Multi-layered structures and uses thereof

1. A vulcanized article comprising:

a cured rubber layer; and

a core layer having a first side and a second side, wherein the core layer is a composite of alternating TPU microlayers and ethylene-vinyl alcohol copolymer barrier microlayers; and

a first cap layer, the first cap layer having a cap layer first side and a cap layer second side, the first side of the first cap layer being in direct contact with the first side of the core layer;

wherein the first cap layer comprises a blended material comprising at least one thermoplastic material and at least one rubber compound,

wherein the at least one thermoplastic material comprises a polydiene polyol-based thermoplastic polyurethane (TPU) and wherein the at least one rubber compound is cured or partially cured,

wherein the cured rubber layer is disposed directly on the cap layer second side of the first cap layer, wherein the cured rubber layer is bonded to and crosslinked with the cap layer on the cap layer second side.

2. The multi-layered structure of claim 1 , wherein the polydiene polyol-based TPU comprises at least one hard segment and at least one soft segment, the TPU having a hard segment content and a soft segment content, wherein the hard segment content is about 20 wt. % to about 50 wt. % and the soft segment content is about 50 wt. % to about 80 wt. %.

3. The multi-layered structure of claim 2 , wherein the soft segment comprises a poly-(C1-C6)-hydroxyl-terminated diol.

4. The multi-layered structure of claim 2 , wherein the soft segment comprises a hydroxyl-terminated diol based on a homopolymer of butadiene.

5. The multi-layered structure of claim 2 , wherein the soft segment comprises a vinyl content of from about 30 wt. % to about 80 wt %.

6. The multi-layered structure of claim 2 , wherein the hard segment comprises —(C6-C18)-arylene-(C1-C6)-alkylene-(C6-C18)-arylene segments.

7. The multi-layered structure of claim 2 , wherein the hard segment comprises —(C6-C10)-arylene-(C1-C3)-alkylene-(C6-C10)-arylene segments.

8. The multi-layered structure of claim 2 , wherein the hard segment comprises -phenylene-methylene-phenylene segments.

9. The multi-layered structure of claim 1 , wherein the first cap layer comprises about 20 wt. % to about 80 wt. % of the at least one thermoplastic material; and about 20 wt. % to about 80 wt. % of the at least one rubber compound.

10. The multi-layered structure of claim 1 , wherein the first cap layer further comprises a tackifier.

11. The multi-layered structure of claim 10 , wherein the first cap layer comprises less than about 40 wt. % tackifier.

12. The multi-layered structure of claim 1 , wherein the multi-layered structure of a given thickness has a gas transmission rate for nitrogen that is at least about ten times lower than the gas transmission rate for nitrogen of a butyl rubber layer of substantially the same thickness as the thickness of the multi-layered structure.

13. The multi-layered structure of claim 1 , wherein the gas transmission rate of at least one of the core layer and the multi-layered structure is about 0.001 cm 3 /m 2 ·atm·day to about 1 cm 3 /m 2 ·atm·day.

14. The multi-layered structure of claim 1 , wherein a peel strength of the first cap layer to a thermoplastic polyurethane (TPU) substrate is about 2 N/mm to about 6 N/mm or the peel strength of the cap layer to the rubber substrate is about 1 N/mm to about 3 N/mm.

15. The multi-layered structure of claim 1 , wherein the rubber compound is a natural rubber, a synthetic rubber, or a combination of both.

16. The multi-layered structure of claim 1 , wherein the rubber compound is natural rubber, butyl rubber, neoprene rubber, nitrile rubber, isoprene rubber, butadiene rubber, styrene-butadiene rubber, ethylene propylene diene monomer (EPDM) rubber, ethylene-propylene rubber, urethane rubber or any combination thereof.

17. The multi-layered structure of claim 1 , wherein the rubber compound is an isoprene rubber, a butyl rubber, a butadiene rubber, a styrene-butadiene rubber or any combination thereof.

18. The multi-layered structure of claim 1 , wherein the rubber compound is styrene-butadiene rubber.

19. The multi-layered structure of claim 1 , further comprising a second cap layer having a second cap layer first side and a second cap layer second side, the second cap layer first side being in direct contact with the second side of the core layer, wherein the second cap layer second side is bonded on the first side to a thermoplastic polymer substrate.

20. The multi-layered structure of claim 1 , wherein the multi-layer polymeric material comprises alternating layers of a first thermoplastic material and a second thermoplastic material, wherein a layer of the second thermoplastic material has a lower nitrogen gas permeability than a layer of the first thermoplastic material.

21. The multi-layered structure of claim 20 , wherein the layer of the second thermoplastic material has an average thickness of about 0.1 microns to about 50 microns.

22. The multi-layered structure of claim 1 , wherein the multi-layer polymeric material comprises alternating polyester polyol-based TPU layers and ethylene-vinyl alcohol copolymer layers.

23. The multi-layered structure of claim 1 , wherein the multi-layered polymeric material further comprises structural layers formed of repurposed polymeric materials.

24. The multi-layered structure of claim 1 , wherein at least one of the first side of the core layer and the second side of the core layer comprise a polydiene polyol-based TPU.

25. The multi-layered structure of claim 1 , wherein the TPU of the TPU microlayers of the core is made using polyether polyols, polyester polyols, polycarbonate polyols, polycapralactone polyols, or any combination thereof.

26. The multi-layered structure of claim 1 , wherein the blended material comprises about 20 weight percent to about 80 weight percent of the polydiene polyol-based TPU.

27. The multi-layered structure of claim 1 , wherein the blended material comprises about 20 weight percent to about 80 weight percent of the cured or partially cured rubber.

28. The vulcanized article of claim 1 , wherein the vulcanized article is an article of footwear.