IP Library Granted Patent US 11,383,302
Granted Patent B2
US 11,383,302 · App. 16/565,168 · Granted Jul 12, 2022

Heat exchangers fabricated by additive manufacturing, related components, and related methods

Inventors: Isabella J. Van Rooyen (Idaho Falls, ID); Piyush Sabharwall (Idaho Falls, ID)
Assignee: Battelle Energy Alliance, LLC
B22F10/20B23P15/26B28B1/001B33Y10/00B33Y70/00B33Y80/00F28F21/04F28F21/081
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Quick Facts
Patent No.
US 11,383,302
App. No.
16/565,168
Granted
Jul 12, 2022
Kind
B2
Abstract

A method of forming at least a component of a heat exchanger comprises introducing a feed material comprising a first portion including a matrix material and a second portion including a sacrificial material on a surface of a substrate, exposing at least the first portion to energy to form bonds between particles of the matrix material and form a first thickness of a structure, introducing additional feed material comprising the first portion over the first thickness of the structure, exposing the additional feed material to energy to form a second thickness of the structure, and removing the sacrificial material from the structure to form at least one channel in the structure. Related heat exchangers and components, and related methods are disclosed.

Claims (49)

1. A method of forming a structure including at least one channel, the method comprising:

disposing a first layer of a material on a substrate, forming the first layer comprising:

disposing a matrix material on the substrate;

disposing a sacrificial material on the substrate adjacent to the matrix material; and

exposing at least the matrix material to energy comprising a laser beam or an electron beam to form bonds between adjacent particles of the matrix material and form a first layer comprising a metal material on the substrate;

disposing a second layer comprising a ceramic material on the first layer;

exposing the second layer of the material to the energy to form a structure; and

removing the sacrificial material from the structure to form channels within the structure.

2. The method of claim 1 , wherein disposing a matrix material on the substrate comprises disposing a matrix material comprising one or more of aluminum nitride, silicon carbide, nickel, chromium, beryllium, SiC—Zr x Si y , FeCrAl, a zirconium alloy and silicate, or aluminum nitride on the substrate.

3. The method of claim 1 , wherein disposing a sacrificial material on the substrate comprises disposing a sacrificial material having a melting temperature less than a melting temperature of the matrix material on the substrate.

4. The method of claim 1 , wherein disposing a sacrificial material on the substrate comprises disposing a sacrificial material having a melting temperature greater than a melting temperature of the matrix material on the substrate.

5. The method of claim 1 , wherein disposing a sacrificial material on the substrate comprises disposing a sacrificial material comprising one or more of polyphenylene sulfide (PPS), polyetheretherketone (PEEK), polyetherketone (PEK), polyphthalamide (PPA), how water moldable polyphthalamide (PPA), polyetherketoneketone (PEKK), polyimide (TPI), high temperature nylon (HTN), polysulfone (PSU), polyethersulfone (PES), polyetherimide (PEI), and liquid crystal polymer (LCP) on the substrate.

6. The method of claim 1 , further comprising exposing the channels to energy after removing the sacrificial material from the structure to reduce a surface roughness of the channels.

7. The method of claim 1 , wherein removing the sacrificial material from the structure comprises melting the sacrificial material.

8. The method of claim 1 , wherein removing the sacrificial material comprises physically removing the sacrificial material from the structure.

9. The method of claim 1 , further comprising exposing the structure to a heat treatment process prior to removing the sacrificial material from the structure.

10. The method of claim 1 , wherein exposing the first layer of the material to the energy to form a structure comprises forming the structure to exhibit a varying weight percent of at least one metal in at least one direction.

11. The method of claim 1 , wherein exposing at least the matrix material to energy comprising a laser beam or an electron beam comprises exposing the at least the matrix material to a laser beam.

12. The method of claim 1 , wherein removing the sacrificial material from the structure comprises chemically reacting the sacrificial material to form one or more reaction byproducts and removing the one or more reaction byproducts from the structure.

13. The method of claim 1 , wherein disposing a first layer of a material on a substrate comprises disposing, on the substrate, the matrix material in a sacrificial material comprising a resin.

14. The method of claim 1 , wherein disposing a matrix material on the substrate comprises disposing a matrix material comprising the ceramic material and the metal material on the substrate.

15. The method of claim 14 , wherein disposing a matrix material on the substrate and removing the sacrificial material from the structure to form channels within the structure comprises forming the structure to comprise a greater amount of the ceramic material proximate the channels than distal from the channels.

16. The method of claim 1 , wherein disposing a sacrificial material on the substrate comprises disposing a sacrificial material comprising a flexible high temperature carbon fiber composite material on the substrate.

17. The method of claim 1 , wherein removing the sacrificial material from the structure to form channels within the structure comprises forming the structure to exhibit a higher melting temperature at locations proximate the channels than distal from the channels.

18. The method of claim 1 , wherein disposing a first layer of a material on a substrate and removing the sacrificial material from the structure to form channels within the structure comprises forming the structure to exhibit a varying composition with a distance from the channels.

19. A method of forming a structure including at least one channel, the method comprising:

disposing a first layer of a material on a substrate, forming the first layer comprising:

disposing a matrix material on the substrate;

disposing a sacrificial material on the substrate adjacent to the matrix material; and

exposing at least the matrix material to energy comprising a laser beam or an electron beam to form bonds between adjacent particles of the matrix material;

disposing a second layer of a material on the first layer;

exposing the second layer of the material to the energy to form a structure exhibiting a varying weight percent of at least one metal in at least one direction; and

removing the sacrificial material from the structure to form channels within the structure.

20. A method of forming a structure including at least one channel, the method comprising:

disposing a first layer of a material on a substrate, forming the first layer comprising:

disposing a matrix material comprising at least one ceramic material and at least one metal material on the substrate;

disposing a sacrificial material on the substrate adjacent to the matrix material; and

exposing at least the matrix material to energy comprising a laser beam or an electron beam to form bonds between adjacent particles of the matrix material;

disposing a second layer of a material on the first layer;

exposing the second layer of the material to the energy to form a structure; and

removing the sacrificial material from the structure to form channels within the structure.

21. A method of forming a structure including at least one channel, the method comprising:

disposing a first layer of a material on a substrate, forming the first layer comprising:

disposing a matrix material on the substrate;

disposing a sacrificial material on the substrate adjacent to the matrix material; and

exposing at least the matrix material to energy comprising a laser beam or an electron beam to form bonds between adjacent particles of the matrix material;

disposing a second layer of a material on the first layer;

exposing the second layer of the material to the energy to form a structure; and

removing the sacrificial material from the structure to form channels within the structure, the structure exhibiting a varying composition with a distance from the channels.

Assignments (2)
CONFIRMATORY LICENSE Recorded Dec 17, 2019
From: BATTELLE ENERGY ALLIANCE, LLC.
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 051655/0323 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 9, 2019
From: VAN ROOYEN, ISABELLA J.; SABHARWALL, PIYUSH
To: BATTELLE ENERGY ALLIANCE, LLC
Reel/Frame 050319/0165 →
Continuity (2)
Provisional Application 62734455 · Sep 21, 2018
Related Publication 20200094322A1 · Mar 26, 2020