Highly contracted synthetic fibroin fiber, production method therefor, and method for contracting synthetic fibroin fiber
The present invention relates to a highly contracted artificial fibroin fiber including a modified fibroin, in which a contraction percentage defined by the following equation exceeds 7%. Contraction percentage={1−(length of contracted artificial fibroin fiber/length of artificial fibroin fiber before being brought into contact with water after spinning)}×100(%)
1. A method for producing a highly contracted artificial fibroin fiber, comprising:
a step of contracting an artificial fibroin fiber containing a modified fibroin by bringing the artificial fibroin fiber into contact with water below a boiling point, wherein:
the modified fibroin is a synthetically produced fibroin,
the modified fibroin is a protein including a domain sequence represented by Formula: [(A) n motif-REP] m , wherein (A) n motif indicates an amino acid sequence in which a percentage alanine residues is 40% or more with respect to the total number of amino acid residues, n is an integer of 2 to 20, REP represents an amino acid sequence consisting of 2 to 200 amino acid residues, m represents an integer of 2 to 300, a plurality of (A) n motifs is the same amino acid sequence or different amino acid sequences, and a plurality of REPs is the same amino acid sequence or different amino acid sequences,
the modified fibroin is a fibroin whose domain sequence is different from the amino acid sequence of naturally occurring fibroin, and
the modified fibroin has a contraction percentage defined by the following equation which exceeds 7%,
contraction percentage={1−(length of contracted artificial fibroin fiber/length of artificial fibroin fiber before being brought into contact with water after spinning)}×100(%).
2. The method for producing a highly contracted artificial fibroin fiber according to claim 1 , wherein the modified fibroin is a modified spider silk fibroin.
3. The method for producing a highly contracted artificial fibroin fiber according to claim 1 , wherein a temperature of the water is 10° C. to 90° C.
4. The method for producing a highly contracted artificial fibroin fiber according to claim 1 , wherein the step of contracting the artificial fibroin fiber further includes drying the artificial fibroin fiber after being brought into contact with the water.
5. A method for contracting an artificial fibroin fiber, comprising:
a step of contracting an artificial fibroin fiber containing a modified fibroin by bringing the artificial fibroin fiber into contact with water below a boiling point,
wherein:
the modified fibroin is a synthetically produced fibroin,
the modified fibroin is a protein including a domain sequence represented by Formula: [(A) n motif-REP] m , wherein (A) n motif indicates an amino acid sequence in which a percentage alanine residues is 40% or more with respect to the total number of amino acid residues, n is an integer of 2 to 20, REP represents an amino acid sequence consisting of 2 to 200 amino acid residues, m represents an integer of 2 to 300, a plurality of (A) n motifs is the same amino acid sequence or different amino acid sequences, and a plurality of REPs is the same amino acid sequence or different amino acid sequences,
the modified fibroin is a fibroin whose domain sequence is different from the amino acid sequence of naturally occurring fibroin, and
the modified fibroin has a contraction percentage defined by the following equation which exceeds 7%,
contraction percentage={1−(length of contracted artificial fibroin fiber/length of artificial fibroin fiber before being brought into contact with water after spinning)}×100(%),
6. The method for contracting an artificial fibroin fiber according to claim 5 , wherein the modified fibroin is a modified spider silk fibroin.
7. The method for contracting an artificial fibroin fiber according to claim 5 , wherein a temperature of the water is 10° C. to 90° C.
8. The method for contracting an artificial fibroin fiber according to claim 5 , wherein the step of contracting the artificial fibroin fiber further includes drying the artificial fibroin fiber after being brought into contact with the water.