IP Library › Granted Patent US 10,859,935
Granted Patent B2
US 10,859,935 · App. 16/550,452 · Granted Dec 8, 2020

Toner

Inventors: Takeshi Ohtsu (Toride, JP); Tadashi Fukuda (Tokyo, JP); Mikihiro Akasaki (Matsudo, JP); Akinori Miyamoto (Bando, JP); Kota Mori (Abiko, JP); Masami Hano (Abiko, JP); Takashi Kase (Tokyo, JP); Daisuke Tsujimoto (Tokyo, JP); Ryuichiro Matsuo (Moriya, JP); Kazuto Hosoi (Abiko, JP); Yoshihiro Ogawa (Toride, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/09716G03G9/0819G03G9/0823G03G9/08755G03G9/097G03G9/09708
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Quick Facts
Patent No.
US 10,859,935
App. No.
16/550,452
Granted
Dec 8, 2020
Kind
B2
Abstract

A toner includes toner particle containing at least a strontium titanate particle on the surface of the toner particle, and the toner is a water-washed toner from which strontium titanate particle desorbable by water washing are removed by water washing. The water-washed toner contains the strontium titanate particle having a number average particle diameter of primary particle (D1) of 10 nm or more and 150 nm or less, and when the distribution of an Sr element in the water-washed toner in the depth direction is determined, (i) the Sr element abundance on the outermost surface x satisfying 0.00<x≤0.80, and (ii) the difference between x and xp “xp−x” satisfying 0.00<xp−x≤0.95, where xp is the maximum peak value (atomic %) of the Sr element abundance in the region from the outermost surface to 50 nm.

Claims (12)

1. A toner, comprising:

a toner particle containing a binder resin and a colorant; and

a strontium titanate particle on a surface of the toner particle, wherein

when the toner is washed by water in order to remove a strontium titanate particle desorbable to obtain a water-washed toner, the water-washed toner contains the strontium titanate particle having a number average particle diameter of primary particle of 10 to 150 nm, and

when a distribution of an Sr element derived from strontium titanate in the water-washed toner in a depth direction is determined, 0.00<x≤0.80 when x (atomic %) is an Sr element abundance on an outermost surface, the distribution has at least one peak of the Sr element abundance in a region from the outermost surface to 50 nm, and 0.00<xp−x≤0.95 when xp (atomic %) is an Sr element abundance at a maximum peak in the region from the outermost surface to 50 nm in the distribution.

2. The toner according to claim 1 , wherein the toner contains the strontium titanate particle at 0.5 to 10.0% by mass.

3. The toner according to claim 1 , wherein a fixing rate of the strontium titanate particle in the toner is 55 to 95% by mass.

4. The toner according to claim 1 , wherein xp (atomic %) is 0.05≤xp≤0.95.

5. The toner according to claim 1 , wherein the strontium titanate particle contained in the water-washed toner has a number average particle diameter of primary particle of 25 to 45 nm.

6. The toner according to claim 1 , wherein a surface of the strontium titanate particle is hydrophobically treated.

7. The toner according to claim 6 , wherein the surface of the strontium titanate particle is hydrophobically treated with a fluorine silane coupling agent.

8. The toner according to claim 1 , wherein the strontium titanate particle has a volume resistivity of 2×10 9 to 2×10 13 Ω·cm.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 27, 2020
From: OHTSU, TAKESHI; FUKUDA, TADASHI; AKASAKI, MIKIHIRO; MIYAMOTO, AKINORI; MORI, KOTA; HANO, MASAMI; KASE, TAKASHI; TSUJIMOTO, DAISUKE; MATSUO, RYUICHIRO; HOSOI, KAZUTO; OGAWA, YOSHIHIRO
To: CANON KABUSHIKI KAISHA
Reel/Frame 051701/0138 →
Priority Claims (2)
JP 2018-159788 · Aug 28, 2018 · national
JP 2018-247559 · Dec 28, 2018 · national
Continuity (1)
Related Publication 20200073266A1 · Mar 5, 2020
Cited By (9)
US 12,228,882 US 12,242,226 US 12,429,791 US 12,613,478 US 12,638,789 US 12,663,736 US 12,675,060 US 12,687,796 US 12,736,890