IP Library Granted Patent US 10,813,904
Granted Patent B2
US 10,813,904 · App. 16/487,304 · Granted Oct 27, 2020

Small molecule anticancer agents

Inventors: Brian Keith Law (Gainesville, FL); Ronald K. Castellano (Gainesville, FL); Renan B. Ferreira (Gainesville, FL)
Assignee: University of Florida Research Foundation, Incorporated
A61K31/22A61K31/517A61K39/3955C07C323/64
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Quick Facts
Patent No.
US 10,813,904
App. No.
16/487,304
Granted
Oct 27, 2020
Kind
B2
Abstract

The invention relates to methods of treating cell proliferative disorders. The invention further relates to pharmaceutical compositions for treating cell proliferative disorders, especially cancer.

Claims (36)

1. A compound of Formula I, or salt thereof:

wherein,

each X is independently S or Se;

each Y is independently S or Se;

each Z is independently S or Se;

each Z 1 , Z 2 , and Z 3 is independently

and

each R 7 is independently H, Na, K, optionally substituted alkyl, optionally substituted aryl, or optionally substituted arylalkyl.

2. A compound of Formula II, or salt thereof:

wherein,

each X is independently S or Se;

each Y is independently S or Se;

each Z is independently S or Se;

each Z 1 , Z 2 , Z 3 , and Z 4 is independently

each R 7 is independently H, Na, K, optionally substituted alkyl, optionally substituted aryl, or optionally substituted arylalkyl; and

each n is independently 0, 1, 2 or 3.

3. The compound of claim 1 , or salt thereof:

wherein, X is S; Y is S; and Z is S.

4. The compound of claim 1 , or salt thereof, wherein, X is S; Y is S; Z is S; and R 7 is K or Na.

5. The compound of claim 2 , or salt thereof, wherein, n is 1; X is S; Y is S; Z is S; and R 7 is K or Na.

6. A compound that is:

or salt thereof.

7. A method of treating a subject suffering from cancer comprising administering to the subject in need thereof a therapeutically effective amount of a compound of claim 1 , or a salt thereof.

8. The method of claim 7 , wherein the cancer is HER2 mediated or breast cancer.

9. The method of claim 8 , wherein the breast cancer is HER2-positive breast cancer.

10. The method of claim 8 , wherein the breast cancer is mediated by HER2, HER3, and/or EGFR.

11. A method of inhibiting cancer cell proliferation comprising administering to the subject in need thereof a therapeutically effective amount of a compound of claim 1 , or a salt thereof.

12. The method of claim 11 , wherein the cancer cell is HER2 mediated or a breast cancer cell.

13. The method of claim 12 , wherein the breast cancer cell is a HER2-positive breast cancer cell.

14. A method of inhibiting cancer cell metastasis comprising administering to the subject in need thereof a therapeutically effective amount of a compound of claim 1 , or a salt thereof.

15. A kit for treating a cell proliferative disorder, the kit comprising a compound of claim 1 , or a salt thereof, and instructions for use.

16. A pharmaceutical composition comprising a compound of claim 1 , or a salt thereof, and a pharmaceutically acceptable carrier.

17. The composition of claim 16 , further comprising an additional therapeutic agent.

18. The composition of claim 17 , wherein the additional therapeutic agent is lapatinib or trastuzumab.

19. A method of treating a subject suffering from cancer comprising administering to the subject in need thereof a therapeutically effective amount of a compound of claim 2 , or a salt thereof.

20. A method of inhibiting cancer cell proliferation comprising administering to the subject in need thereof a therapeutically effective amount of a compound of claim 2 , or a salt thereof.

Assignments (2)
CONFIRMATORY LICENSE Recorded Nov 16, 2020
From: UNIVERSITY OF FLORIDA
To: THE GOVERNMENT OF THE UNITED STATES, AS REPRESENTED BY THE SECRETARY OF THE ARMY
Reel/Frame 054421/0970 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 21, 2019
From: LAW, BRIAN KEITH; CASTELLANO, RONALD K.; FERREIRA, RENAN B.
To: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INCORPORATED
Reel/Frame 050115/0978 →
Continuity (2)
Provisional Application 62461734 · Feb 21, 2017
Related Publication 20200054592A1 · Feb 20, 2020