IP Library › Granted Patent US 11,407,925
Granted Patent B2
US 11,407,925 · App. 16/604,104 · Granted Aug 9, 2022

Adhesive sheet and method of applying adhesive sheet to rough surface

Inventors: Hidetoshi Abe (Yamagata, JP); Kengo Imamura (Tokyo, JP); Katsuya Ono (Yamagata, JP); Yoshihiko Takeda (Miyagi, JP); Takeo Yamamoto (Yamagata, JP)
Assignee: 3M INNOVATIVE PROPERTIES COMPANY
C09J7/385C08F220/06C08F220/1808C08F236/20C08K3/22C09J7/255C09J7/29C09J7/38C09J133/08C08K7/16C08K2003/2237C09J2301/124C09J2301/16C09J2301/20C09J2301/302C09J2301/408C09J2301/412C09J2400/163C09J2433/00C09J2467/001C09J2467/006Y10T428/2891
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Quick Facts
Patent No.
US 11,407,925
App. No.
16/604,104
Granted
Aug 9, 2022
Kind
B2
Abstract

An adhesive sheet of an embodiment of the present disclosure is an adhesive sheet including: a rigid resin film having a thickness of 80 micrometers to 500 micrometers, and a first pressure sensitive adhesive layer being disposed on or above a surface of the rigid resin film, wherein the first pressure sensitive adhesive layer includes elastic resin microspheres having a volume average particle diameter of 110 micrometers or greater and a tacky binder, and the first pressure sensitive adhesive layer has an uneven surface due to the presence of the microspheres.

Claims (30)

1. An adhesive sheet comprising:

a rigid resin film having a thickness of 80 micrometers to 500 micrometers and a yield modulus of 10 MPa to 300 MPa, wherein a product of the yield modulus and the thickness of the rigid resin film is 0.9×10 4 N/m to 5×10 4 N/m, and

a first pressure sensitive adhesive layer being disposed on or above a surface of the rigid resin film, wherein

the first pressure sensitive adhesive layer comprises elastic resin microspheres having a volume average particle diameter of 110 micrometers or greater and a tacky binder, and

the first pressure sensitive adhesive layer has an uneven surface due to the presence of the microspheres.

2. The adhesive sheet according to claim 1 , further comprising:

a transparent resin film having a graphic image printed on a surface of the transparent resin film.

3. The adhesive sheet according to claim 2 , further comprising a second pressure sensitive adhesive layer on another face of the rigid resin film.

4. The adhesive sheet according to claim 3 , wherein the second pressure sensitive adhesive layer contains a white pigment.

5. The adhesive sheet according to claim 1 , wherein the microspheres are tacky.

6. The adhesive sheet according to claim 1 , wherein the microspheres have a compressive elastic modulus at 20° C. of 1 kPa to 100 kPa.

7. The adhesive sheet according to claim 1 , wherein the rigid resin film has a tensile strength at 2% strain of 40 N/25 mm or greater.

8. The adhesive sheet according to claim 1 , wherein the rigid resin film is a polyester film.

9. The adhesive sheet according to claim 1 , wherein the thickness of the rigid resin film is 0.2 times the volume average particle diameter of the microspheres or greater.

10. The adhesive sheet according to claim 1 , wherein the first pressure sensitive adhesive layer has an island structure comprising a cluster of the microspheres.

11. The adhesive sheet according to claim 1 , wherein the first pressure sensitive adhesive layer has a 60 degree gloss of 50 or less on the uneven surface.

12. The adhesive sheet according to claim 1 , wherein the difference between the maximum thickness and the minimum thickness of the first pressure sensitive adhesive layer is 50 micrometers or greater.

13. The adhesive sheet according to claim 1 , wherein the tacky binder is an acrylic pressure sensitive adhesive.

14. The adhesive sheet according to claim 1 , wherein the mass ratio of the tacky binder to the microspheres in the first pressure sensitive adhesive layer is from 40:60 to 90:10.

15. The adhesive sheet according to claim 1 , further comprising a metal layer.

16. The adhesive sheet according to claim 15 , wherein the metal layer is arranged on another face of the rigid resin film or above another face of the rigid resin film than the first pressure sensitive adhesive layer.

17. The adhesive sheet according to claim , wherein the rigid resin film is a transparent resin film having a graphic image printed on a surface of the transparent resin film.

18. A method of applying an adhesive sheet on a rough surface, the method comprising:

providing an adhesive sheet, the adhesive sheet comprising:

a rigid resin film having a thickness of 80 micrometers to 500 micrometers and a yield modulus of 10 MPa to 300 MPa, wherein a product of the yield modulus and the thickness of the rigid resin film is 0.9×10 4 N/m to 5×10 4 N/m, and

a first pressure sensitive adhesive layer being disposed on or above a surface of the rigid resin film, wherein

the first pressure sensitive adhesive layer comprises elastic resin microspheres having a volume average particle diameter of 110 micrometers or greater and a tacky binder, and

the first pressure sensitive adhesive layer has an uneven surface due to the presence of the microspheres; and

applying the adhesive sheet on a rough surface;

the adhesive sheet exhibiting a smooth appearance after being applied on the rough surface.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 9, 2019
From: ABE, HIDETOSHI; IMAMURA, KENGO; ONO, KATSUYA; TAKEDA, YOSHIHIKO; YAMAMOTO, TAKEO
To: 3M INNOVATIVE PROPERTIES COMPANY
Reel/Frame 050670/0571 →
Priority Claims (2)
JP JP2017-077645 · Apr 10, 2017 · national
JP JP2018-026922 · Feb 19, 2018 · national
Continuity (1)
Related Publication 20210009863A1 · Jan 14, 2021