IP Library Granted Patent US 10,766,022
Granted Patent B2
US 10,766,022 · App. 16/561,914 · Granted Sep 8, 2020

Hydrocarbon conversion catalyst composition

Inventors: László Domokos (Amsterdam, NL); Laurent Georges Huve (Colombes, FR); Hermanus Jongkind (Amsterdam, NL); Aan Hendrik Klazinga (Hilversum, NL); Marcello Stefano Rigutto (Amsterdam, NL)
Assignee: Shell Oil Company
B01J29/7446B01J23/42B01J23/44B01J23/755B01J29/70B01J29/703B01J29/708B01J29/7049B01J29/7261B01J29/7461B01J29/7661B01J29/7861B01J29/80B01J35/10B01J37/0009B01J37/0201B01J37/30C10G35/065C10G45/62C10G45/64C10G47/16C10G47/18C10G47/20C10G49/08C10G50/00C10G65/043C10G65/12B01J2229/16B01J2229/186B01J2229/20B01J2229/32B01J2229/37B01J2229/42
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Quick Facts
Patent No.
US 10,766,022
App. No.
16/561,914
Granted
Sep 8, 2020
Kind
B2
Abstract

A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.

Claims (22)

1. A catalytic dewaxing process for reducing the pour point of a wax-containing feedstock, said catalytic dewaxing process comprises:

contacting under dewaxing conditions said wax-containing feedstock, having a 10% distillation point at 200° C. as measured by ASTM D-2887-93, with a dewaxing catalyst composition, wherein said dewaxing conditions include a contacting temperature in the range of from 250 to 400° C., a contacting pressure in the range of from 5×10 5 to 200×10 5 Pa, and a liquid hourly space velocity in the range of from 0.1 to 10 hr −1 , and thereby providing a reduction of the pour point of said wax-containing feedstock by at least 10° C.;

wherein said dewaxing catalyst comprises a dealuminated dried and calcined extrudate, wherein said extrudate, before drying and calcination, comprises a binder that is essentially free of alumina and which comprises both a silica powder, wherein said silica powder comprises powder particles having a mean diameter between 10 μm and 200 μm, and a silica sol; EU-2 zeolite, wherein said EU-2 zeolite has a silica-to-alumina molar bulk ratio before the dealumination of said dried and calcined extrudate in the range of from 100 to 210; a plasticising agent; and water in an amount of at least 35% and not exceeding 60% by weight of the extrudate before drying and calcination; and

a catalytic metal selected from the group consisting of platinum, palladium and nickel;

wherein the dealumination of said dried and calcined extrudate is done by contacting said dried and calcined extrudate with an aqueous solution of fluorosilicate salt having a concentration of at least 0.005 mole of fluorosilicate salt/liter and at most 0.5 mole of fluorosilicate salt/liter and at a temperature in the range of from 10° C. to 120° C., and

wherein the amount of said EU-2 zeolite present in said catalyst composition is at least 15% wt. of said catalyst composition; and

wherein the EU-2 zeolite is in the form of EU-2 zeolite particles, where the average aluminum concentration of the EU-2 zeolite particles is at least two times the aluminum concentration at the surface of the particles.

2. The process as recited in claim 1 , wherein the EU-2 zeolite content in said catalyst composition, on a dry basis, is in the range of from 20 to 70 wt. % as calculated on the total weight of said catalyst composition.

3. The process as recited in claim 2 , wherein said fluorosilicate salt of said fluorosilicate salt solution is represented by the formula:

( A )2/ b SiF6

wherein ‘A’ is a metallic or non-metallic cation other than H+ having the valence ‘b’.

4. The process as recited in claim 3 , wherein the plasticizing agent is selected from the group consisting of dextrose, gelatin, glucose, glues, gums, salts, waxes, starch and cellulose ethers.

5. The process as recited in claim 4 , wherein said binder contains at most 2% wt. alumina, based on dry weight of the binder.

6. The process as recited in claim 5 , wherein said binder contains at most 1.1% wt. alumina, based on dry weight of the binder.

7. The process as recited in claim 6 , wherein said extrudate further comprises zeolite ZSM-12 that is present therein in an amount of at most 50% wt., based on the weight of said EU-2 zeolite present in said catalyst composition.

8. The process as recited in claim 7 , wherein the amount of EU-2 zeolite is at least 25% wt. and at most 65% wt.

9. The process as recited in claim 8 , wherein said plasticizing agent is methylcellulose or a methylcellulose derivative.

10. The process as recited in claim 9 , wherein said binder contains at most 0.2% wt. alumina, based on dry weight of the binder.

11. The process according to claim 10 , wherein said contacting temperature is in the range of from 275 to 350° C. and said contacting pressure is in the range of from 15×10 5 to 170×10 5 Pa.

12. The process according to claim 11 , wherein said wax-containing feedstock has a wax content of at least 50% by weight as determined by ASTM method D3235.

13. The process according to claim 12 , wherein said reduction of the pour point of said wax-containing feedstock is at least 20° C.

14. The process according to claim 13 , wherein said wax-containing feedstock has a wax content of at least 80% by weight.

Assignments (1)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
Priority Claims (1)
EP 10306165 · Oct 25, 2010 · regional
Continuity (2)
Division 13881058
Related Publication 20190388880A1 · Dec 26, 2019