Vehicular components having chromium-based reflective coating at least partially permeable to light
A vehicular component includes at least one light source disposed at least partially within an interior of the vehicular component and configured to emit light based on at least receiving electrical power from an electrical power source. The vehicular component further includes a transparent polymeric portion substantially enclosing the interior and the at least one light source. The transparent polymeric portion has an inner surface, an outer surface disposed opposite the inner surface and a chromium-based reflective coating coated on the outer surface. With the at least one light source receiving electrical power from the electrical power source, the chromium-based reflective coating is at least partially permeable to at least some light which is emitted by the at least one light source and passed through the transparent polymeric portion. At least one area of the outer surface of the transparent polymeric portion is devoid of the chromium-based reflective coating.
1. A vehicular component, comprising:
at least one light source disposed at least partially within an interior of the vehicular component, wherein the at least one light source is configured to emit light based on at least receiving electrical power from an electrical power source; and
a transparent polymeric portion substantially enclosing the interior and the at least one light source, the transparent polymeric portion having an inner surface, an outer surface disposed opposite the inner surface and a chromium-based reflective coating coated on the outer surface, wherein with the at least one light source receiving
electrical power from the electrical power source, the chromium-based reflective coating is at least partially permeable to at least some light which is emitted by the at least one light source and passed through the transparent polymeric portion, and wherein at least one area of the outer surface of the transparent polymeric portion is devoid of the chromium-based reflective coating.
2. The vehicular component according to claim 1 , wherein the at least one area of the outer surface of the transparent polymeric portion which is devoid of the chromium- based reflective coating comprises at least one etching, and wherein the at least one etching exposes the outer surface of the transparent polymeric portion within at least one etched gap defined by the at least one etching.
3. The vehicular component according to claim 1 , wherein the at least one light source, while unlit and emitting no light, is concealed behind the chromium-based reflective coating coated on the outer surface of the transparent polymeric portion.
4. The vehicular component according to claim 1 , wherein the at least one light source comprises a plurality of light sources, wherein a first number of the plurality of light sources, while unlit and emitting no light, is concealed behind the chromium-based reflective coating coated on the outer surface of the transparent polymeric portion, and wherein a second number of the plurality of light sources, whether lit and emitting light or unlit and emitting no light, is visible through the transparent polymeric portion by way of the at least one area of the outer surface of the transparent polymeric portion which is devoid of the chromium-based reflective coating.
5. The vehicular component according to claim 1 , wherein the at least one light source comprises at least one of an incandescent light source, a light-emitting diode (LED) light source, or a combination of incandescent and light-emitting diode (LED) light sources.
6. The vehicular component according to claim 1 , wherein the vehicular component is configured to be mounted to a vehicle, and wherein with the vehicular component mounted to the vehicle, the chromium-based reflective coating coated on the outer surface of the transparent polymeric portion is positioned to aesthetically correspond to, and appear substantially merged with, a metallic reflective coating coated on at least a portion of another vehicular component mounted to the vehicle immediately adjacent to the vehicular component.
7. The vehicular component according to claim 6 , wherein the other vehicular component mounted to the vehicle immediately adjacent to the vehicular component is selected from the group consisting of a trim piece, a vehicle exterior component, a front grill, a front bumper, a rear bumper, a headlamp bezel and a tail lamp bezel.
8. The vehicular component according to claim 1 , wherein the vehicular component is selected from the group consisting of a lighting module, a vehicle exterior component, a trim piece, a front bumper, a rear bumper, a lamp assembly, a headlamp assembly and a tail lamp assembly.
9. The vehicular component according to claim 1 , wherein the transparent polymeric portion is formed from a material selected from the group consisting of polyacrylate, polyester, polystyrene, polyethylene, polypropylene, polyamides, polyimides, polycarbonate, epoxy, phenolic, acrylonitrile-butadiene-styrene, acrylonitrile-styrene-acrylates, acetal and blends thereof.
10. The vehicular component according to claim 1 , wherein the transparent polymeric portion is formed from a material selected from the group consisting of polycarbonate, poly(2,2′-dihydroxyphenylpropane) carbonate, poly diethylene glycol bis(allyl carbonate), polymethyl methacrylate, polystyrene and blends thereof.
11. The vehicular component according to claim 1 , wherein the transparent polymeric portion includes a pre-coated film in the form of a hardcoat, a silicon hardcoat, an inorganic oxide, a thin metal film, or a combination of these pre-coated films.
12. The vehicular component according to claim 1 , wherein the chromium-based reflective coating is an alloy of chromium and a dopant material, the dopant material being selected from a group of hexagonally close-packed transition metals, the alloy having a crystal structure of a primary body-centered cubic phase in coexistence with a secondary omega hexagonally close-packed phase.
13. The vehicular component according to claim 12 , wherein the alloy is a binary alloy of the chromium and the dopant material.
14. The vehicular component according to claim 13 , wherein an atomic percentage of the dopant material in the binary alloy ranges from about 1.9 at. % to about 5.8 at. %.
15. The vehicular component according to claim 12 , wherein the group of hexagonally close-packed transition metals includes at least one of zirconium, titanium, cobalt, hafnium, rubidium, yttrium and osmium.
16. The vehicular component according to claim 12 , wherein the alloy is a binary alloy and the dopant material is zirconium, and wherein an atomic percentage of the zirconium in the binary alloy ranges from about 4.5 at. % to about 5.8 at. %.
17. The vehicular component according to claim 12 , wherein the alloy is a binary alloy and the dopant material is titanium, and wherein an atomic percentage of the titanium in the binary alloy ranges from about 1.9 at. % to about 5.8 at. %.
18. The vehicular component according to claim 12 , wherein the alloy is a binary alloy and the dopant material is cobalt, and wherein an atomic percentage of the cobalt in the binary alloy ranges from about 1.9 at.% to 5.7 at.%.
19. The vehicular component according to claim 1 , wherein the chromium-based reflective coating has a thickness of 200 nm or less.
20. The vehicular component according to claim 1 , wherein the chromium-based reflective coating has a thickness of 200 nm, 100 nm, from 40 nm to 80 nm, from 50 nm to 70 nm, or about 60 nm.