Methods and devices for real-time detection of fouling chemistry
Methods and devices for real-time detection of fouling chemistry are described herein. In one aspect, a method of detecting and characterizing fouling of a membrane used for separation in a fluid-based system can include illuminating the membrane with one or more light sources, collecting Raman spectroscopy data from the membrane, and based on the Raman data, determining at least one selected from the group consisting of: presence or absence of membrane fouling, severity of membrane fouling, and composition of the membrane fouling, where the Raman spectroscopy is selected from the group consisting of Coherent Anti-Stokes Raman Scattering (CARS), Stimulated Raman Scattering (SRS), and spontaneous Raman Scattering.
1. A method of detecting and characterizing fouling of a membrane used for separation in a fluid-based system, the method comprising:
illuminating the membrane with one or more light sources;
collecting Raman spectroscopy data from the membrane; and
based on the Raman spectroscopy data, determining at least one selected from the group consisting of: presence or absence of membrane fouling, severity or thickness of membrane fouling, and composition of the membrane fouling;
wherein the Raman spectroscopy is selected from the group consisting of Coherent Anti-Stokes Raman Scattering (CARS), Stimulated Raman Scattering (SRS), and spontaneous Raman Scattering.
2. The method of claim 1 , wherein the membrane fouling is membrane scaling.
3. The method of claim 1 , wherein the membrane fouling comprises deposition on the membrane, or in a set of pores of the membrane, of a material selected from the group consisting of calcium salts, sulfate salts, magnesium salts, sodium salts, potassium salts, barium salts, strontium salts, aluminum salts, iron salts, carbonate salts, hydroxides, fluoride salts, chloride salts, bromide salts, polysaccharides, proteins, lipids, colloidal iron compounds, colloidal silicon compounds, colloidal aluminum compounds, and at least one organism.
4. The method of claim 3 , wherein the deposition on the membrane further comprises at least two materials of the group, wherein the determining further comprises determining the composition of the two materials.
5. The method of claim 1 , wherein the membrane comprises at least one selected from the group consisting of a polyamide, polyether sulfone (PES), polydimethyl siloxane, cellulose acetate (CA), polyacrylonitrile (PAN), polyamides, polyamide-imide (PI), polyethylene (PE), polypropylene (PP), polysulfone (PS), polytetrafluoroethylene (PTFE), polyvinylidene difluoride (PVDF), tungsten, palladium, stainless steel, aluminum, titanium, a metal oxide, a metal nitride, a metal carbide, and a zeolite material.
6. The method of claim 1 , wherein the membrane is a thin film composite (TFC) membrane.
7. The method of claim 1 , wherein the fluid-based system is at least one selected from the group consisting of a water desalination system, a waste water system, a biofiltration system, a gas separation system, a pharmaceutical separation system, a food or beverage separation system, a liquid carbon dioxide separation system, an organic solvent separation system, whereby such systems consist of one or more microfiltration (MF) membranes, ultrafiltration (UF) membranes, nanofiltration (NF) membranes and hyperfiltration (RO) membranes.
8. The method of claim 1 , wherein the one or more light sources are two lasers, each having a different frequency.
9. The method of claim 8 , wherein the frequency difference of the two lasers corresponds to a molecular vibration frequency of a membrane fouling compound.
10. The method of claim 1 , wherein the Raman spectroscopy data are collected using a spectrometer and a camera.
11. The method of claim 1 , wherein the CARS is implemented using at least one dual comb laser source.
12. The method of claim 1 , wherein the membrane is illuminated through at least one optical window that allows transmission of the at least one light source.
13. The method of claim 1 , further comprising:
scanning a frequency difference between the one or more light sources, wherein the Raman spectroscopy data is collected using a photodetector.
14. An apparatus for detecting and characterizing fouling in a fluid-based system, the apparatus comprising:
a flow cell defining a cavity;
a separation membrane positioned within the cavity; and
a Raman microscope comprising one or more light sources, the Raman microscope configured or adapted to:
illuminate the membrane with the one or more light sources;
collect Raman spectroscopy data from the membrane; and
based on the Raman spectroscopy data, determine at least one selected from the group consisting of: presence or absence of membrane fouling, severity of membrane fouling, and composition of the membrane fouling;
wherein the Raman spectroscopy is selected from the group consisting of Coherent Anti-Stokes Raman Scattering (CARS), Stimulated Raman Scattering (SRS), and spontaneous Raman Scattering.
15. The apparatus of claim 14 , wherein the membrane fouling is membrane scaling.
16. The apparatus of claim 14 , wherein the membrane fouling comprises deposition on the separation membrane, or in a set of pores of the separation membrane, of a material selected from the group consisting of calcium salts, sulfate salts, magnesium salts, sodium salts, potassium salts, barium salts, strontium salts, aluminum salts, iron salts, carbonate salts, hydroxides, fluoride salts, chloride salts, bromide salts, polysaccharides, proteins, lipids, colloidal iron compounds, colloidal silicon compounds, colloidal aluminum compounds, and at least one organism.
17. The apparatus of claim 16 , wherein the deposition on the separation membrane further comprises at least two materials of the group, wherein the determining further comprises determining the composition of the two materials.
18. The apparatus of claim 14 , wherein the separation membrane comprises at least one selected from the group consisting of a polyamide, polyether sulfone (PES), polydimethyl siloxane, cellulose acetate (CA), polyacrylonitrile (PAN), polyamides, polyamide-imide (PI), polyethylene (PE), polypropylene (PP), polysulfone (PS), polytetrafluoroethylene (PTFE), polyvinylidene difluoride (PVDF), tungsten, palladium, stainless steel, aluminum, titanium, a metal oxide, a metal nitride, a metal carbide, and a zeolite material.
19. The apparatus of claim 14 , wherein the fluid-based system is at least one selected from the group consisting of a water desalination system, a waste water system, a biofiltration system, a gas separation system, a pharmaceutical separation system, a food or beverage separation system, a liquid carbon dioxide separation system, an organic solvent separation system, whereby such systems consist of one or more microfiltration (MF) membranes, ultrafiltration (UF) membranes, nanofiltration (NF) membranes, and hyperfiltration (RO) membranes.
20. A method of monitoring severity or thickness of fouling of a membrane used for separation in a fluid-based system, the method comprising:
illuminating the membrane with one or more light sources;
collecting Raman spectroscopy data from the membrane; and
based on the Raman spectroscopy data, determining severity or thickness of membrane fouling;
wherein the Raman spectroscopy is selected from the group consisting of Coherent Anti-Stokes Raman Scattering (CARS), Stimulated Raman Scattering (SRS), and spontaneous Raman Scattering.