Method of manufacturing SiC single crystal and covering member
A method of manufacturing a SiC single crystal includes: a storing step of storing a SiC source, which is a powder, in an inner bottom part of a crucible, wherein the crucible is configured to store the SiC source and to attach a seed crystal to a position of the crucible which faces the SiC source; a placing step of placing a porous material on at least a portion of a first surface of the SiC source, wherein the first surface is positioned on a side of the seed crystal; and a crystal growth step of sublimating the SiC source by heating to grow a crystal on the seed crystal, in which the porous material is formed of carbon or a carbide, and the hole diameter of the porous material is smaller than the average particle diameter of the SiC source.
1. A method of manufacturing a SiC single crystal, comprising:
a storing step of storing a SiC source which is a powder in an inner bottom part of a crucible, wherein the crucible is also configured to attach a seed crystal to a position of the crucible which faces the SiC source;
a placing step of placing a porous material on at least a portion of a first surface of the SiC source, wherein the first surface is positioned on a side of the seed crystal; and
a crystal growth step of sublimating the SiC source by heating to grow the SiC single crystal on the seed crystal,
wherein the porous material is a compact sintered body in which holes have been formed,
the porous material has a face A on the side of the seed crystal and a face B on a side of the SiC source, and has a plurality of holes communicating with the face B from the face A in a thickness direction of the porous material,
a hole diameter of the holes of the porous material is 70% or less of an average particle diameter of powder particles which form the SiC source,
the porous material consists of a SiC sintered body, and
the hole diameter of the holes is constant in the thickness direction of the porous material.
2. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein the porous material covers 70% or more of the first surface of the SiC source.
3. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein the porous material has an opening at a center thereof, and
the porous material covers an outer side of the first surface of the SiC source.
4. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein a thickness of the porous material is smaller than 40% of a height of the stored SiC source.
5. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein a whole of the first surface of the SiC source is covered with the porous material.
6. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein the hole diameter of the holes is 60% or less of the average particle diameter of the powder particles which form the SiC source.
7. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein porosity of the porous material is 40% or more and 60% or less.
8. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein porosity of the porous material is 45% or more and 50% or less.
9. The method of manufacturing a SiC single crystal according to claim 1 ,
wherein the hole is formed perpendicular to the face A and the face B.