Methods and uses for improving the performance of diesel engines using fuel additives
A diesel fuel composition comprising as an additive an ester compound which is the reaction product of an optionally substituted polycarboxylic acid or an anhydride thereof and an alcohol or formula ROH, wherein R is an optionally substituted hydrocarbyl group.
1. A diesel fuel composition comprising as an additive an ester compound which is the reaction product of an optionally substituted polycarboxylic acid or an anhydride thereof and an alcohol of formula ROH, wherein R is an optionally substituted hydrocarbyl group; and the additive includes compounds having the formula (C1) or (C2):
wherein R 1 is an optionally substituted alkyl or alkenyl group having 20 to 24 carbon atoms or a polyisobutenyl group having a number average molecular weight of from 240 to 5000.
2. A method of combatting deposits in a modern diesel engine having a high pressure fuel system, the method comprising combusting in the engine a diesel fuel composition comprising as an additive the reaction product of an optionally substituted polycarboxylic acid or an anhydride thereof and an alcohol of formula ROH, wherein R is an optionally substituted hydrocarbyl group.
3. The composition according to claim 1 wherein the optionally substituted polycarboxylic acid or anhydride thereof is a hydrocarbyl substituted succinic acid or a hydrocarbyl substituted succinic anhydride.
4. The composition according to claim 1 wherein R is an alkyl group having 6 to 36 carbon atoms.
5. The composition according to claim 1 wherein the polycarboxylic acid or anhydride thereof includes an optionally substituted alkyl or alkenyl group having 20 to 24 carbon atoms.
6. The composition according to claim 1 wherein the optionally substituted polycarboxylic acid or hydrocarbyl substituted anhydride and alcohol of formula ROH are reacted in a ratio of from 1.5:1 to 1:1.5.
7. The method according to claim 2 wherein the additive includes compounds having the formula (C1) or (C2):
8. The composition according to claim 1 wherein the additive comprises the reaction product of a succinic acid or anhydride of formula (A3) or (A4):
and an alcohol of formula ROH; wherein R is an unsubstituted alkyl group having 2 to 20 carbon atoms; and R 1 is an alkyl or alkenyl group having 20 to 24 carbon atoms or a polyisobutenyl group having a number average molecular weight of from 240 to 1300.
9. The composition according to claim 1 wherein the additive comprises the reaction product of a succinic acid or anhydride having a C 20 to C 24 alkyl or alkenyl substituent and an alcohol selected from the group consisting of butanol and 2-ethylhexanol.
10. The composition according to claim 1 wherein the additive includes compounds having the formula (E):
11. The method according to claim 2 which achieves “keep clean” performance.
12. The method according to claim 2 which achieves “clean up” performance.
13. The method according to claim 2 wherein the deposits are injector deposits.
14. The method according to claim 13 wherein the deposits are internal diesel injector deposits.
15. The composition according to claim 1 wherein the diesel fuel composition comprises less than 50 ppm sulphur by weight.
16. The composition according to claim 1 wherein the diesel fuel composition comprises biodiesel.
17. The composition according to claim 1 wherein the diesel fuel composition comprises one or more further detergents selected from the group consisting of:
(i) a quaternary ammonium salt additive;
(ii) the product of a Mannich reaction between an aldehyde, an amine and an optionally substituted phenol;
(iii) the reaction product of a carboxylic acid-derived acylating agent and an amine;
(iv) the reaction product of a carboxylic acid-derived acylating agent and hydrazine;
(v) a salt formed by the reaction of a carboxylic acid with di-n-butylamine or tri-n-butylamine;
(vi) the reaction product of a hydrocarbyl-substituted dicarboxylic acid or anhydride and an amine compound or salt which product comprises at least one amino triazole group; and
(vii) a substituted polyaromatic detergent additive.
18. The composition according to claim 1 wherein the diesel fuel composition comprises a mixture of two or more ester additives.
19. The method according to claim 2 which achieves an improvement in performance of one or more of:
a reduction in power loss of the engine;
a reduction in external diesel injector deposits;
a reduction in internal diesel injector deposits;
an improvement in fuel economy;
a reduction in fuel filter deposits;
a reduction in emissions; or
an increase in maintenance intervals.
20. The method according to claim 19 which provides an improvement in performance in modern diesel engines having a high pressure fuel system and provides an improvement in performance in traditional diesel engines.
21. The composition according to claim 1 which further comprises one or more further additives selected from the group consisting of: lubricity improvers, corrosion inhibitors and cold flow improvers.