Facile direct functionalization of pristine graphene nanoparticles
Graphene is a single layer carbon-based material known for high strength, high flexibility, high electrical conductivity, high surface area, hydrophobicity and barrier property. Introduction of surface functional groups on graphene enhances most of these properties. A facile and economical process to prepare amine and fluoride functionalized graphenes is disclosed. The disclosed processes utilize direct functionalization of pristine graphene without pre-functionalization (GO). Successful functionalization of both aminated and fluorinated graphenes were confirmed by the analyses of FT-IR, thermal gravimetric analysis (TGA), Raman, UV-Vis, and dispersion study. Amine functional groups can react with epoxy resin and urethane resin to form a covalent bond, and fluorinated graphene can give high hydrophobicity and durability, therefore both can be applied as a material or a component in polymer and composite coatings for corrosion protection, moisture or gas barriers.
1. A method for preparing an aminated graphene comprising reacting graphene with urea in a solvent or a solvent-deionized water mixture, and wherein the ratio of the graphene and the urea is in the range of 0.1-4.0 by weight.
2. The method of claim 1 wherein the graphene comprises at least one of mechanically exfoliated graphene, mechanically exfoliated graphene nanoparticles or graphene film.
3. The method of claim 2 wherein the graphene nanoparticles have a diameter in the range of 10 nm to 100 microns.
4. The method of claim 1 wherein the graphene comprises at least one of reduced chemically exfoliated graphene or reduced chemically exfoliated graphene nanoparticles.
5. The method of claim 1 , wherein the mass percentage of carbon in the graphene is in the range of 99.0% 99.9%.
6. The method of claim 1 , wherein the mass percentage of carbon in the graphene is greater than 99.99%.
7. The method of claim 1 wherein the solvent is selected from the group consisting of: ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, any high boiling glycol, a triol based solvent and combinations thereof.
8. The method of claim 1 wherein the reacting temperature is in the range of 150-250° C., at 1 atmospheric pressure, under reflux in air or under reflux in inert conditions.
9. The method of claim 1 wherein the reacting duration is in the range of 1-24 hours.
10. The method of claim 1 further comprising the step of including the aminated graphene as a component in a coating, a polymer, a composite or a polymer film.
11. The method of claim 10 wherein the coating is a urethane coating or an epoxy coating.
12. The method of claim 1 further comprising the step of including the aminated graphene as a component as a UV absorbing additive.
13. A method for preparing an aminated graphene comprising a reaction by reacting graphene with an aminating reagent in a solvent-deionized water mixture, wherein the solvent-deionized water mixture includes at least one solvent selected from the group consisting of: ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, any high boiling glycol, and a triol based solvent.
14. The method of claim 13 wherein the triol based solvent comprises glycerol, or wherein the solvent-deionized water mixture has a deionized water content in the range of 5%-60% by volume.
15. The method of claim 13 , wherein the solvent-deionized water mixture has a deionized water content in the range of 5%-60% by volume.
16. The method of claim 13 , wherein the aminating reagent is selected from the group consisting of urea, ethylenediamine, and para-phenylenediamine.
17. An aminated graphene, obtained in a reaction by reacting graphene with an aminating reagent in a solvent or a solvent-deionized water mixture, wherein the mass percentage of amine functional groups (—NH 2 ) is in the range of 1%<—NH 2 <50%, mass percentage of carbon is in the range of 30%<C %<99%, and mass percentage of oxygen is in the range 0%<O %<0.1%.
18. A composition selected from the group consisting of a coating, polymer, composite and a polymer film comprising the aminated graphene of claim 17 .
19. The composition of claim 18 wherein the coating is a urethane coating or an epoxy coating.
20. A UV absorbing additive comprising the aminated graphene of claim 17 .