IP Library › Granted Patent US 11,054,757
Granted Patent B2
US 11,054,757 · App. 16/583,861 · Granted Jul 6, 2021

Toner, image forming apparatus, image forming method, and process cartridge

Inventors: Yohichi Kitagawa (Shizuoka, JP); Keiji Makabe (Shizuoka, JP); Yuka Mizoguchi (Shizuoka, JP); Tsuneyasu Nagatomo (Shizuoka, JP); Shinya Nakayama (Shizuoka, JP)
Assignee: Ricoh Company, Ltd.
G03G9/08755G03G9/0819G03G9/0827G03G15/08G03G21/1814
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Quick Facts
Patent No.
US 11,054,757
App. No.
16/583,861
Granted
Jul 6, 2021
Kind
B2
Abstract

A toner including toner base particles each including a binder resin and a colorant, and external additive, wherein the toner satisfies conditions (a), (b), and (c) below: (a) storage elastic modulus G′(50) of the toner at 50° C. and storage elastic modulus G′(90) of the toner at 90° C. satisfy Formula (1); G ′(50)/ G ′(90)≥6.0×10 2   Formula (1) (b) a BET specific surface area Bt(m 2 /g) of the toner and a coverage Ct (%) of the toner base particles covered with the external additive satisfy Formula (2); and Bt −0.03× Ct ≤1.60  Formula (2) (c) the external additive includes at least cohered particles, the cohered particles are non-spherical secondary particles each formed through cohesion of primary particles, and a number average secondary particle diameter of the cohered particles is 130 nm or greater.

Claims (32)

1. A toner comprising:

toner base particles each including a binder resin and a colorant; and

external additive;

wherein the toner satisfies conditions (a), (b), and (c) below:

(a) storage elastic modulus G′(50) of the toner at 50° C. and storage elastic modulus G′(90) of the toner at 90° C. satisfy Formula (1):

G ′(50)/ G ′(90)≥6.0×10 2   Formula (1)

(b) a BET specific surface area Bt(m 2 /g) of the toner and a coverage Ct (%) of the toner base particles covered with the external additive satisfy Formula (2):

Bt− 0.03× Ct≤ 1.60  Formula (2)

(c) the external additive includes at least cohered particles,

the cohered particles are non-spherical secondary particles each formed through cohesion of primary particles, and

a number average secondary particle diameter of the cohered particles is 130 nm or greater.

2. The toner according to claim 1 ,

wherein an amount B (% by mass) of the external additive liberated from the toner satisfies Formula (4),

B> 0.8  Formula (4)

where the amount B of the liberated external additive is an amount of the external additive liberated from the toner when 3.75 g of the toner is dispersed in 50 mL of a 0.5% by mass polyoxyalkylene alkyl ether dispersion liquid in a 110 mL vial and applying ultrasonic wave vibrations for 1 minute at 20 kHz and 750 W.

3. An image forming apparatus comprising:

an electrostatic latent image bearing member;

an electrostatic latent image forming unit configured to form an electrostatic latent image on the electrostatic latent image bearing member;

a developing unit configured to develop the electrostatic latent image formed on the electrostatic latent image bearing member with a toner to form a toner image, where the developing unit stores therein the toner;

a transferring unit configured to transfer the toner image formed on the electrostatic latent image bearing member to a surface of a recording medium; and

a fixing unit configured to fix the toner image transferred onto the recording medium,

wherein the toner is the toner according to claim 1 .

4. The image forming apparatus according to claim 3 , further comprising a cleaning unit configured to remove the toner remained on the electrostatic latent image bearing member.

5. An image forming method comprising:

forming an electrostatic latent image on an electrostatic latent image bearing member;

developing the electrostatic latent image formed on the electrostatic latent image bearing member with a toner to form a toner image;

transferring the toner image formed on the electrostatic latent image bearing member to a surface of a recording medium; and

fixing the toner image transferred onto the surface of the recording medium,

wherein the toner is the toner according to claim 1 .

6. A process cartridge comprising:

an electrostatic latent image bearing member; and

a developing unit configured to develop an electrostatic latent image formed on the electrostatic latent image bearing member with the toner according to claim 1 to form a toner image, where the developing unit stores therein the toner.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2019
From: KITAGAWA, YOHICHI; MAKABE, KEIJI; MIZOGUCHI, YUKA; NAGATOMO, TSUNEYASU; NAKAYAMA, SHINYA
To: RICOH COMPANY, LTD.
Reel/Frame 050502/0560 →
Priority Claims (2)
JP JP2018-181271 · Sep 27, 2018 · national
JP JP2018-204925 · Oct 31, 2018 · national
Continuity (1)
Related Publication 20200103775A1 · Apr 2, 2020