Method for forming lithium metal and inorganic material composite thin film and method for pre-lithiation of negative electrode for lithium secondary battery by using same
A method for pre-lithiation of a negative electrode and a negative electrode formed by the method, the method including forming a mixture of inorganic material powder and molten lithium, forming a lithium metal-inorganic material composite ribbon, rolling the ribbon into a film and bonding the lithium metal-inorganic material composite film on a surface of a negative electrode to form a lithium metal-inorganic material composite layer on the surface of the negative electrode. This method reduces the deterioration of lithium during application of a mixture slurry and a negative electrode for a secondary battery, manufactured by the method for pre-lithiation, has improved initial irreversibility, and a secondary battery manufactured using such a negative electrode has excellent charging and discharging efficiency.
1. A method for pre-lithiating a negative electrode, the method comprising:
adding an inorganic powder to molten lithium to form a mixture;
extruding the mixture and cooling the mixture to prepare a lithium metal-inorganic composite ribbon having a thickness of 100 μm to 200 μm;
rolling the lithium metal-inorganic composite ribbon to produce a lithium metal-inorganic composite film; and
bonding the lithium metal-inorganic composite film on a surface of the negative electrode to form a lithium metal-inorganic composite layer on the surface of the negative electrode.
2. The method of claim 1 , wherein a thickness of the lithium metal-inorganic composite layer is 1 μm to 50 μm.
3. The method of claim 1 , wherein the inorganic powder comprises at least one selected from the group consisting of alumina (Al 2 O 3 ), titanium dioxide (TiO 2 ), zirconium dioxide (ZrO 2 ), silicon dioxide (SiO 2 ), tin oxide (SnO 2 ), cerium oxide (CeO 2 ), magnesium oxide (MgO), calcium oxide (CaO), and yttria (Y 2 O 3 ).
4. The method of claim 1 , wherein a mixing ratio of the molten lithium and the inorganic powder is 70 to 85% by volume of the molten lithium and 15 to 30% by volume of the inorganic powder.
5. The method of claim 1 , further comprising
mixing a binder with the molten lithium or the mixture of the molten lithium and inorganic powder.
6. The method of claim 1 , wherein the lithium metal-inorganic composite layer does not remain in a metallic form of lithium after an initial activation charge.
7. The method of claim 1 , wherein the inorganic powder has a particle diameter of 0.1 μm to 10 μm.
8. The method of claim 1 , wherein the negative electrode comprises silicon oxide.