Rubber composition, processing method thereof, and high-strength product using the same
The present invention discloses a rubber composition. The rubber composition includes a rubber matrix and a crosslinking system. The rubber matrix includes, in parts by weight, the following components: a branched polyethylene with a content represented as A, in which 0<A≤100, an EPM with a content represented as B, in which 0≤B<100, and an EPDM with a content represented as C, in which 0≤C<100. Based on 100 parts by weight of said rubber matrix, the content of the crosslinking system is represented as D: 1≤D≤15 parts. The crosslinking system includes at least one of a crosslinking agent and an auxiliary crosslinking agent. The branched polyethylene has a degree of branching of not less than 50 branches/1000 carbon atoms, a weight average molecular weight of not less than 50,000, and a Mooney viscosity ML(1+4) at 125° C. of not less than 2. The rubber composition provided by the present invention can effectively solve the problems of low crosslinking efficiency and mechanical strength in the prior art, and simultaneously has good electrical insulation properties and mechanical strength.
1. A rubber composition comprising a rubber matrix and a crosslinking system, wherein the rubber matrix comprises, based on 100 parts by weight of the rubber matrix,
a branched polyethylene with a content represented as A, in which 0<A≤100 parts, and
an EPM with a total content represented as B, in which 0≤B<100 parts;
an EPDM with a total content represented as C, in which 0≤C<100 parts;
wherein, with respect to 100 parts by weight of the total amount of the rubber matrix, the crosslinking system is represented as D, in which 1≤D<15 parts;
wherein the crosslinking system comprises at least one of a crosslinking agent and an auxiliary crosslinking agent; and wherein the branched polyethylene comprises an ethylene homopolymer having a branching degree of from about 60 to 99 branches/1000 carbon atoms, a weight average molecular weight of from 66,000 to 518,000, and a Mooney viscosity ML(1+4) at 125° C. of from 6 to 102.
2. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of from 60 to 94 branches/1000 carbon atoms.
3. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of from 60 to 90 branches/1000 carbon atoms.
4. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of from 60 to 87 branches/1000 carbon atoms.
5. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of from 60 to 82 branches/1000 carbon atoms.
6. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of from 60 to 70 branches/1000 carbon atoms.
7. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of 60 branches/1000 carbon atoms, 70 branches/1000 carbon atoms, 82 branches/1000 carbon atoms, 87 branches/1000 carbon atoms, 94 branches/1000 carbon atoms, or 99 branches/1000 carbon atoms.
8. The rubber composition according to claim 1 , wherein the ethylene homopolymer has a branching degree of about 60 branches/1000 carbon atoms, about 70 branches/1000 carbon atoms, about 82 branches/1000 carbon atoms, about 87 branches/1000 carbon atoms, 94 branches/1000 carbon atoms, or 99 branches/1000 carbon atoms.
9. The rubber composition according to claim 1 , wherein the crosslinking agent comprises at least one of sulfur and a peroxide crosslinking agent, and the peroxide crosslinking agent comprises at least one of di-tert-butyl peroxide, dicumyl peroxide, tert-butyl cumyl peroxide, 1,1-di-tert-butyl peroxide-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexyne-3, bis(tert-butylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-bis(benzoylperoxy)hexane, tert-butyl peroxybenzoate, and tert-butylperoxy-2-ethylhexyl carbonate.
10. The rubber composition according to claim 1 , wherein the auxiliary crosslinking agent comprises at least one of triallyl cyanurate, triallyl isocyanurate, ethylene glycol dimethacrylate, ethyl dimethacrylate, triethylene glycol dimethacrylate, triallyl trimellitate, trimethylolpropane trimethacrylate, N,N′-m-phenylene bismaleimide, N,N′-bis(furfurylidene)acetone, 1,2-polybutadiene, and sulfur.
11. The rubber composition according to claim 1 , wherein, based on 100 parts by weight of the rubber matrix, the crosslinking system further comprises up to 3 parts of a vulcanization accelerator, and the vulcanization accelerator comprises at least one of 2-mercaptobenzothiazole, dibenzothiazyl disulfide, tetramethylthiuram monosulfide, tetramethylthiuram disulfide, tetraethylthiuram disulfide, N-cyclohexyl-2-benzothiazolesulfenamide, N,N-dicyclohexyl-2-benzothiazolesulfenamide, bismaleimide, and ethylene thiourea.
12. The rubber composition according to claim 1 , wherein the rubber composition further comprises, based on 100 parts by weight of the rubber matrix:
2 to 10 parts of a metal oxide,
5 to 50 parts of a plasticizer,
0 to 10 parts of a coloring agent,
30 to 200 parts of an inorganic filler,
1 to 3 parts of a stabilizer, and
1 to 2 parts of a coupling agent.
13. The rubber composition according to claim 12 , wherein:
the rubber metal oxide comprises at least one of zinc oxide, magnesium oxide, calcium oxide, lead monoxide, and lead tetraoxide;
the plasticizer comprises at least one of pine tar, engine oil, naphthenic oil, paraffin oil, coumarone, stearic acid, and paraffin;
the coloring agent comprises at least one of carbon black, titanium pigment, pigment blue, and pigment green;
the inorganic filler comprises at least one of calcium carbonate, talcum powder, calcined clay, magnesium silicate, and magnesium carbonate;
the stabilizer comprises at least one of 2,2,4-trimethyl-1,2-dihydroquinoline polymer (RD), 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline (AW), and 2-mercaptobenzimidazole (MB); and
the coupling agent comprises at least one of vinyl tris(2-methoxyethoxy)silane (A-172), γ-glycidyloxypropyl trimethoxysilane (A-187), and γ-mercaptopropyl trimethoxysilane (A-189).
14. A wire comprising a conductor and an insulating layer, wherein the insulating layer comprises a rubber compound formed from the rubber composition according to claim 1 .
15. A cable comprising a conductor, an insulating layer, and a sheath layer, wherein at least one of the insulating layer and the sheath layer comprises a rubber compound formed from the rubber composition according to claim 1 .
16. A high strength rubber product comprising a rubber compound formed from the rubber composition according to claim 1 .
17. The high strength rubber product of claim 16 , wherein the high strength rubber product is a glove.
18. The high strength rubber product of claim 16 , wherein the high strength rubber product is a condom.
19. The high strength rubber product of claim 16 , wherein the crosslinking system in the rubber composition comprises a radiation-sensitized auxiliary crosslinking agent.
20. The high strength rubber product of claim 16 , wherein the high strength rubber product is a rubber plug.