Dielectric ceramic composition and multi-layer ceramic electronic component using the same
A dielectric ceramic composition and a multilayer ceramic electronic component are provided, the dielectric ceramic composition includes a barium titanate base material main component and a subcomponent, a microstructure after sintering includes a first crystal grain including 3 or less domain boundaries and a second crystal grain including 4 or more domain boundaries, and an area ratio of the second crystal grain to the total crystal grains is 20% or less.
1. A dielectric ceramic composition, comprising a barium titanate base material main component and a subcomponent,
wherein a microstructure after sintering of the dielectric ceramic composition includes a first crystal grain including 4 or more domain boundaries, and
an area ratio of the first crystal grain to the total crystal grains is 20% or less.
2. The dielectric ceramic composition of claim 1 , wherein the barium titanate base material main component includes a base material main component indicated by ABO 3 , in which A is at least one element selected from the group consisting of barium (Ba), strontium (Sr), and calcium (Ca), and B is at least one of titanium (Ti) or zirconium (Zr), wherein ratios of each element of A and B included as ABO 3 vary depending on the combination of the selected elements of A and B.
3. The dielectric ceramic composition of claim 1 , wherein the subcomponent includes:
a first subcomponent including one or more variable-valence acceptor elements selected from the group consisting of manganese (Mn), vanadium (V), chromium (Cr), iron (Fe), nickel (Ni), cobalt (Co), copper (Cu), and zinc (Zn), an oxide thereof, and a carbonate thereof;
a second subcomponent including one or more elements selected from the group consisting of a fixed-valence acceptor element including magnesium (Mg), an oxide thereof, and a carbonate thereof;
a third subcomponent including one or more elements selected from the group consisting of yttrium (Y), dysprosium (Dy), holmium (Ho), erbium (Er), gadolinium (Gd), cerium (Ce), neodymium (Nd), samarium (Sm), terbium (Tb), thulium (Tm), lanthanum (La), gadolinium (Gd), and ytterbium (Yb), an oxide thereof, a carbonate thereof;
a fourth subcomponent including one or more elements selected from the group consisting of barium (Ba) and calcium (Ca), an oxide thereof, and a carbonate thereof;
a fifth subcomponent including one or more elements selected from the group consisting of an oxide of an Si element, a carbonate of the Si element, and glass containing the Si element; and
a sixth subcomponent including one or more elements selected from the group consisting sodium (Na) and lithium (Li), an oxide thereof, a carbonate thereof.
4. The dielectric ceramic composition of claim 3 , wherein the third subcomponent is included in the dielectric ceramic composition in a range of 0.3 mol % to 5.4 mol %, inclusive, with respect to the base material main component.
5. The dielectric ceramic composition of claim 3 , wherein the fourth subcomponent is included in the dielectric composition in 5 mol % or less with respect to the base material main component.
6. The dielectric ceramic composition of claim 3 , wherein the fifth subcomponent is included in the dielectric composition in a range of 0.5 mol % to 5 mol %, inclusive, with respect to the base material main component.
7. The dielectric ceramic composition of claim 3 , wherein, with respect to the base material main component,
the first subcomponent is included in the dielectric composition in a range of 0.1 mol % to 1.0 mol %, inclusive,
the second subcomponent is included in the dielectric composition in 2 mol % or less, and
the sixth subcomponent is included in the dielectric composition in 1 mol % or less.
8. The dielectric ceramic composition of claim 1 , wherein the subcomponent includes:
a third subcomponent including one or more elements selected from the group consisting of yttrium (Y), dysprosium (Dy), holmium (Ho), erbium (Er), gadolinium (Gd), cerium (Ce), neodymium (Nd), samarium (Sm), terbium (Tb), thulium (Tm), lanthanum (La), and Yb, oxides thereof, and carbonates thereof;
a fourth subcomponent including one or more elements selected from the group consisting of Ba and Ca, oxides thereof, and carbonates thereof; and
a fifth subcomponent including one or more elements selected from the group consisting of oxides of an Si element, carbonates of the Si element, and glass containing the Si element, and
a relationship between the contents (atomic percent (at %)) of the third, fourth, and fifth subcomponents is on or inside boundaries of a quadrangle connecting points A (0.5, 1.9), B (0.5, 3.1), C (5, 5.4), and D (5, 3.275), when an X-axis refers to the content (at %) of the fifth subcomponent, and a Y-axis refers to the total content (at %) of the third subcomponent and the fourth subcomponent.
9. The dielectric ceramic composition of claim 1 , wherein the microstructure after sintering further includes a second crystal grain including 3 or less domain boundaries.
10. The dielectric ceramic composition of claim 1 , wherein the area ratio of the first crystal grain to the total crystal grains is 10% or less.
11. The dielectric ceramic composition of claim 2 , wherein the ABO 3 is (Ba 1-x Ca x )(Ti 1-y Ca y )O 3 , or (Ba 1-x-z Ca x Sr z )(Ti 1-y Ca y )O 3 in which x is a number from 0 to 0.2, y is a number from 0 to 0.1, and z is a number from 0 to 0.1.
12. The dielectric ceramic composition of claim 2 , wherein the ABO 3 is BaTiO 3 .
13. A multilayer ceramic electronic component, comprising:
a ceramic body including a dielectric layer and an internal electrode; and
an external electrode formed on an external surface of the ceramic body, and electrically connected to the internal electrode,
wherein a microstructure of the dielectric layer includes a first crystal grain including 4 or more domain boundaries, and
an area ratio of the first crystal grain to the total crystal grains is 20% or less.
14. The multilayer ceramic electronic component of claim 13 , wherein the dielectric layer includes:
a barium titanate base material main component;
a third subcomponent including one or more elements selected from the group consisting of yttrium (Y), dysprosium (Dy), holmium (Ho), erbium (Er), gadolinium (Gd), cerium (Ce), neodymium (Nd), samarium (Sm), terbium (Tb), thulium (Tm), lanthanum (La), and ytterbium (Yb), oxides thereof, and carbonates thereof;
a fourth subcomponent including one or more elements selected from the group consisting of barium (Ba) and calcium (Ca), oxides thereof, and carbonates thereof; and
a fifth subcomponent including one or more elements selected from the group consisting of an oxide of an Si element, a carbonate of the Si element, and glass containing the Si element, and
a relationship between the contents (atomic percent (at %)) of the third, fourth, and fifth subcomponents is on or inside boundaries of a quadrangle connecting points A (0.5, 1.9), B (0.5, 3.1), C (5, 5.4), and D (5, 3.275), when an X-axis refers to the content (at %) of the fifth subcomponent, and a Y-axis refers to the total content (at %) of the third subcomponent and the fourth subcomponent.
15. The multilayer ceramic electronic component of claim 13 , wherein the internal electrode includes a first internal electrode and a second internal electrode, disposed to oppose each other with the dielectric layer interposed therebetween.
16. The multilayer ceramic electronic component of claim 13 , wherein the microstructure of the dielectric layer further includes a second crystal grain including 3 or less domain boundaries.
17. The multilayer ceramic electronic component of claim 13 , wherein the area ratio of the first crystal grain to the total crystal grains is 10% or less.
18. A dielectric ceramic composition, comprising:
a barium titanate base material main component;
a third subcomponent including one or more elements selected from the group consisting of yttrium (Y), dysprosium (Dy), holmium (Ho), erbium (Er), gadolinium (Gd), cerium (Ce), neodymium (Nd), samarium (Sm), terbium (Tb), thulium (Tm), lanthanum (La) and ytterbium (Yb), oxides thereof, and carbonates thereof;
a fourth subcomponent including one or more elements selected from the group consisting of barium (Ba) and calcium (Ca), oxides thereof, and carbonates thereof; and
a fifth subcomponent including one or more elements selected from the group consisting of an oxide of an Si element, a carbonate of the Si element, and glass containing the Si element, and
a relationship between the contents (atomic percent (at %)) of the third, fourth, and fifth subcomponents is on or inside boundaries of a quadrangle connecting points A (0.5, 1.9), B (0.5, 3.1), C (5, 5.4), and D (5, 3.275), when an X-axis refers to the content (at %) of the fifth subcomponent, and a Y-axis refers to the total content (at %) of the third subcomponent and the fourth subcomponent.
19. The dielectric ceramic composition of claim 18 , further comprising:
a first subcomponent including one or more variable-valence acceptor elements selected from the group consisting of manganese (Mn), vanadium (V), chromium (Cr), iron (Fe), nickel (Ni), cobalt (Co), copper (Cu), and zinc (Zn), an oxide thereof, and a carbonate thereof;
a second subcomponent including one or more elements selected from the group consisting of a fixed-valence acceptor element including magnesium (Mg), an oxide thereof, and a carbonate thereof; and
a sixth subcomponent including one or more elements selected from the group consisting sodium (Na) and lithium (Li), an oxide thereof, a carbonate thereof.
20. The dielectric ceramic composition of claim 18 , wherein a microstructure after sintering of the dielectric ceramic composition includes a first crystal grain including 3 or less domain boundaries and a second crystal grain including 4 or more domain boundaries, and
an area ratio of the second crystal grain to the total crystal grains is 20% or less.