Method for dispersion of nanocellulose in melt-processed polymers

1. A method of preparing a substantially homogeneous nanocellulose-dispersed organic hydrophobic polymer composition, wherein the method comprises:

a) preparing a nanocellulose solution with a first solvent;

b) preparing an organic additive solution with a second solvent, wherein the second solvent is capable of being a common solvent for said nanocellulose and said additive, and the first and the second solvent may be same or different, wherein the organic additive is selected from the group consisting of polyethylene glycol (PEG), sugars, natural acids, phthalate ester, dicarboxylic acid esters, phosphate esters, sulfonamides, benzoates, glycerides, any derivative thereof, or any combination thereof;

c) mixing the nanocellulose solution and the organic additive solution to provide a solution mixture of said nanocellulose and said organic additive;

d) removing said first solvent and said second solvent from said solution mixture under vacuum condition and at a temperature of at least 50° C. to provide a substantially solvent free composition comprising said nanocellulose and said organic additive; and

e) melt-compounding said substantially solvent free composition comprising said nanocellulose and said organic additive with an organic hydrophobic polymer to provide a substantially homogeneous polymer composition comprising said nanocellulose, said organic additive, and said organic hydrophobic polymer, wherein said organic hydrophobic polymer comprises polylactic acid (PLA), Poly(Lactide-co-Glycolide) (PGLA), polycaprolactone, polyhyroxyalkanoates, ethylene vinyl alcohol (EVOH), Poly(hexano-6-lactam) (Nylon 6), Poly[imino(1,6-dioxohexamethylene) iminohexamethylene] (Nylon 66), Poly(11-aminoundecanoicacid) (Nylon 11), Poly(dodecano-12-lactam) (Nylon 12), Poly(methyl methacrylate) (PMMA), polystyrene, Acrylonitrile butadiene styrene (ABS), Polyacrylonitrile (PAN), Polyvinyl chloride (PVC), any derivative thereof, or any combination thereof.

2. The method of claim 1 , wherein the nanocellulose comprises cellulose nanofibrils (CNFs), cellulose nanocrystals (CNCs), or a combination thereof.

3. The method of claim 1 , wherein said first and said second solvent are both water.

4. The method of claim 1 , wherein said first solvent is water, said second solvent is a water soluble organic solvent.

5. The method of claim 4 , wherein said second solvent comprises alcohols, ketones, esters, ethers, acetonitrile, or any combination thereof.

6. The method of claim 5 , wherein said first solvent is water, said second solvent is a straight or branched C 1 -C 5 alcohol, acetone, ethyl acetate, tetrahydrofuran, acetonitrile, or any combination thereof.