amount of the isoprene-based rubber and the polybutadiene rubber of 60% by mass or more,
the rubber composition comprising, per 100 parts by mass of the rubber component, 1 to 500 parts by mass of the silica and 0.1 to 100 parts by mass of the terpene-based resin, and
wherein the rubber composition has an E* at 0° C. of 3.0 to 8.0, a difference between E* at −10° C. and E* at 10° C. of 10.0 or less, and a tan δ at 0° C. of 0.14 to 0.26.
2. The pneumatic tire according to claim 1 ,
wherein the terpene-based resin is at least one selected from the group consisting of α-pinene homopolymers, terpene-based resins having an α-pinene unit content of 99% by mass or higher, and copolymers containing an α-pinene unit and a β-pinene unit.
3. The pneumatic tire according to claim 1 ,
wherein the terpene-based resin has a number average molecular weight of 500 to 775 and a z-average molecular weight of 1300 to 1600.
4. The pneumatic tire according to claim 1 ,
wherein the rubber composition comprises 30 to 80 parts by mass of the silica per 100 parts by mass of the rubber component.
5. The pneumatic tire according to claim 1 ,
wherein the silica has a nitrogen adsorption specific surface area of 160 m2/g or more.
6. The pneumatic tire according to claim 1 ,
wherein the silica has a nitrogen adsorption specific surface area of 190 m2/g or more.
7. The pneumatic tire according to claim 1 ,
wherein the rubber composition comprises 0.1 to 50 parts by mass of carbon black per 100 parts by mass of the rubber component.
8. The pneumatic tire according to claim 1 ,
wherein the polybutadiene rubber has a cis content of 90% by mass or higher.
9. The pneumatic tire according to claim 1 ,
wherein the rubber composition comprises 0.1 to 100 parts by mass of a polar plasticizer per 100 parts by mass of the rubber component.
10. The pneumatic tire according to claim 9 ,
wherein the polar plasticizer has a glass transition temperature of −80° C. or lower.
11. The pneumatic tire according to claim 1 ,
wherein the pneumatic tire is a studless winter tire.