All-solid-state battery and production method of the same
Disclosed is an all-solid-state battery including a positive electrode, a negative electrode, and a solid electrolyte layer interposed between the positive electrode and the negative electrode. At least one of the positive electrode and the negative electrode contains first solid electrolyte particles. The solid electrolyte layer contains second solid electrolyte particles having ion conductivity. An average particle diameter D 1 of the first solid electrolyte particles, and an average particle diameter D 2 of the second solid electrolyte particles satisfy D 2 >D 1.
1. An all-solid-state battery, comprising
a positive electrode, a negative electrode, and a solid electrolyte layer interposed between the positive electrode and the negative electrode,
wherein the positive electrode contains first solid electrolyte particles and the negative electrode contains first solid electrolyte particles,
wherein the solid electrolyte layer contains second solid electrolyte particles having ion conductivity,
wherein the first solid electrolyte particles contained in the positive electrode include at least one selected from the group consisting of a sulfide and a hydride,
wherein the first solid electrolyte particles contained in the negative electrode include at least one selected from the group consisting of a sulfide and a hydride,
wherein the second solid electrolyte particles contained in the solid electrolyte layer include at least one selected from the group consisting of a sulfide and a hydride,
wherein an average particle diameter D 1 of the first solid electrolyte particles, and an average particle diameter D 2 of the second solid electrolyte particles satisfy D 2 >D 1 ,
wherein the average particle diameter D 2 of the second solid electrolyte particles is 3 μm or more,
wherein the second solid electrolyte particles include a first group of particles and a second group of particles, and
wherein the second group of particles of the second solid electrolyte particles each have an average particle diameter D 22 of 1 nm or more and less than 100 nm.
2. The all-solid-state battery of claim 1 , wherein the solid electrolyte layer has a thickness of 5 μm or more and 150 μm or less, the thickness being smaller than a thickness of the positive electrode and a thickness of the negative electrode.
3. The all-solid-state battery of claim 1 , wherein the average particle diameter D 2 of the second solid electrolyte particles is 50 μm or less, and equal to or less than a half of the thickness of the solid electrolyte layer.
4. The all-solid-state battery of claim 1 , wherein the average particle diameter D 1 of the first solid electrolyte particles is 0.01 μm or more and 10 μm or less.
5. The all-solid-state battery of claim 1 , wherein the first group of particles of the second solid electrolyte particles each have a particle diameter of 1 μm or more,
wherein the second group of particles of the second solid electrolyte particles each have a diameter of less than 1 μm, and
wherein an average particle diameter D 21 of the first group of particles of the second solid electrolyte particles, the average particle diameter D 22 of the second group of particles of the second solid electrolyte particles, and the average particle diameter D 1 of the first solid electrolyte particles satisfy D 21 >D 1 >D 22 .
6. The all-solid-state battery of claim 5 , wherein the first group of particles of the second solid electrolyte particles are contained in the solid electrolyte layer at a ratio of 50 volume % or more.
7. The all-solid-state battery of claim 1 , wherein the solid electrolyte layer has a packing density of 99 volume % or more.
8. A production method of an all-solid-state battery, the method comprising:
a step of forming an electrode group that includes a positive electrode, a negative electrode, and a solid electrolyte layer interposed between the positive electrode and the negative electrode; and
a pressing step of pressing the electrode group,
wherein at least one of the positive electrode and the negative electrode contains first solid electrolyte particles,
wherein in the step of forming the electrode group, the solid electrolyte layer is formed by using second solid electrolyte particles having ion conductivity by a dry process,
wherein an average particle diameter d 1 of the first solid electrolyte particles used for the electrode, and an average particle diameter d 2 of the second solid electrolyte particles used for the solid electrolyte layer satisfy d 2 >d 1 ,
wherein the average particle diameter d 2 of the second solid electrolyte particles is 3 μm or more,
wherein the second solid electrolyte particles include a first group of particles and a second group of particles, and
wherein the second group of particles of the second solid electrolyte particles each have an average particle diameter D 22 of 1 nm or more and less than 100 nm.
9. The method of claim 8 , wherein, in the pressing step, the electrode group is pressed at a pressure of 100 MPa or more and 1500 MPa or less.
10. The method of claim 8 , wherein the solid electrolyte layer is formed without using a binder.
11. An all-solid-state battery, comprising
a positive electrode, a negative electrode, and a solid electrolyte layer interposed between the positive electrode and the negative electrode,
wherein at least one of the positive electrode and the negative electrode contains first solid electrolyte particles,
wherein the solid electrolyte layer contains second solid electrolyte particles having ion conductivity,
wherein an average particle diameter D 1 of the first solid electrolyte particles, and an average particle diameter D 2 of the second solid electrolyte particles satisfy D 2 >D 1 ,
wherein the average particle diameter D 2 of the second solid electrolyte particles is 3 μm or more,
wherein the second solid electrolyte particles include a first group of particles each having a particle diameter of 1 μm or more, and a second group of particles each having a diameter of less than 1 μm,
wherein an average particle diameter D 21 of the first group of particles of the second solid electrolyte particles, an average particle diameter D 22 of the second group of particles of the second solid electrolyte particles, and the average particle diameter D 1 of the first solid electrolyte particles satisfy D 21 >D 1 >D 22 , and
wherein the average particle diameter D 22 of the second group of particles of the second solid electrolyte particles is 1 nm or more and less than 100 nm.
12. The all-solid-state battery of claim 11 , wherein the average particle diameter D 21 of the first group of particles of the second solid electrolyte particles is 5 μm or more and 20 μm or less.
13. The all-solid-state battery of claim 11 , wherein the solid electrolyte layer has a thickness of 5 μm or more and 150 μm or less, the thickness being smaller than a thickness of the positive electrode and a thickness of the negative electrode.
14. The all-solid-state battery of claim 11 , wherein the average particle diameter D 2 of the second solid electrolyte particles is 50 μm or less, and equal to or less than a half of the thickness of the solid electrolyte layer.
15. The all-solid-state battery of claim 11 , wherein the average particle diameter D 1 of the first solid electrolyte particles is 0.01 μm or more and 10 μm or less.
16. The all-solid-state battery of claim 11 , wherein the first group of particles are contained in the solid electrolyte layer at a ratio of 50 volume % or more.
17. The all-solid-state battery of claim 11 , wherein the solid electrolyte layer has a packing density of 99 volume % or more.
18. The all-solid-state battery of claim 11 , wherein the solid electrolyte layer contains no residue of an organic binder or contains a residue of an organic binder, and
wherein the amount of the residue of the organic binder in the solid electrolyte layer is 1 mass % or less, when the solid electrolyte layer contains the residue of the organic binder.