Surface modified nanoparticles
Surface-modified nanoparticles are produced by associating ligand interactive agents with the surface of a nanoparticle. The ligand interactive agents are bound to surface modifying ligands that are tailored to impart particular solubility and/or compatibility properties. The ligand interactive agents are crosslinked via a linking/crosslinking agent, such as hexamethoxymethylmelamine or a derivative thereof. The linking/crosslinking agent may provide a binding site for binding the surface modifying ligands to the ligand interactive agents.
1. A composition of matter, the composition comprising:
a host material; and
a population of surface-modified nanoparticles dispersed in the host material, the surface-modified nanoparticles comprising:
a ligand interactive agent-nanoparticle association complex;
a linking/crosslinking agent bound to a ligand interactive agent of the ligand interactive agent-nanoparticle association complex; and
a surface modifying ligand bound to the linking/crosslinking agent,
wherein the surface modifying ligand is configured to render the surface-modified nanoparticles compatible with the host material.
2. The composition of claim 1 , wherein the host material is a solvent.
3. The composition of claim 2 , wherein the solvent is a polar solvent selected from the group consisting of water, ethanol, propanol, butanol, acetone, methylethylketone, tripropylmethylmethacrylate, and methylmethacrylate.
4. The composition of claim 2 , wherein the solvent is water.
5. The composition of claim 4 , wherein the surface modifying ligand is a monomethoxy polyethylene oxide.
6. The composition of claim 1 , wherein the host material is a polymer or resin.
7. The composition of claim 6 , wherein the host material is a polydimethylsiloxane polymer.
8. The composition of claim 7 , wherein the surface modifying ligand is a monohydroxy polydimethylsiloxane.
9. The composition of claim 6 , wherein the host material is an epoxy polymer or resin.
10. The composition of claim 9 , wherein the surface modifying ligand is trimethylolpropane triglycidyl ether.
11. The composition of claim 6 , wherein the host material is a polystyrene resin or a polystyrene copolymer resin.
12. The composition of claim 11 , wherein the surface modifying ligand is a monomethoxy polyethylene oxide.
13. The composition of claim 1 , wherein the nanoparticle of the ligand interactive agent-nanoparticle association complex comprises a metal oxide.
14. The composition of claim 13 , wherein the metal oxide is selected from the group consisting of an iron oxide, titanium oxide, zinc oxide, zirconium oxide, and aluminum oxide.
15. The composition of claim 1 , wherein the nanoparticle of the ligand interactive agent-nanoparticle association complex comprises a metal.
16. The composition of claim 15 , wherein the metal is gold or silver.
17. The composition of claim 1 , wherein the nanoparticle of the ligand interactive agent-nanoparticle association complex comprises a semiconductor material.
18. The composition of claim 17 , wherein the semiconductor material is selected from the group consisting of CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, InP, InAs, InSb, AlP, AlS, AlAs, AlSb, GaN, GaP, GaAs, GaSb, PbS, PbSe, Si, Ge, and any combination thereof.