IP Library Granted Patent US 10,870,585
Granted Patent B2
US 10,870,585 · App. 16/572,896 · Granted Dec 22, 2020

Production of calcium carbonate via solid-state calcium hydroxide particles and carbon dioxide, and associated systems and methods

Inventors: Brent LaMar (Sandy, UT); Jared Ira Leikam (West Jordan, UT); Joseph Lewis (Stansbury Park, UT)
Assignee: GRAYMONT (PA) INC.
C01F11/18
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Quick Facts
Patent No.
US 10,870,585
App. No.
16/572,896
Granted
Dec 22, 2020
Kind
B2
Abstract

Methods and systems for producing calcium carbonate from calcium hydroxide and carbon dioxide are disclosed herein. In some embodiments, a method for producing calcium carbonate comprises (i) providing a first plurality of particles comprising solid-state calcium hydroxide, and (ii) introducing a gas stream comprising carbon dioxide to the first plurality of particles to produce a second plurality of particles comprising calcium carbonate. Individual ones of the first plurality of particles can include a specific surface area of at least 20 m 2 /g and a free moisture content of from 2% to 20%. The second plurality of particles comprising calcium carbonate are not produced via precipitation.

Claims (26)

1. A method for producing calcium carbonate from calcium hydroxide and carbon dioxide, comprising:

providing a first plurality of particles comprising solid-state calcium hydroxide, individual ones of the first plurality of particles including (i) a specific surface area of at least 20 m 2 /g and (ii) a free moisture content of from 2% to 20% by weight; and

introducing a gas stream comprising carbon dioxide to the first plurality of particles to produce a second plurality of particles comprising at least 40% by weight solid-state calcium carbonate, wherein the second plurality of particles are not part of a liquid slurry comprising precipitated calcium carbonate.

2. The method of claim 1 , wherein introducing the gas stream comprises introducing the gas stream such that the carbon dioxide of the gas stream directly contacts the calcium hydroxide of the first plurality of particles to produce the calcium carbonate of the second plurality of particles.

3. The method of claim 2 , wherein the gas stream comprises at least 30% by weight carbon dioxide.

4. The method of claim 1 , wherein providing the first plurality of particles comprises providing the first plurality of particles to a conditioner, and wherein introducing the gas stream comprises introducing the gas stream to the conditioner.

5. The method of claim 1 , wherein the first and second pluralities of particles are not part of a liquid slurry comprising precipitated calcium carbonate.

6. The method of claim 1 , wherein the second plurality of particles comprising calcium carbonate is not produced via precipitation.

7. The method of claim 1 , wherein the second plurality of particles comprises at least 95% by weight calcium carbonate.

8. The method of claim 1 , wherein:

the first plurality of particles comprises at least 90% by weight calcium hydroxide,

providing the first plurality of particles comprises providing the first plurality of particles to a conditioner, and

introducing the gas stream includes injecting the gas stream to the conditioner, thereby causing the carbon dioxide of the gas stream to directly contact at least a portion of the first plurality of particles.

9. The method of claim 1 , wherein the gas stream is a first gas stream, the method further comprising:

after introducing the first gas stream, grinding at least a portion of the second plurality of particles to produce a third plurality of particles comprising a first concentration of calcium carbonate; and

after grinding, introducing a second gas stream comprising carbon dioxide to the third plurality of particles to produce a fourth plurality of particles comprising a second concentration of calcium carbonate greater than the first concentration of calcium carbonate.

10. The method of claim 9 , further comprising, while grinding, introducing a third gas stream comprising carbon dioxide to the second plurality of particles.

11. The method of claim 1 , wherein the gas stream comprising carbon dioxide is received from a lime kiln, and wherein the carbon dioxide comprises at least about 40% by weight of the gas stream.

12. The method of claim 1 , wherein individual ones of the first plurality of particles have a free moisture content of from about 10% to 20% by weight.

13. A method for producing calcium carbonate from calcium hydroxide and carbon dioxide, comprising:

providing a first plurality of particles comprising solid-state calcium hydroxide to a conditioner, individual ones of the first plurality of particles including (i) a specific surface area of at least 20 m 2 /g and (ii) a free moisture content of from 2% to 20% by weight; and

introducing a gas stream comprising carbon dioxide to the conditioner such that the carbon dioxide directly contacts the first plurality of particles to produce a second plurality of particles comprising at least 40% by weight solid-state calcium carbonate, wherein the second plurality of particles are not part of a liquid slurry comprising precipitated calcium carbonate.

14. The method of claim 13 , wherein providing the first plurality of particles comprises directing the first plurality of particles from a hydrator to the conditioner.

15. The method of claim 13 , wherein the first and second pluralities of particles are not part of a liquid slurry comprising precipitated calcium carbonate.

16. The method of claim 13 , wherein the gas stream comprises at least 30% by weight carbon dioxide.

17. The method of claim 13 , wherein the first plurality of particles comprise a specific surface area of at least 30 m 2 /g.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 31, 2019
From: LAMAR, BRENT; LEIKAM, JARED IRA; LEWIS, JOSEPH
To: GRAYMONT (PA) INC.
Reel/Frame 050878/0855 →
Continuity (2)
Provisional Application 62732427 · Sep 17, 2018
Related Publication 20200087158A1 · Mar 19, 2020
Cited By (1)
US 12,709,547