Electronic devices having corrosion-resistant coatings
An electronic device such as a wristwatch may include a conductive housing. A corrosion-resistant coating may be deposited on the conductive housing. The coating may include transition layers and an uppermost alloy layer. The transition layers may include a chromium seed layer on the conductive housing and a chromium nitride layer on the chromium seed layer. The uppermost alloy layer may include TiCrCN or other alloys and may provide the coating with desired optical reflection and absorption characteristics. The transition layers may include a minimal number of coating defects, thereby eliminating potential sites at which visible defects could form when exposed to salt water. This may allow the electronic device to exhibit a desired color and to be submerged in salt water without producing undesirable visible defects on the conductive housing structures.
1. An electronic device, comprising:
a conductive housing structure; and
a coating on the conductive housing structure, the coating comprising:
a chromium seed layer on the conductive housing structure,
a chromium nitride layer on the chromium seed layer, and
a TiCrCN layer on the chromium nitride layer.
2. The electronic device defined in claim 1 , wherein the TiCrCN layer is an uppermost layer of the coating.
3. The electronic device defined in claim 1 , further comprising an antismudge layer on the TiCrCN layer.
4. The electronic device defined in claim 1 , wherein the conductive housing structure comprises stainless steel having an inclusion count less than 75 per 10,000 square microns.
5. The electronic device defined in claim 1 , wherein the electronic device has opposing front and rear faces, the electronic device further comprising:
a display at the front face, wherein the conductive housing structure comprises a conductive wall at the rear face.
6. The electronic device defined in claim 1 , wherein the coating has a total thickness between 1.0 micron and 2.0 microns.
7. The electronic device defined in claim 6 , wherein the TiCrCN layer has a first thickness, the chromium nitride layer has a second thickness greater than the first thickness, and the chromium seed layer has a third thickness less than the first thickness.
8. The electronic device defined in claim 1 , wherein the TiCrCN layer has a molar % of nitrogen between 25% and 35%, a molar % of carbon between 10% and 25%, and a molar % of chromium between 1% and 10%.
9. An electronic device comprising:
a display;
a conductive housing wall; and
a coating on the conductive housing wall that configures the conductive housing wall to exhibit a given color, the coating comprising:
a chromium seed layer on the conductive housing wall,
a transition layer on the chromium seed layer, the transition layer comprising chromium, and
an uppermost alloy layer comprising nitrogen.
10. The electronic device defined in claim 9 , wherein the transition layer comprises a chromium nitride layer.
11. The electronic device defined in claim 10 , wherein the uppermost alloy layer comprises a TiCrCN layer.
12. The electronic device defined in claim 10 , wherein the uppermost alloy layer comprises a CrCN layer.
13. The electronic device defined in claim 10 , wherein the uppermost alloy layer comprises a TiAlN layer.
14. The electronic device defined in claim 10 , wherein the uppermost alloy layer comprises a TiAlCrN layer.
15. The electronic device defined in claim 10 , wherein the uppermost alloy layer comprises a TiCN layer and the coating further comprises a titanium layer interposed between the chromium nitride layer and the TiCN layer.
16. The electronic device defined in claim 9 , wherein the transition layer comprises a CrSi layer, the uppermost alloy layer comprises a CrSiCN layer, and the coating further comprises a CrSiN layer interposed between the CrSi layer and the CrSiCN layer.
17. The electronic device defined in claim 9 , wherein the transition layer comprises a CrC layer and the uppermost alloy layer comprises a CrCN layer.
18. An electronic device, comprising:
a stainless steel housing structure;
a corrosion-resistant coating on the stainless steel housing structure, wherein the corrosion-resistant coating comprises a chromium nitride layer and an uppermost coloring layer; and
an oleophobic coating on the corrosion-resistant coating.