Thermal interface material assemblies and systems and methods for controllably changing surface tack of thermal interface materials

1. A thermal interface material assembly comprising a thermal interface material having first and second surfaces, a first coating along the first surface of the thermal interface material, and a second coating along the second surface of the thermal interface material, wherein:

the thermal interface material comprises thermally-conductive filler;

the first coating decreases the surface tack of the first surface of the thermal interface material to a first level less than the surface tack of the underlying thermal interface material;

the second coating increases the surface tack of the second surface of the thermal interface material to a second level more than the surface tack of the underlying thermal interface material; and

the first coating is chemically bonded or is configured to be chemically bonded to the thermal interface material via cross linking of the first coating with the thermal interface material.

2. The thermal interface material assembly of claim 1 , wherein the first coating is chemically bonded to the thermal interface material via a reaction including cross linking of polymer chains of the first coating and polymer chains of the thermal interface material.

3. The thermal interface material assembly of claim 1 , wherein the first coating comprises a silicon-hydrogen functional group cross-linker.

4. The thermal interface material assembly of claim 1 , wherein the first coating includes a one-part and/or two-part silane composition.

5. The thermal interface material assembly of claim 1 , wherein the second coating comprises a two-part silane composition.

6. The thermal interface material assembly of claim 1 , wherein:

the first coating includes polysiloxane; and/or

the first coating includes silicon hydrogen functional groups and vinyl functional groups.

7. The thermal interface material assembly of claim 1 , wherein the first coating comprises methyl vinyl silane, a platinum catalyzer, a coupling agent, and a silicon-hydrogen functional group cross-linker.

8. The thermal interface material assembly of claim 1 , wherein:

the thermal interface material comprises a first silicone and the thermally-conductive filler;

the first coating comprises a second silicone; and

the first coating is chemically bonded to the thermal interface material via a reaction including cross linking of polymer chains of the respective thermal interface material and the first coating.

9. The thermal interface material assembly of claim 1 , wherein the first coating comprises a one-part silane composition having a viscosity less than 400 centipoises.

10. The thermal interface material assembly of claim 9 , wherein the first coating further comprises a two-part silane composition having a viscosity from 400 centipoises to 2000 centipoises.

11. The thermal interface material assembly of claim 10 , wherein:

the one-part silane composition has a number average molecular weight less than 10000; and

the two-part silane composition has a number average molecular weight from 10000 to 30000.

12. The thermal interface material assembly of claim 9 , wherein the first coating further comprises a two-part silane composition having a viscosity greater than 2000 centipoises.

13. The thermal interface material assembly of claim 12 , wherein:

the one-part silane composition has a number average molecular weight less than 10000; and

the two-part silane composition has a number average molecular weight greater than 30000.

14. The thermal interface material assembly of claim 1 , wherein:

the first coating is directly on the first surface of the thermal interface material; and

the second coating is directly on the second surface of the thermal interface material.

15. The thermal interface material assembly of claim 1 , further comprising a first liner, and wherein the first coating is between the first surface of the thermal interface material and an inner surface of the first liner, whereby the first coating is configured such that at least a portion of the first coating will remain along the first surface of the thermal interface material after removal of the first liner from the thermal interface material assembly to thereby decrease the surface tack of the first surface of the thermal interface material.

16. The thermal interface material assembly of claim 1 , wherein:

the thermal interface material comprises a first silicone and the thermally-conductive filler;

the first coating comprises a second silicone; and

the second coating comprises a third silicone.

17. The thermal interface material assembly of claim 16 , further comprising a first liner and a second liner, wherein:

the first coating is between the first surface of the thermal interface material and an inner surface of the first liner, whereby the first coating is configured such that at least a portion of the first coating will remain along the first surface of the thermal interface material after removal of the first liner from the thermal interface material assembly to thereby decrease the surface tack of the first surface of the thermal interface material; and

the second coating is between the second surface of the thermal interface material and an inner surface of the second liner, whereby the second coating is configured such that at least a portion of the second coating will remain along the second surface of the thermal interface material after removal of the second liner from the thermal interface material assembly to thereby increase the surface tack of the second surface of the thermal interface material.

18. The thermal interface material assembly of claim 1 , further comprising a first liner and a second liner, wherein:

the first coating is between the first surface of the thermal interface material and an inner surface of the first liner, whereby the first coating is configured such that at least a portion of the first coating will remain along the first surface of the thermal interface material after removal of the first liner from the thermal interface material assembly to thereby decrease the surface tack of the first surface of the thermal interface material; and

the second coating is between the second surface of the thermal interface material and an inner surface of the second liner, whereby the second coating is configured such that at least a portion of the second coating will remain along the second surface of the thermal interface material after removal of the second liner from the thermal interface material assembly to thereby increase the surface tack of the second surface of the thermal interface material.

19. The thermal interface material assembly of claim 18 , wherein:

the first liner comprises a first polyethylene terephthalate liner;

the second liner comprises a second polyethylene terephthalate liner; and

the thermal interface material comprises a thermally-conductive gap filler sheet material-having the first surface with the surface tack decreased by the first coating and the second surface with the surface tack increased by the second coating.

20. The thermal interface material assembly of claim 1 , wherein the thermal interface material comprises a thermally-conductive gap filler sheet material having the first surface with the surface tack decreased by the first coating.