IP Library › Granted Patent US 11,453,767
Granted Patent B2
US 11,453,767 · App. 16/495,289 · Granted Sep 27, 2022

Propylene ethylene random copolymer

Inventors: Gabriele Mei (Channelview, TX); Antonio Mazzucco (Ferrara, IT); Tiziana Caputo (Ferrara, IT); Enrico Balestra (Ferrara, IT); Davide Tartari (Ferrara, IT); Gilberto Moscardi (Ferrara, IT)
Assignee: Basell Poliolefine Italia S.r.l.
C08L23/12C08L23/06C08F210/06C08L2207/06
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Quick Facts
Patent No.
US 11,453,767
App. No.
16/495,289
Granted
Sep 27, 2022
Kind
B2
Abstract

A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm> 155−1.4× C 2  (I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM> 1900−285× C 2+50× Xs   (II).

Claims (19)

1. A propylene ethylene copolymer having:

(i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer;

(ii)) a fraction soluble in xylene at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer;

(iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g;

(iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I):

Tm> 155−1.4× C 2  (I),

wherein Tm is the melting point of the propylene ethylene copolymer measured by DSC and C2 is the wt % of ethylene derived units of the propylene ethylene copolymer, based upon the total weight of the copolymer; and

(v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II)

TM> 1900−285× C 2+50× Xs   (II),

wherein TM is the flexural modulus in MPA, C2 is the wt % of ethylene derived units of the propylene ethylene copolymer, based upon the total weight of the copolymer, and Xs is the fraction soluble in xylene at 25° C. (wt %) of the propylene ethylene copolymer, based upon the total weight of the copolymer.

2. The propylene ethylene copolymer according to claim 1 having a melt flow rate MFR, (ISO 1133 (230° C., 2.16 kg) ranging from 0.2 g/10 min to 100 g/10 min.

3. The propylene ethylene copolymer according to claim 1 having the ethylene derived units content ranging from 3.3 wt % to 10.2 wt %, based upon the total weight of the copolymer.

4. The propylene ethylene copolymer according to claim 1 , wherein the fraction soluble in xylene at 25° C. ranges from 8.2 wt % to 25.3 wt %, based upon the total weight of the copolymer.

5. The propylene ethylene copolymer according to claim 1 , wherein the intrinsic viscosity of the fraction soluble in xylene at 25° C. ranges from 3.5 dl/g to 5.2 dl/g.

6. The propylene ethylene copolymer according to claim 1 , wherein relation (I) is Tm>156−1.4×C2.

7. The propylene ethylene copolymer according to claim 1 , wherein relation (II) is TM>1920−285×C2+50×Xs.

8. The propylene ethylene copolymer according to claim 1 having the ethylene derived units content ranging from 3.8 wt % to 9.2 wt %, based upon the total weight of the copolymer.

9. The propylene ethylene copolymer according to claim 1 , wherein the fraction soluble in xylene at 25° C. ranges from 9.1 wt % to 22.0 wt %, based upon the total weight of the copolymer.

10. The propylene ethylene copolymer according to claim 1 , wherein the intrinsic viscosity of the fraction soluble in xylene at 25° C. ranges from 3.7 dl/g to 5.0 dl/g.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 4, 2020
From: MEI, GABRIELE; MAZZUCCO, ANTONIO; CAPUTO, TIZIANA; BALESTRA, ENRICO; TARTARI, DAVIDE; MOSCARDI, GILBERTO
To: BASELL POLIOLEFINE ITALIA S.R.L.
Reel/Frame 053697/0435 →
Priority Claims (1)
EP 17162952 · Mar 27, 2017 · regional
Continuity (1)
Related Publication 20200032041A1 · Jan 30, 2020
Cited By (1)
US 12,187,880