Solid electrolyte, electrode, power storage device, and method for producing solid electrolytes
A solid electrolyte ( 10 ) of the present disclosure includes porous silica ( 11 ) having a plurality of pores ( 12 ) interconnected mutually and an electrolyte ( 13 ) coating inner surfaces of the plurality of pores ( 12 ). The electrolyte ( 13 ) includes 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide represented by EMI-TFSI and a lithium salt dissolved in the EMI-TFSI. A molar ratio of the EMI-TFSI to the porous silica ( 11 ) is larger than 1.5 and less than 2.0.
1. A solid electrolyte comprising:
mesoporous silica having a plurality of pores interconnected mutually; and
an electrolyte coating inner surfaces of the plurality of pores and forming a three-dimensional network, wherein the electrolyte comprises 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide represented by EMI-TFSI and a lithium salt dissolved in the EMI-TFSI, the lithium salt comprising lithium bis(trifluoromethanesulfonyl)imide, and
wherein a molar ratio of the EMI-TFSI to a silicon alkoxide that forms the mesoporous silica is 1.7 or more and 1.8 or less.
2. The solid electrolyte according to claim 1 , wherein
the electrolyte comprises a first electrolyte layer having contact with the inner surfaces of the plurality of pores,
the first electrolyte layer comprises a first anion layer, a first cation layer, and a second anion layer,
the first anion layer comprises a plurality of first bis(trifluoromethanesulfonyl)imide ions adsorbed to the inner surfaces of the plurality of pores of the mesoporous silica,
the first cation layer comprises a plurality of 1-ethyl-3-methylimidazolium ions ionically bonded to the plurality of first bis(trifluoromethanesulfonyl)imide ions respectively, and
the second anion layer comprises a plurality of second bis(trifluoromethanesulfonyl)imide ions ionically bonded to the plurality of 1-ethyl-3-methylimidazolium ions respectively.
3. The solid electrolyte according to claim 1 , wherein
the mesoporous silica forms a single layer, and an outer boundary of the solid electrolyte is defined by the mesoporous silica.
4. The solid electrolyte according to claim 1 , wherein the silicon alkoxide comprises at least one selected from tetraethyl orthosilicate, a substituted tetraethyl orthosilicate, and tetramethyl orthosilicate.
5. The solid electrolyte according to claim 4 , wherein the silicon alkoxide comprises tetraethyl orthosilicate.
6. An electrode, comprising:
the solid electrolyte according to claim 1 ; and
an electrode active material.
7. The electrode according to claim 6 , further comprising at least one selected from a conductive agent and a binder.
8. The electrode according to claim 6 , further comprising a conductive agent, wherein
a plurality of first particles made of the electrode active material and a plurality of second particles made of the conductive agent are fixed in a matrix of the solid electrolyte.
9. A power storage device, comprising:
a positive electrode;
a negative electrode; and the solid electrolyte according to claim 1 .
10. A power storage device, comprising:
a positive electrode; and
a negative electrode, wherein
at least one selected from the positive electrode and the negative electrode is the electrode according to claim 6 .
11. A method for producing a solid electrolyte, comprising:
mixing a silicon alkoxide, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMI-TFSI), lithium bis(trifluoromethanesulfonyl)imide, water, and an organic solvent to prepare a liquid mixture;
causing gelation of the liquid mixture to form a gel mixture; and
drying the gel mixture to form a solid electrolyte, the solid electrolyte comprising mesoporous silica having a plurality of pores interconnected mutually and an electrolyte coating inner surfaces of the plurality of pores and forming a three-dimensional network, wherein the molar ratio of the EMI-TFSI to the silicon alkoxide forming the mesoporous silica is 1.7 or more and 1.8 or less.
12. The method according to claim 11 , wherein the silicon alkoxide comprises at least one selected from tetraethyl orthosilicate, a substituted tetraethyl orthosilicate, and tetramethyl orthosilicate.
13. A solid electrolyte comprising:
mesoporous silica having a plurality of pores interconnected mutually; and
an electrolyte coating inner surfaces of the plurality of pores and forming a three-dimensional network, wherein the electrolyte comprises 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide represented by EMI-TFSI and a lithium salt dissolved in the EMI-TFSI, the lithium salt comprising lithium bis(trifluoromethanesulfonyl)imide,
wherein a molar ratio of the EMI-TFSI to a silicon alkoxide that forms the mesoporous silica is 1.7 or more and 1.8 or less, and
wherein the electrolyte comprises a first electrolyte layer having contact with the inner surfaces of the plurality of pores,
the first electrolyte layer comprises a first anion layer, a first cation layer, and a second anion layer,
the first anion layer comprises a plurality of first bis(trifluoromethanesulfonyl)imide ions adsorbed to the inner surfaces of the plurality of pores of the mesoporous silica,
the first cation layer comprises a plurality of 1-ethyl-3-methylimidazolium ions ionically bonded to the plurality of first bis(trifluoromethanesulfonyl)imide ions respectively, and
the second anion layer comprises a plurality of second bis(trifluoromethanesulfonyl)imide ions ionically bonded to the plurality of 1-ethyl-3-methylimidazolium ions respectively.