Method for manufacturing superconductor comprising magnesium diboride, and super-conductor comprising magnesium diboride
According to an exemplary embodiment of the present invention, provided is a method for manufacturing a superconductor including magnesium diboride, the method including: a first mixture preparation step of preparing a first mixture including a boron powder and a liquid chlorinated hydrocarbon compound; a second mixture preparation step of preparing a second mixture including the first mixture and a magnesium powder; a molded body manufacturing step of manufacturing a molded body by pressurizing the second mixture; and a sintering step of sintering the molded body to manufacture a superconductor including magnesium diboride.
1. A method for manufacturing a superconductor, the method comprising:
preparing a first mixture comprising a boron powder and a liquid chlorinated hydrocarbon compound;
preparing a second mixture comprising the first mixture and a magnesium powder;
manufacturing a molded body by pressurizing the second mixture; and
sintering the molded body to manufacture the superconductor including magnesium diboride.
2. The method of claim 1 , wherein the first mixture has a weight ratio of the boron powder to the liquid chlorinated hydrocarbon compound of 1:0.2 to 1:25.
3. The method of claim 1 , wherein the second mixture has a molar ratio of the first mixture to the magnesium powder of 2:1.
4. The method of claim 1 , wherein the boron powder comprises 99% or more of boron powder particles having a particle size of 20 nm to 100 nm based on an entirety of the boron powder.
5. The method of claim 1 , wherein the magnesium powder comprises 99% or more of magnesium powder particles having a particle size of 1 μm to 5 μm based on an entirety of the magnesium powder.
6. The method of claim 1 , wherein
the boron powder comprises oxygen and chlorine,
a content of the oxygen is 0.3 at % to 0.7 at % based on the boron powder,
a content of the chlorine is 0.03 at % to 0.1 at % based on the boron powder, and
a balance is boron.
7. The method of claim 1 , wherein the liquid chlorinated hydrocarbon compound is chloroform, carbon tetrachloride, or a combination of chloroform and carbon tetrachloride.
8. The method of claim 1 , wherein the sintering is performed at 600° C. to 1000° C. for 110 minutes to 10 hours.
9. The method of claim 1 , wherein the sintering is performed in an inert gas atmosphere.
10. A superconductor comprising:
magnesium diboride and chlorine,
wherein a content of the chlorine is 0.1 at % to 2 at % based on the magnesium diboride.
11. The superconductor of claim 10 , wherein the chlorine is present at crystal grain boundary of the magnesium diboride or inside thereof.