IP Library Granted Patent US 11,213,806
Granted Patent B1
US 11,213,806 · App. 16/448,632 · Granted Jan 4, 2022

Catalyst supports—composition and process of manufacture

Inventor: Madan Bhasin (Charleston, WV)
B01J27/224B01J23/50B01J35/023B01J35/1009B01J35/1014B01J35/1038B01J35/1042B01J37/0203B01J37/08C07C5/3335C07D301/06C10G11/02C10G45/04C10G47/02C07C2521/08C07C2521/18C07C2523/50C10G2300/202C10G2300/207
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Quick Facts
Patent No.
US 11,213,806
App. No.
16/448,632
Granted
Jan 4, 2022
Kind
B1
Abstract

A catalyst support comprising at least 95% silicon carbide, having surface areas of ≤10 m 2 /g and pore volumes of ≤1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO 2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C., and removing residual carbon from the heated support under temperatures below 1000° C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).

Claims (6)

1. A method of producing a catalyst support, the method comprising:

a. mixing silicon carbide particles of 0.1-20 microns, silicon dioxide and carbonaceous materials to form an extrusion,

b. under inert atmospheres, heating the extrusion at temperatures of greater than 1400° C. to form the catalyst support, and

c. removing residual carbon from the heated catalyst support under temperatures below 1000° C.

2. The method of producing a catalyst support of claim 1 , wherein the silicon carbide particles are selected from a combination of particle sizes, some of which are 0.1-1 microns, some of which are 1-5 microns, and some which are 5-10 microns.

3. The method of producing a catalyst support of claim 1 , wherein the extrusion is heated in the presence of argon or helium.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 25, 2023
From: MID-ATLANTIC TECHNOLOGY, RESEARCH & INNOVATION CENTER, INC.
To: AVN CORPORATION
Reel/Frame 063102/0230 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2019
From: BHASIN, MADAN
To: MID-ATLANTIC TECHNOLOGY, RESEARCH & INNOVATION CENTER, INC.
Reel/Frame 050248/0854 →
Continuity (1)
Provisional Application 62688236 · Jun 21, 2018