Exhaust gas purification catalyst device
An exhaust gas purification catalyst device includes a honeycomb base material and an inlet-side coat layer, wherein: the honeycomb base material includes a plurality of cells partitioned by porous partition walls, the plurality of cells including inlet-side cells and outlet-side cells and being configured such that exhaust gas that has flowed into the inlet-side cells passes through the partition walls and is exhausted from the outlet-side cells; and the inlet-side coat layer is present on the surface sides of the partition walls of the inlet-side cells, with the proportion of 4-9 μm through-pores in the through-pore diameter distribution of the partition walls being at least 80 vol %, and the peak pore diameter measured using a mercury porosimeter being at least 3.0 μm greater than the peak through-pore diameter measured using a perm porometer.
1. An exhaust gas purification catalyst device having a honeycomb substrate and an inlet side coat layer; wherein
the honeycomb substrate has a plurality of cells partitioned by porous partition walls, and this plurality of cells includes inlet side cells, which are open on the upstream side of exhaust gas flow and sealed on the downstream side, and outlet side cells, which are sealed on the upstream side of exhaust gas flow and open on the downstream side, and are configured such that exhaust gas that has flowed into the inlet side cells as a result thereof passes through the partition walls and is discharged from the outlet side cells,
the inlet side coat layer is present on the surface sides of the partition walls of the inlet side cells
the proportion of through-pores having a diameter of 4 μm or more to 9 μm or less in the distribution of the through-pore diameter of the partition walls as measured according to the bubble point method using a perm-porometer is 80% by volume or more, and
the peak pore diameter as measured according to the mercury intrusion method using a mercury porosimeter is 3.0 μm or more larger than the peak through-pore diameter measured according to the bubble point method using a perm-porometer.
2. The catalyst device according to claim 1 , wherein the inlet side coat layer is present only within a range from the partition wall surfaces of the inlet side cells to a depth of 30% of the partition wall thickness.
3. The catalyst device according to claim 2 , wherein the inlet side coat layer is present only within a range from the partition wall surfaces of the inlet side cells to a depth of 10% of the partition wall thickness.
4. The catalyst device according to claim 1 , wherein the peak pore diameter measured according to the mercury intrusion method using a mercury porosimeter is 9 μm or more.
5. The catalyst device according to claim 1 , wherein the inlet side coat layer is present over a length of 70% or more of the length of the honeycomb substrate from the upstream side end of exhaust gas flow of the honeycomb substrate.
6. The catalyst device according to claim 1 , wherein the inlet side coat layer is present over a length of 98% or more of the length of the honeycomb substrate from the upstream side end of exhaust gas flow of the honeycomb substrate.
7. The catalyst device according to claim 1 , further having an outlet side coat layer present on the surfaces or insides of the partition walls of the outlet side cells.
8. A method for producing the exhaust gas purification catalyst device according to claim 1 , wherein
the production method comprises forming a slurry coat layer by coating a slurry for coat layer formation within the inlet side cells of the honeycomb substrate and baking the honeycomb substrate after forming the slurry coat layer, and
the slurry for coat layer formation contains inorganic oxide particles and a pore forming material.
9. The method according to claim 8 , wherein the pore forming material is an organic polymer particle.
10. The method according to claim 8 , wherein the average particle diameter of the pore forming material is 10 nm or more to 500 nm or less.
11. The method according to claim 8 , wherein the amount of the slurry coat layer per unit volume of the honeycomb substrate after baking is 1 g/L or more to 15 g/L or less.