Method and plant for producing nitric acid
View Patent ↗A process and a plant for producing nitric acid involves oxidizing ammonia in the presence of catalysts to provide nitrogen monoxide-containing process gas in an oxidation reactor. The formed nitrogen monoxide may be supplied with oxygen-containing gas, and nitrogen monoxide is oxidized to provide nitrogen dioxide that is reacted with water in an absorption apparatus to give nitric acid, nitrous acid, and/or solutions of nitrates and/or nitrites. Oxidation of the nitrogen monoxide may be effected in an additional reactor positioned between the oxidation reactor and the absorption apparatus and traversed by the process gas. The oxidation of the nitrogen monoxide may be effected in an additional reactor parallel and connected to the absorption apparatus and traversed by the process gas. The disclosed processes and plants feature a high energy efficiency combined with a simple construction, and existing plants are easily upgradeable.
1. A process for producing nitric acid comprising:
oxidizing ammonia with oxygen in a presence of catalysts to provide a process gas containing nitrogen monoxide in an oxidation reactor;
supplying oxygen-containing gas to the nitrogen monoxide;
oxidizing the nitrogen monoxide in a second reactor to provide nitrogen dioxide that is reacted with water in an absorption apparatus to provide nitric acid, nitrous acid, and/or solutions of nitrates and/or nitrites, wherein the second reactor is a container charged with a catalyst for oxidizing the nitrogen monoxide to provide the nitrogen dioxide, wherein the second reactor is at least one of:
positioned between the oxidation reactor and the absorption apparatus with respect to a flow direction of the process gas such that the process gas traverses the second reactor, or
positioned in parallel with the absorption apparatus and connected to the absorption apparatus such that the process gas traverses the second reactor; and
causing the process gas to enter the second reactor at a temperature of 160° C.-350° C.
2. The process of claim 1 wherein the second reactor is positioned downstream of the oxidation reactor and upstream of a residual gas heater with respect to the flow direction of the process gas.
3. The process of claim 1 wherein the second reactor is a container whose total gas content is large enough for the oxidation of the nitrogen monoxide to provide the nitrogen dioxide as a gas-phase reaction to proceed completely.
4. The process of claim 1 wherein the second reactor is a radial bed reactor comprising a concentric catalyst bed that is traversed by the process gas.