Composition comprising cinmethylin-containing microparticles and a further herbicide
The present invention relates to a composition containing microparticles which comprise cinmethylin and a polymeric material which surrounds or embeds cinmethylin, and at least one herbicide different from cinmethylin. The invention further relates to a method for preparing such compositions and the use of such compositions for controlling undesired vegetation.
1. A composition comprising
(a) microparticles which comprise cinmethylin and a polymeric material which surrounds or embeds cinmethylin; and
(b) an herbicide different from cinmethylin and selected from the group of picolinafen, diflufenican, and flufenacent, wherein the herbicide different from cinmethylin is not enclosed in the microparticle.
2. The composition of claim 1 , wherein cinmethylin and the herbicide different therefrom are present in a weight ratio of from 100:1 to 1:100.
3. The composition of claim 1 , wherein the microparticles are selected from the group consisting of
microcapsules comprising a shell and a core, where the core comprises cinmethylin and the shell comprises a polymeric material;
matrix particles containing a polymeric material in form of a polymer matrix in which cinmethylin is embedded; and
mixed forms thereof.
4. The composition of claim 1 , wherein the polymeric material is selected from the group consisting of polyureas, polyurethanes, poly(meth)acrylates, aminoplasts, polystyrenes, polyamides, polysulfonamides, polyesters and polycarbonates.
5. The composition of claim 4 , wherein the polymeric material is selected from the group consisting of polyureas, poly(meth)acrylates and aminoplasts.
6. The composition of claim 3 , wherein the microparticles are microcapsules comprising a shell and a core, wherein the core comprises cinmethylin and the shell comprises polyurea obtainable by polyaddition reaction of at least one aliphatic or aromatic polyisocyanate and at least one aliphatic or aromatic polyamine.
7. The composition of claim 3 , wherein in the microcapsules the weight ratio of cinmethylin and the polymeric material comprised in the shell is of from 1:1 to 80:1, and in the matrix particles the weight ratio of cinmethylin and the polymeric material forming the polymer matrix is of from 10:1 to 1:10.
8. The composition of claim 1 , wherein the average particle size d50 of the microparticles, as determined according to ISO 13320:2009, Particle Size Analysis—Laser Diffraction Methods, is from 0.05 to 100 μm.
9. The composition of claim 8 , wherein the average particle size d50, as determined according to ISO 13320:2009, Particle Size Analysis—Laser Diffraction Methods, is from 0.5 to 100 μm when the microparticles are microcapsules, and the average particle size d50 is of from 50 nm to 1 μm when the microparticles are matrix particles.
10. The composition of claim 1 , containing the microparticles in an amount of from 10 to 70% by weight, based on the total weight of the composition.
11. The composition of claim 1 , which is an aqueous dispersion.
12. The composition of claim 1 further comprising a surfactant, further dispersing agent, emulsifier, wetting agent, further adjuvant, solubilizer, penetration enhancer, protective colloid, adhesion agent, thickener, humectant, antifoam, antifreeze agent, stabilizer, antimicrobial agent, pigment, colorant, buffer, tackifier or binder.
13. A method for preparing the composition of claim 1 comprising polymerizing one or more monomers or curing a pre-polymer or pre-condensate in the presence of the cinmethylin, and mixing with the herbicide different from cinmethylin.
14. The composition of claim 3 , wherein the microparticles are microcapsules.