Method for producing ammonia and urea in a common facility
View Patent ↗A process for preparing ammonia or ammonia and urea in a facility may involve compressing a crude synthesis gas stream that includes hydrogen, nitrogen, and carbon dioxide, washing a substream of the crude synthesis gas with ammonia to form a purified synthesis gas stream depleted of carbon dioxide and a condensate, synthesizing ammonia from the purified synthesis gas stream, and synthesizing urea from the condensate to form an aqueous urea composition. In the preparation of ammonia and urea, the crude synthesis gas stream may be, after being compressed, divided into a first synthesis gas substream and a second synthesis gas substream. In some instances, only the first synthesis gas substream is scrubbed with liquid ammonia.
1. A plant for preparing ammonia and urea or for preparing ammonia, the plant comprising:
an apparatus configured to provide a crude synthesis gas stream comprising hydrogen, nitrogen, and carbon dioxide;
a compressor configured to compress the crude synthesis gas stream to form a compressed synthesis gas stream;
a scrubbing column configured to scrub the compressed synthesis gas stream with a composition comprising ammonia to form a purified synthesis gas stream depleted of carbon dioxide and a condensate;
a first reactor configured to synthesize ammonia from the purified synthesis gas stream;
a second reactor configured to synthesize urea from the condensate to form an aqueous urea composition;
a first dividing apparatus downstream of the compressor for dividing the compressed synthesis gas stream into a first synthesis gas stream and a second synthesis gas stream;
a first conduit via which only the first synthesis gas stream can be fed to the scrubbing column, the first conduit leading from the first dividing apparatus to the scrubbing column;
a stripper;
a second conduit via which only the second synthesis gas stream can be fed to the stripper, the second conduit leading from the first dividing apparatus to the stripper; and
a third conduit extending from the second reactor to the stripper, wherein the aqueous urea composition is conveyable from the second reactor to the stripper via the third conduit.
2. The plant of claim 1 comprising:
a second dividing apparatus disposed upstream of the compressor, wherein by way of the second dividing apparatus the crude synthesis gas stream is dividable into a first substream and a second substream, wherein a fourth conduit for the first substream extends from the second dividing apparatus to the compressor, wherein a fifth conduit for the second substream extends from the second dividing apparatus to a scrubbing apparatus configured to scrub the second substream of the crude synthesis gas with a first scrubbing solution comprising water and ammonia to form a pre-purified synthesis gas stream depleted of carbon dioxide and a second scrubbing solution enriched in carbon dioxide and for driving off carbon dioxide from the second scrubbing solution to form a compressed carbon dioxide stream; and
means for combining a pre-purified third synthesis gas substream from the scrubbing apparatus downstream of the scrubbing apparatus and upstream of the compressor with a first synthesis gas substream to form a combined synthesis gas stream that can be fed via a conduit to the compressor.
3. The plant of claim 1 comprising at least one of:
a sixth conduit for feeding a stripping gas stream from the stripper to the scrubbing column; or
an apparatus disposed upstream of the first reactor for synthesis of ammonia and configured to effect methanation of a purified synthesis gas stream depleted of carbon dioxide from the scrubbing column to form a high-purity synthesis gas stream.
4. The plant of claim 1 comprising a series of apparatuses configured to remove, separate off, and recover ammonia and water from at least part of a compressed carbon oxide stream obtained downstream of the scrubbing apparatus.