Core-shell particles and use thereof
View Patent ↗The manufacturing method provided by the present invention is a method for manufacturing core-shell particles that includes core particles and a shell, the constituent metal elements of the foregoing being different from each other. In the present invention, a quinone-containing core particle dispersion containing at least core particles consisting of a first metal, hydroquinone (HQ), benzoquinone (BQ), and a second metal compound including a second metal element for making up the shell is prepared, and a reduction treatment is performed on the quinone-containing core particle dispersion, through addition of a reducing agent, to form a shell including the second metal element as a main constituent element, on the surface of the core particles. A mass ratio: HQ/BQ ratio of added hydroquinone (HQ) and benzoquinone (BQ) is 0.1 to 120.
1. A powder material substantially comprising:
metal core-shell particles comprising core particles, and a shell covering at least part of the core particles, main constituent metal elements of the core particles and the shell being different from each other;
wherein, upon measurement of the powder material in a state of being dispersed in a medium, a ratio D DLS /D SEM of a Z average particle size (D DLS ) based on a dynamic light scattering (DLS) method and an average particle size (D SEM ) based on a field-emission scanning electron micrograph (FE-SEM image) is 2 or lower; and
wherein both hydroquinone (HQ) and benzoquinone (BQ) are deposited on the surface of the core-shell particles, and a mass ratio: HQ/BQ ratio of the hydroquinone (HQ) and benzoquinone (BQ) is 0.1 to 120.
2. The powder material according to claim 1 , wherein upon measurement of the powder material in a state of being dispersed in a medium, the Z average particle size (D DLS ) based on a dynamic light scattering method is 0.1 μm to 2 μm, and a polydispersity index (PDI) based on a dynamic light scattering method is 0.3 or lower.
3. The powder material according to claim 1 , wherein the core particles are made up of silver (Ag) as a main constituent metal element, and the shell is made up of at least one metal belonging to a platinum group or nickel (Ni) as a main constituent metal element, wherein the platinum group is limited to consisting of ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and platinum (Pt).
4. The powder material according to claim 1 , wherein a mass proportion of the shell with respect to 100 mass % as the mass of the totality of the core-shell particles contained in the powder material is 0.5 to 45 mass %.
5. A conductive paste, comprising:
the powder material according to claim 1 ; and
a medium for dispersing the powder material.