IP Library › Granted Patent US 10,854,835
Granted Patent B2
US 10,854,835 · App. 16/458,308 · Granted Dec 1, 2020

Organic electroluminescent element and novel iridium complex

Inventors: Kousuke Watanabe (Kanagawa, JP); Yuichirou Itai (Kanagawa, JP)
Assignee: UDC IRELAND LIMITED
H01L51/5012C07F15/0033C09K11/06H01L51/0085H05B33/14C09K2211/1007C09K2211/1029C09K2211/185H01L51/5016
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Quick Facts
Patent No.
US 10,854,835
App. No.
16/458,308
Granted
Dec 1, 2020
Kind
B2
Abstract

An iridium complex which has a phenylpyridine bidentate ligand containing a group represented by the following general formula (A): wherein X represents a cyano group or a halogenated alkyl group; L represents a single bond or a divalent linking group; R represents a substituent; n represents an integer of 0 to 4; * represents a binding site to a phenylpyridine bidentate ligand.

Claims (25)

1. A compound represented by the following general formula (1):

wherein R 111 to R 134 each independently represent a hydrogen atom or a substituent;

at least two adjacent groups out of R 111 to R 114 , R 114 and R 115 , at least two adjacent groups out of R 115 to R 118 , at least two adjacent groups out of R 119 to R 122 , R 122 and R 123 , at least two adjacent groups out of R 123 to R 126 , at least two adjacent groups out of R 127 to R 130 , R 130 and R 131 , or at least two adjacent groups out of R 131 to R 134 may be bonded to each other to form a ring;

provided that at least one of R 119 to R 134 represents a group represented by the following general formula (A), and that none of R 111 to R 118 represent a group represented by general formula (A):

X represents a cyano group or a trifluoromethyl group;

L represents a single bond or a divalent linking group;

R represents a substituent, wherein when a plurality of R's are present, they may be the same as or different from each other;

n represents an integer of 0 to 4; and

* represents a binding site.

2. The compound of claim 1 , wherein the compound represented by the general formula (1) is a compound represented by the following general formula (2):

wherein R 111 to R 123 , R 125 , R 126 , and R 211 to R 215 each independently represent a hydrogen atom or a substituent, wherein two groups out of R 111 to R 118 may be each the same as or different from each other;

at least two adjacent groups out of R 111 to R 114 , R 114 and R 115 , at least two adjacent groups out of R 115 to R 118 , at least two adjacent groups out of R 119 to R 122 , R 122 and R 123 , or R 125 and R 126 may be bonded to each other to form a ring; and

L represents a single bond or a divalent linking group;

provided that at least one of R 211 to R 215 represents a cyano group or a trifluoromethyl group.

3. The compound of claim 1 , wherein the compound represented by the general formula (1) is a compound represented by the following general formula (4):

wherein R 111 to R 120 , R 122 to R 126 , and R 411 to R 415 each independently represent a hydrogen atom or a substituent, wherein two groups out of R 111 to R 118 may be each the same as or different from each other;

at least two adjacent groups out of R 111 to R 114 , R 114 and R 115 , at least two adjacent groups out of R 115 to R 118 , R 119 and R 120 , R 122 and R 123 , or at least two adjacent groups out of R 123 to R 126 , may be bonded to each other to form a ring; and

L represents a single bond or a divalent linking group;

provided that at least one of R 411 to R 415 represents a cyano group or a trifluoromethyl group.

4. The compound of claim 1 , wherein the compound represented by the general formula (1) is a compound represented by the following general formula (6):

wherein R 111 to R 124 , R 126 , and R 611 to R 615 each independently represent a hydrogen atom or a substituent, wherein two groups out of R 111 to R 118 may be each the same as or different from each other;

at least two adjacent groups out of R 111 to R 114 , R 114 and R 115 , at least two adjacent groups out of R 115 to R 118 , at least two adjacent groups out of R 119 to R 122 , R 122 and R 123 , or R 123 and R 124 , may be bonded to each other to form a ring; and

L represents a single bond or a divalent linking group;

provided that at least one of R 611 to R 615 represents a cyano group or a trifluoromethyl group.

5. The compound of claim 1 , wherein X in the general formula (A) is a cyano group.

Priority Claims (1)
JP 2011-218507 · Sep 30, 2011 · national
Continuity (2)
Continuation 14240109
Related Publication 20190341569A1 · Nov 7, 2019