Adhesive for flexible optical film
An adhesive for a flexible optical film, especially an acrylate pressure-sensitive adhesive for a flexible display device is disclosed. The shear storage modulus (G′ (60° C./0.1 Hz) ) at the temperature of 60° C. and the frequency of 0.1 Hz and the shear storage modulus (G′ (30° C./1 Hz) ) at the temperature of 30° C. and the frequency of 1 Hz of the present acrylate pressure-sensitive adhesive satisfy the relation: (G′ (60° C./0.1 Hz) −G′ (30° C./1 Hz) )/G′ (30° C./1 Hz) >−0.29, and the loss tangent (tan δ (60° C./0.1 Hz) ) at the temperature of 60° C. and the frequency of 0.1 Hz and the loss tangent (tan δ (30° C./1 Hz) ) at the temperature of 30° C. and the frequency of 1 Hz of the present acrylate pressure-sensitive adhesive satisfy the relation: (tan δ (60° C./0.1 Hz) −tan δ (30° C./1 Hz) )/tan δ (30° C./1 Hz) <0.2.
1. An adhesive for a flexible optical film, comprising at least a (meth)acrylate polymer, a hardener, and a silane coupling agent, which is characterized in that:
(A) a shear storage modulus (G′ (60° C./0.1 Hz) ) measured at the temperature of 60° C. and the frequency of 0.1 Hz and a shear storage modulus (G′ (30° C./1 Hz) ) measured at the temperature of 30° C. and the frequency of 1 Hz satisfy the relation: (G′ (60° C./0.1 Hz) −G′ (30° C./1 Hz) )/G′ (30° C./1 Hz) >−0.29; and
(B) a loss tangent (tan δ (60° C./0.1 Hz) ) measured at the temperature of 60° C. and the frequency of 0.1 Hz and a loss tangent (tan δ (30° C./1 Hz) ) measured at the temperature of 30° C. and the frequency of 1 Hz satisfy the relation:
(tan δ (60° C./0.1 Hz) −tan δ (30° C./1 Hz) )/tan δ (30° C./1 Hz) <0.2.
2. The adhesive according to claim 1 , wherein the shear storage modulus (G′ (60° C./0.1 Hz) ) measured at the temperature of 60° C. and the frequency of 0.1 Hz is ranging from 0.05 MPa to and 0.09 MPa, and the shear storage modulus (G′ (30° C./1 Hz) ) measured at the temperature of 30° C. and the frequency of 1 Hz is ranging from 0.07 MPa to 0.15 MPa.
3. The adhesive according to claim 1 , wherein the loss tangent (tan δ (60° C./0.1 Hz) ) measured at the temperature of 60° C. and the frequency of 0.1 Hz is ranging from 0.08 to 0.15, and the loss tangent (tan δ (30° C./1 Hz) ) measured at the temperature of 30° C. and the frequency of 1 Hz is ranging from 0.09 to 0.12.
4. The adhesive according to claim 1 , wherein the (meth)acrylate polymer includes an alkyl (meth)acrylate, an aromatic (meth)acrylate, and a hydroxyl monomer.
5. The adhesive according to claim 4 , wherein the number average molecular weight (Mn) of the (meth)acrylate polymer is ranging between 1,500,000 and 2,500,000, and the glass transition temperature (Tg) is ranging between −30° C. and −35° C.
6. The adhesive according to claim 1 , further comprising an addition agent selected from one of the group consisting of an antistatic agent, an UV absorbent, a low molecular weight polymer, a plasticizer, a filler, a colorant and a pigment, or combinations thereof.