Viscosity index improver and lubricating oil composition
A viscosity index improver containing a copolymer (A) whose essential constituent monomer is a monomer (a) having a number average molecular weight of 800 to 4,000 represented by the following formula (1), the copolymer (A) having a solubility parameter in the range of 9.00 to 9.40: wherein R 1 is a hydrogen atom or a methyl group; —X 1 — is a group represented by —O—, —O(AO) m —, or —NH—, AO is a C2-C4 alkyleneoxy group, m is an integer of 1 to 10, each AO may be the same or different when m is 2 or more, and the (AO) m moieties may be randomly bonded or block-bonded; R 2 is a residue after removal of one hydrogen atom from a hydrocarbon polymer whose essential constituent monomer is butadiene in which the butadiene is present in a proportion of 50% by weight or more based on the weight of R 2 , or after removal of one hydrogen atom from a polymer formed by partial hydrogenation of the hydrocarbon polymer; and p represents a number of 0 or 1.
1. A viscosity index improver comprising:
a copolymer (A) whose essential constituent monomer is a monomer (a) having a number average molecular weight of 800 to 4,000 represented by the following formula (1), the copolymer (A) having a solubility parameter in the range of 9.00 to 9.40:
wherein R 1 is a hydrogen atom or a methyl group; —X 1 — is a group represented by —O—, —O(AO) m —, or —NH—, AO is a C2-C4 alkyleneoxy group, m is an integer of 1 to 10, each AO may be the same or different when m is 2 or more, and the (AO) m moieties may be randomly bonded or block-bonded; R 2 is a residue after removal of one hydrogen atom from a hydrocarbon polymer whose essential constituent monomer is butadiene in which the butadiene is present in a proportion of 50% by weight or more based on the weight of R 2 , or after removal of one hydrogen atom from a polymer formed by partial hydrogenation of the hydrocarbon polymer; and p represents a number of 0 or 1, and
wherein in the formula (1), a structure derived from the butadiene constituting a part or all of R 2 has a 1,2-adduct/1,4-adduct molar ratio of 40/60 to 70/30.
2. The viscosity index improver according to claim 1 ,
wherein the molecular weight of copolymer segments per repeating unit of the monomer (a) as calculated by the following formula (1) is 2,500 to 11,000:
Molecular weight of copolymer segments per repeating unit= M×A/a (1)
where M is the weight average molecular weight of the monomer (a); a is the total weight of the monomer (a) constituting the copolymer (A); and A is the total weight of all monomers constituting the copolymer (A).
3. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) contains, as a constituent monomer, 10 to 50% by weight of the monomer (a) based on the weight of the copolymer (A).
4. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) has a weight average molecular weight of 5,000 to 2,000,000.
5. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) is a copolymer further containing an alkyl (meth)acrylate (b) having a C1-C4 alkyl group as a constituent monomer.
6. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) is a copolymer further containing a monomer (c) represented by the following formula (2) as a constituent monomer:
wherein R 3 is a hydrogen atom or a methyl group; —X 2 — is a group represented by —O— or —NH—; R 4 O is a C2-C4 alkyleneoxy group; R 5 is a C1-C8 alkyl group; and q is an integer of 1 to 20, each R 4 O may be the same or different when q is 2 or more, and the (R 4 O) q moieties may be randomly bonded or block-bonded.
7. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) is a copolymer further containing, as a constituent monomer, at least one of an alkyl (meth)acrylate (d) having a C12-C36 linear alkyl group or a monomer (e) represented by the following formula (3):
wherein R 6 is a hydrogen atom or a methyl group; —X 3 — is a group represented by —O— or —NH—; R 7 O is a C2-C4 alkyleneoxy group; R 8 and R 9 are each independently a C4-C24 linear alkyl group; and r is an integer of 0 to 20, each R 7 O may be the same or different when r is 2 or more, and the (R 7 O), moieties may be randomly bonded or block-bonded.
8. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) contains, as constituent monomers, 10 to 50% by weight of the monomer (a), 1 to 80% by weight of the following monomer (b), 0 to 60% by weight of the following monomer (c), 0 to 40% by weight of the following monomer (d), and 0 to 40% by weight of the following monomer (e), based on the weight of the copolymer (A):
monomer (b): alkyl (meth)acrylate having a C1-C4 alkyl group;
monomer (c): monomer represented by the following formula (2):
wherein R 3 is a hydrogen atom or a methyl group; —X 2 — is a group represented by —O— or —NH—; R 4 O is a C2-C4 alkyleneoxy group; R 5 is a C1-C8 alkyl group; and q is an integer of 1 to 20, each R 4 O may be the same or different when q is 2 or more, and the (R 4 O) q moieties may be randomly bonded or block-bonded;
monomer (d): alkyl (meth)acrylate having a C12-C36 linear alkyl group; and
monomer (e): monomer represented by the following formula (3),
wherein R 6 is a hydrogen atom or a methyl group; —X 3 — is a group represented by —O— or —NH—; R 7 O is a C2-C4 alkyleneoxy group; R 8 and R 9 are each independently a C4-C24 linear alkyl group; and r is an integer of 0 to 20, each R 7 O may be the same or different when r is 2 or more, and the (R 7 O), moieties may be randomly bonded or block-bonded.
9. The viscosity index improver according to claim 1 ,
wherein the copolymer (A) is a copolymer further containing at least one monomer selected from the group consisting of a nitrogen atom-containing monomer (f), a hydroxyl group-containing monomer (g), a phosphorus atom-containing monomer (h), and an aromatic ring-containing vinyl monomer (i).
10. The viscosity index improver according to claim 1 , further containing a (co)polymer (B) represented by the following formula (4), and the weight ratio (A)/(B) of the copolymer (A) to the (co)polymer (B) is 90/10 to 99.8/0.2:
wherein Z is a hydrogen atom, a methyl group, or a group represented by Y—X 4 —; Y is a hydrogen atom or a (meth)acryloyl group; —X 4 — is a C1-C10 alkylene group or a group represented by —O—, —O(AO) t —, or —NH—, AO is a C2-C4 alkyleneoxy group, t is an integer of 1 to 10, each AO may be the same or different when t is 2 or more, and the (AO) t moieties may be randomly bonded or block-bonded; and R 1 is a polymer of at least one monomer selected from the group consisting of a C2-C18 olefin, a C4-C10 alkadiene, and a C8-C17 styrene derivative, or when the polymer has an unsaturated group, R 10 is a residue after removal of one hydrogen atom from the polymer in which the unsaturated group is partially or completely hydrogenated; and s is a number of 0 or 1.
11. A lubricating oil composition comprising:
at least one base oil selected from the group consisting of API Group I to IV base oils, GTL base oils, and synthetic lubricant base oils; and
the viscosity index improver according to claim 1 ,
wherein the amount of the copolymer (A) in the lubricating oil composition is 0.1 to 20% by weight.
12. The lubricating oil composition according to claim 11 , further containing at least one additive selected from the group consisting of dispersants, detergents, antioxidants, oiliness improvers, pour point depressants, friction and wear modifiers, extreme pressure additives, defoamers, demulsifiers, metal deactivators, and corrosion inhibitors, in a total amount of 0.1 to 30% by weight.