IP Library Granted Patent US 11,193,190
Granted Patent B2
US 11,193,190 · App. 16/510,524 · Granted Dec 7, 2021

Low-cost cast creep-resistant austenitic stainless steels that form alumina for high temperature oxidation resistance

Inventors: Philip J Maziasz (Oak Ridge, TN); Govindarajan Muralidharan (Knoxville, TN); Bruce A. Pint (Knoxville, TN); Kinga A. Unocic (Knoxville, TN); Ying Yang (Farragut, TN)
Assignee: UT-BATTELLE, LLC
C22C38/42C22C38/06C22C38/34C22C38/38C22C38/44C22C38/48
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Quick Facts
Patent No.
US 11,193,190
App. No.
16/510,524
Granted
Dec 7, 2021
Kind
B2
Abstract

An air castable Fe-based stainless steel alloy comprises in weight % based on the total weight of the alloy 18-22% Cr, 15-22% Ni, 3-6% Al, 0.5-5% Mn, 0-3.5% W, 0-5% Cu, 0-2% Si, 1-2.5% Nb, 0.3-0.6% C balance Fe wherein, Cu+W+Si=0.5-10.5, and the alloy provides an oxidation resistance of 0.5<specific mass change<+2 mg/cm 2 after 400 one hour cycles at 900° C. in 10% water vapor.

Claims (26)

1. An air castable Fe-based stainless steel alloy comprising in weight % based on the total weight of the alloy:

18-22% Cr

15-22% Ni

3.25-6% Al

0.5-5% Mn

1.05-3.5% W

3.05-5% Cu

0-2% Si

1-2.5% Nb

0.3-0.6% C

<0.1% N

balance Fe

wherein, Cu+W+Si=4.1-10.5%, and the alloy provides an oxidation resistance of −2<mass change <+2 mg/cm 2 after 300 one hour cycles at 950° C. in 10% water vapor.

2. The alloy of claim 1 , further comprising 0-2% Ta.

3. The alloy of claim 2 , wherein Ta+Nb<4.0%.

4. The alloy of claim 2 , wherein Ta/Nb=0-0.75.

5. The alloy of claim 1 , further comprising 0.1-5.0% Co.

6. The alloy of claim 1 , wherein the alloy is non-magnetic and free of alpha or delta ferrite phases, and does not form a thermal or strain induced martensite phase.

7. The alloy of claim 1 , wherein the Cu/W ratio is 0.87-1.67.

8. The alloy of claim 1 , wherein Nb/C is from 2-5.

9. The alloy of claim 1 , wherein Cr/Al is 4.7-6.77.

10. The alloy of claim 1 , wherein the Cr/(Al+Si) ratio is 2.25-6.15.

11. The alloy of claim 1 , wherein the alloy provides an oxidation resistance of −0.5<mass change <+2 mg/cm 2 after 400 one hour cycles at 900° C. in 10% water vapor.

12. The alloy of claim 1 , wherein the alloy provides creep rupture resistance of 863 hours at 950° C., 35 MPa and 469 hours at 1050° C., 10 MPa.

13. The alloy of claim 1 , wherein the alloy provides a yield strength of 41.6 Ksi and tensile strength of 84.1 Ksi at room temperature.

14. The alloy of claim 1 , wherein the alloy provides an elongation of 11.1% at room temperature and 39% at 1000° C.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2021
From: MAZIASZ, PHILIP J.; MURALIDHARAN, GOVINDARAJAN; PINT, BRUCE A.; UNOCIC, KINGA A.; YANG, YING
To: UT-BATTELLE, LLC
Reel/Frame 057893/0322 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PROPERTY NUMBER PREVIOUSLY RECORDED AT REEL: 050509 FRAME: 0538. ASSIGNOR(S) HEREBY CONFIRMS THE EXECUTIVE ORDER. Recorded Sep 30, 2019
From: UT-BATTELLE, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 050591/0830 →
CONFIRMATORY LICENSE Recorded Sep 27, 2019
From: UT-BATTELLE, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 050509/0538 →
Continuity (3)
Continuation In Part 16258526 · Jan 25, 2019
Provisional Application 62621638 · Jan 25, 2018
Related Publication 20190330723A1 · Oct 31, 2019