Electrically actuated switch
An electrically actuated switch comprises a first electrode, a second electrode, and an active region disposed therebetween. The active region comprises at least one primary active region comprising at least one material that can be doped or undoped to change its electrical conductivity, and a secondary active region comprising at least one material for providing a source/sink of ionic species that act as dopants for the primary active region(s). Methods of operating the switch are also provided.
1. A solid-state switch, comprising:
a first electrode;
a second electrode;
a first semiconducting-ionic-conductor layer situated adjacent to the first electrode, wherein an electrical conductivity of the first semiconducting-ionic-conductor layer has an initial first value when undoped;
a dopant source layer situated between the first semiconducting-ionic-conductor layer and the second electrode, wherein the dopant source layer is to, in response to a bias voltage across the first and second electrodes, provide dopants to the first semiconducting-ionic-conductor layer to increase the electrical conductivity of the first semiconducting-ionic-conductor layer to a second value that is higher than the initial first value, thereby switching the solid-state switch from a first resistance state to a second resistance state; and
a second semiconducting-ionic-conductor layer situated between the dopant source layer and the second electrode, wherein the dopant source layer is to, in response to a bias voltage across the first and second electrodes, provide dopants to the first or second semiconducting-ionic-conductor layer, depending on a polarity of the bias voltage thereby setting an on/off polarity of the solid-state switch.
2. The solid-state switch of claim 1 , further comprising a molecular layer positioned between the first semiconducting-ionic-conductor layer and the first electrode.
3. The solid-state switch of claim 2 , wherein the molecular layer comprises an inert material.
4. The solid-state switch of claim 1 , wherein the first or second electrode comprises Pt.
5. The solid-state switch of claim 1 , wherein the dopants provided by the dopant source layer are selected from the group consisting of: ionized interstitial or substitutional impurity atoms, cation donor species, anion vacancies, and anionic acceptor species.
6. The solid-state switch of claim 1 , wherein the dopants provided by the dopant source layer are selected from the group consisting of: hydrogen, alkali and alkaline earth cations, transition metal cations, rare earth cations, oxygen anions or vacancies, chalcogenide anions or vacancies, nitrogen anions or vacancies, pnictide anions or vacancies, or halide anions or vacancies.
7. The solid-state switch of claim 1 , wherein the first semiconducting-ionic-conductor layer or the dopant source layer comprises at least one material selected from the group consisting of: oxides, sulfides, selenides, nitrides, phosphides, arsenides, chlorides, and bromides of transition metals, rare earth metals, and alkaline earth metals.
8. The solid-state switch of claim 7 , wherein the first semiconducting-ionic-conductor layer or the dopant source layer comprises one or more of: Ti, Zr, and Hf.
9. The solid-state switch of claim 7 , wherein the first semiconducting-ionic-conductor layer and the dopant source layer comprise a material combination selected from the group consisting of:
TiO2/TiO2-x;
ZrO2/ZrO2-x;
HfO2/HfO2-x;
SrTiO3/SrTiO3-x;
GaN/GaN1-x;
CuCl/CuCl1-x; and
GaN/GaN:S.