Nonaqueous electrolyte battery and battery pack
According to one embodiment, provided is a nonaqueous electrolyte battery that includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte. The separator is disposed between the positive electrode and the negative electrode. The separator includes a fiber-made nonwoven fabric having a tortuosity of 1.8 to 3 and a vacancy of 40% to 60%. The negative electrode has an operating potential of 0.7 V or more with respect to the potential of metallic lithium.
1. A nonaqueous electrolyte battery comprising:
a positive electrode;
a negative electrode having an operating potential of 0.7 V or more with respect to a potential of metallic lithium;
a separator disposed between the positive electrode and the negative electrode, the separator comprising a fiber-made nonwoven fabric having a tortuosity of 1.8 to 3 and a vacancy of 40% to 60%; and
a nonaqueous electrolyte,
wherein the fiber-made non-woven fabric has an air permeability according to a Gurley method (JIS-P-8117) in a range of 0.01 (sec/100 cc) to 1 (sec/100 cc).
2. The nonaqueous electrolyte battery according to claim 1 , wherein the negative electrode has an operating potential of 0.7 V to 3 V with respect to a potential of metallic lithium.
3. The nonaqueous electrolyte battery according to claim 1 , wherein the fiber-made nonwoven fabric comprises a fiber made of at least one material selected from the group consisting of cellulose, polyester, polyvinyl alcohol, polyamide, polytetrafluoroethylene, and vinylon.
4. The nonaqueous electrolyte battery according to claim 3 , wherein the fiber made of the at least one material has an average fiber diameter of 20 μm or less.
5. The nonaqueous electrolyte battery according to claim 3 , wherein the fiber made of the at least one material comprises at least 30% by mass of cellulose fiber.
6. The nonaqueous electrolyte battery according to claim 1 , wherein the separator has a density in a range of 4×10 5 (g/m 3 ) to 8×10 5 (g/m 3 ).
7. The nonaqueous electrolyte battery according to claim 1 , wherein the separator has a basis weight in a range of 7 (g/m 2 ) to 20 (g/m 2 ).
8. The nonaqueous electrolyte battery according to claim 1 , wherein the separator has a thickness in a range of 10 μm to 35 μm.
9. The nonaqueous electrolyte battery according to claim 1 , wherein the negative electrode comprises a negative electrode active material, the negative electrode active material comprising lithium titanate having a spinel structure.
10. The nonaqueous electrolyte battery according to claim 9 , wherein the negative electrode active material further comprises at least one selected from the group consisting of titanium oxide having a monoclinic structure, orthorhombic titanium-containing oxide, monoclinic niobium titanium composite oxide, and lithium titanate having a ramsdellite structure.
11. The nonaqueous electrolyte battery according to claim 9 , wherein the negative electrode active material comprises at least 10% by mass of the lithium titanate having a spinel structure.
12. The nonaqueous electrolyte battery according to claim 9 , wherein the negative electrode active material comprises the lithium titanate having a spinel structure in a range of 10% by mass or more and less than 100% by mass.
13. A battery pack comprising one of the nonaqueous electrolyte battery according to claim 1 , or comprising two or more of the nonaqueous electrolyte batteries.