Porous ceramic structure for carbon dioxide capture
In one inventive concept, a product includes a three dimensional ceramic structure having an open cell structure with a plurality of pores, wherein the pores connect through the ceramic structure from one side of the ceramic structure to an opposite side of the ceramic structure.
1. A product, comprising:
a three dimensional ceramic structure having an open cell structure with a plurality of pores, wherein the pores connect through the ceramic structure from one side of the ceramic structure to an opposite side of the ceramic structure, wherein an average diameter of the pores is in a range of about 10 nanometers to about 1000 nanometers.
2. The product as recited in claim 1 , wherein the ceramic structure comprises a Y 2 O 3 -doped ZrO 2 selected from the group consisting of: tetragonal zirconia polycrystal and yttria fully stabilized zirconia.
3. The product as recited in claim 1 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 500 nanometers.
4. The product as recited in claim 1 , wherein a density of the ceramic structure is in a range of about 20% to about 50% of a density of a solid ceramic form of identical composition.
5. The product as recited in claim 1 , comprising a molten hydroxide in the pores, the molten hydroxide being retained in the pores by capillary action.
6. The product as recited in claim 5 , wherein the molten hydroxide is potassium hydroxide.
7. The product as recited in claim 5 , wherein the molten hydroxide is a mixture comprising of lithium hydroxide, potassium hydroxide, and sodium hydroxide.
8. The product as recited in claim 5 , wherein the ceramic structure has physical characteristics that enable the ceramic structure to retain the molten hydroxide in the pores after exposure to temperatures at about 400 degrees Celsius for at least 100 hours.
9. The product as recited in claim 5 , wherein the ceramic structure has physical characteristics that enable the ceramic structure to retain the molten hydroxide in the pores after at least twenty heating and cooling cycles, wherein the heating is to about 400 degrees Celsius, wherein the cooling is to at least room temperature.
10. A method of forming a porous ceramic structure, the method comprising:
combining metal oxide nanoparticles and a polymer to create a slurry mixture;
forming a body of the slurry mixture;
curing the formed body for crosslinking the polymer;
heating the formed body to a first temperature for removing the polymer from the formed body; and
heating the formed body to a second temperature for sintering the formed body of the metal oxide nanoparticles, thereby creating a porous ceramic structure having an open cell structure with a plurality of pores, wherein the pores connect through the ceramic structure from one side of the ceramic structure to an opposite side of the ceramic structure.
11. The method as recited in claim 10 , wherein the slurry mixture comprises metal oxide nanoparticles in a range of about 50 wt % to about 80 wt % of total mixture.
12. The method as recited in claim 10 , wherein the metal oxide nanoparticles comprise a Y 2 O 3 -doped ZrO 2 selected from the group consisting of: tetragonal zirconia polycrystal and yttria fully stabilized zirconia.
13. The method as recited in claim 10 , wherein the metal oxide nanoparticles have an average diameter in a range of at least about 20 nanometers to about 600 nanometers.
14. The method as recited in claim 10 , wherein the forming the body comprises extruding the slurry mixture into a free-standing shape.
15. The method as recited in claim 10 , wherein the formed body has a curved surface.
16. The method as recited in claim 10 , wherein the body of the slurry mixture is formed by additive manufacturing of the slurry mixture.
17. The method as recited in claim 16 , wherein the additive manufacturing is direct ink writing, wherein an ink is the slurry mixture.
18. The method as recited in claim 10 , further comprising filling the porous ceramic structure with an inorganic base material, wherein the inorganic base material includes a molten hydroxide.
19. The method as recited in claim 18 , wherein the molten hydroxide includes molten potassium hydroxide.
20. The method as recited in claim 18 , wherein the molten hydroxide is a mixture comprising of lithium hydroxide, potassium hydroxide, and sodium hydroxide.
21. A product, comprising:
a three dimensional (3D) ceramic structure having a predefined shape characteristic of formation by additive manufacturing processes,
wherein the ceramic structure has an open cell structure with a plurality of pores, wherein the pores connect through the ceramic structure from one side of the ceramic structure to an opposite side of the ceramic structure,
wherein an average diameter of the pores is in a range of about 10 nanometers to about 1000 nanometers.
22. The product as recited in claim 21 , wherein the ceramic structure has physical characteristics of formation by casting a ceramic mixture into a mold.
23. The product as recited in claim 21 , wherein the ceramic structure has physical characteristics of formation by extruding a ceramic mixture into a free-standing 3D shape.
24. The product as recited in claim 21 , wherein an average diameter of the pores is in a range of about 10 nanometers to about 500 nanometers.
25. The product as recited in claim 21 , comprising a molten hydroxide in the pores, the molten hydroxide being retained in the pores by capillary action.