Boronic acid monomers and methods of making boronic acid monomers
Boronic acid monomers, methods of making boronic acid monomer, and the like, are provided. Embodiments of the present disclosure are advantageous in that the boronic acid monomers are water soluble at a neutral pH, which is uncommon for boronic acids. As a result, the boronic acid monomers can be used in aqueous polymerization reactions with other hydrophilic monomers to yield polymers including boronic acids and esters.
1. A composition comprising: a monomer:
wherein Z is a polymerizable group, wherein the polymerizable group is selected from: an acrylamide group, a methacrylamide group, an acrylate group, a methacrylate group, N-carboxyanhydride group, a N-thiocarboxyanhydride group, a norbornene group, or an oxynorbornene group.
2. The composition of claim 1 , wherein the monomer is selected from the following:
wherein R is H or an alkyl group, wherein X is O, NH, or N(alkyl), and n is 0 to 4.
3. The composition of claim 1 , wherein the monomer is:
wherein the polymerizable group is selected from: an acrylamide group, a methacrylamide group, an acrylate group, or a methacrylate group.
4. The composition of claim 1 , wherein the monomer is:
wherein the polymerizable group is selected from: N-carboxyanhydride group or a N-thiocarboxyanhydride group.
5. The composition of claim 1 , wherein the monomer is:
wherein the polymerizable group is selected from: a norbornene group, or an oxynorbornene group.
6. A composition comprising: a monomer:
wherein R is H or an alkyl group, wherein X is O, NH, or N(alkyl), and n is 0 to 4.