Method for preparing foamed thermoplastic polyurethane elastomer product
The present invention relates to a method for preparing a foamed thermoplastic polyurethane elastomer product, comprising the steps of: 1) coating a binder: coating the binder on the surfaces of expandable thermoplastic polyurethane elastomer particles; 2) curing and molding: adding the product obtained from step 1) to a mold and then placing it in a vulcanizing machine for curing and molding; and 3) cooling and setting: cooling the mold after the molding in step 2) to obtain the product of the present invention. By means of pre-coating the binder on the surfaces of expanded thermoplastic polyurethane elastomer particles according to the present invention, the weight of the binder can be reduced, and the properties of the expanded thermoplastic polyurethane elastomer particles can be utilized to the maximum extent.
1. A method for preparing a foamed thermoplastic polyurethane elastomer product, comprising the steps of:
1) coating a binder on surfaces of expanded thermoplastic polyurethane elastomer particles to form a product;
2) vulcanizing and molding: adding the product obtained from step 1) to a mold and then placing it in a vulcanizing machine at a vulcanizing temperature of 40-200° C. and a vulcanizing pressure of 0.01-1 MPa for a vulcanizing time of 1-30 minutes to vulcanize and mold the product from step 1); and
3) cooling and setting: cooling the mold after the vulcanizing and molding in step 2) to a cooling temperature for a cooling time to obtain the foamed thermoplastic polyurethane elastomer product;
wherein the method does not comprise a step of welding the expanded thermoplastic polyurethane particles through a steam medium; and
wherein the mass ratio of the binder to the expanded thermoplastic polyurethane elastomer particles in step 1) is from 1:500 to 1:10,000.
2. The method according to claim 1 , wherein the binder in step 1) is a hot meltable resin having a melting point of 40-200° C., in the form of powder or liquid.
3. The method according to claim 2 , wherein the binder in step 1) is one of a thermoplastic polyurethane elastomer, an acrylate, an epoxy resin, a single-component polyurethane, a two-component polyurethane, and an aqueous polyurethane.
4. The method according to claim 2 , wherein the hot meltable resin is in the form of powder and has a particle size of 30-5,000 meshes.
5. The method according to claim 3 , wherein the hot meltable resin in the form of powder has a particle size of 50-3,000 meshes.
6. The method according to claim 1 , wherein the expanded thermoplastic polyurethane elastomer particles in step 1) have a density of 0.001-0.6 g/cm 3 .
7. The method according to claim 6 , wherein the expanded thermoplastic polyurethane elastomer particles in step 1) have a density of 0.05-0.3 g/cm 3 .
8. The method according to claim 1 , wherein the mass ratio of the binder to the expanded thermoplastic polyurethane elastomer particles in step 1) is from 1:800 to 1:10,000.
9. The method according to claim 1 , wherein the process of coating the binder on the surfaces of expanded thermoplastic polyurethane elastomer particles in step 1) is one of electrostatic adsorption, spray coating, and dry mixing.
10. The method of claim 1 , wherein in step 3), the cooling temperature is 10-40° C. and the cooling time is 1-20 minutes.
11. The method according to claim 2 , wherein the hot meltable resin is in the form of liquid and has an effective solid content of 5-100 wt %.
12. The method according to claim 11 , wherein the hot meltable resin in the form of liquid has an effective solid content of 10-80 wt %.