IP Library Granted Patent US 10,988,645
Granted Patent B1
US 10,988,645 · App. 16/561,152 · Granted Apr 27, 2021

Non-flammable contact adhesive

Inventors: Daniel C. Purvis, II (Purmela, TX); David A. Altenberg (Belton, TX); Kenneth Pechal (Rogers, TX); Eric Kendall (Temple, TX)
Assignee: WILSONART LLC
C09J153/02C09J9/00C09J11/06C09J11/08C09J109/06
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Quick Facts
Patent No.
US 10,988,645
App. No.
16/561,152
Granted
Apr 27, 2021
Kind
B1
Abstract

A non-flammable contact adhesive includes a solvent composed of a mixture of flammable and non-flammable components. The contact adhesive includes copolymer rubbers, tackifiers, stabilizer resins, and carbon dioxide gas.

Claims (25)

1. A non-flammable contact adhesive, comprising:

a chemically distinct solvent comprised of a mixture of flammable and non-flammable components;

chemically distinct copolymer rubbers;

chemically distinct tackifiers;

chemically distinct stabilizer resins; and

carbon dioxide gas.

2. The non-flammable contact adhesive according to claim 1 , wherein the carbon dioxide gas is included at a ratio of 1.5 pounds of carbon dioxide per 30 pounds of the cumulative weight of the solvent, copolymer rubbers, tackifiers, and stabilizer resins.

3. The non-flammable contact adhesive according to claim 2 , further including nitrogen gas.

4. The non-flammable contact adhesive according to claim 1 , wherein the non-flammable contact adhesive is an aerosol adhesive.

5. The non-flammable contact adhesive according to claim 1 , wherein the solvent is comprised of trans-dichloroethylene, a hydrofluoroolefin, and a hydrofluorocarbon fluid.

6. The non-flammable contact adhesive according to claim 5 , wherein the solvent is comprised of 40 to 90 weight percent of trans-dichloroethylene, 5 to 20 weight percent of hydrofluoroolefin, and 5 to 20 weight percent of hydrofluorocarbon fluid.

7. The non-flammable contact adhesive according to claim 5 , wherein the solvent is comprised of 40 to 90 weight percent of trans-dichloroethylene, 5 to 20 weight percent of hydrofluoroolefin, and 5 to 10 weight percent of hydrofluorocarbon fluid with zero ozone-depletion potential.

8. The non-flammable contact adhesive according to claim 5 , wherein the copolymer rubbers are a mixture of poly(styrene-isoprene-styrene) resins and poly(styrene-butadiene-styrene) resins.

9. The non-flammable contact adhesive according to claim 8 , wherein the copolymer rubbers are comprised of approximately 80% poly(styrene-isoprene-styrene) resins and 20% poly(styrene-butadiene-styrene) resins.

10. The non-flammable contact adhesive according to claim 5 , wherein the hydrofluoroolefin is trans-1-chloro-3,3,3-trifluoropropene.

11. The non-flammable contact adhesive according to claim 5 , wherein the hydrofluorocarbon fluid is 1,1,1,2,2,3,4,5,5,5-decafluoropentane.

12. The non-flammable contact adhesive according to claim 5 , wherein the solvent further includes tert-butyl acetate and parachlorobenzotrifluoride (PCBTF).

13. The non-flammable contact adhesive according to claim 12 , wherein the hydrofluoroolefin is trans-1-chloro-3,3,3-trifluoropropene.

14. The non-flammable contact adhesive according to claim 12 , wherein the hydrofluorocarbon fluid is 1,1,1,2,2,3,4,5,5,5-decafluoropentane.

15. The non-flammable contact adhesive according to claim 1 , wherein the copolymer rubbers are a mixture of poly(styrene-isoprene-styrene) resins and poly(styrene-butadiene-styrene) resins.

16. The non-flammable contact adhesive according to claim 15 , wherein the copolymer rubbers are comprised of approximately 80% poly(styrene-isoprene-styrene) resins and 20% poly(styrene-butadiene-styrene) resins.

17. The non-flammable contact adhesive according to claim 1 , wherein the tackifiers at least two resins selected rosin esters, aliphatic resins, cycloaliphatic hydrocarbon resins, water-white thermoplastic resins made from purified aromatic hydrocarbon monomers, polyterpene resins, and terpene phenolic resins.

18. The non-flammable contact adhesive according to claim 1 , wherein the stabilizing resins are mixtures comprising at least two selected from the group consisting of tris(2,4,-di-tert-butylphenyl) phosphite, octadecyl-3-(3,5-di-tert butyl-4-hydrophenyl)-propionate, or pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate).

19. The non-flammable contact adhesive according to claim 1 , wherein the non-flammable contact adhesive has a percent solid level of 15% to 36% with the solvent constituting 64% to 85% by weight of the non-flammable contact adhesive.

20. The non-flammable contact adhesive according to claim 1 , wherein the non-flammable contact adhesive has 70 to approximately 130 parts by weight per hundred parts by weight of a block copolymer rubber of tackifiers and 0.5 to 8 parts by weight per hundred parts by weight block of a copolymer rubber of stabilizers.

Assignments (2)
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Aug 5, 2024
From: WILSONART LLC
To: DEUTSCHE BANK AG NEW YORK BRANCH
Reel/Frame 068550/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 5, 2019
From: PURVIS, DANIEL C., II; ALTENBERG, DAVID A.; PECHAL, KENNETH; KENDALL, ERIC
To: WILSONART LLC
Reel/Frame 050276/0539 →
Continuity (2)
Continuation In Part 16242056 · Jan 8, 2019
Provisional Application 62615670 · Jan 10, 2018
Cited By (1)
US 12,577,433