Polycarbonate composition comprising pearlescent pigment and/or interference pigment
The invention relates to compositions based on aromatic polycarbonate comprising metal oxide-coated micas as effect pigment, which do not have any significant increase in molecular weight of the polycarbonate, as can be seen from the MVR, under thermal stress. This is achieved by the addition of small amounts of an anhydride-modified α-olefin polymer, optionally in combination with phosphorus-containing thermal stabilizer.
1. A composition comprising
A) 50 wt % to 98.5 wt % of aromatic polycarbonate, having melt volume flow rate (MVR) of from 5 to 20 cm 3 /(10 min) determined according to ISO 1133:2012-03 at a testing temperature of 300° C. with a load of 1.2 kg,
B) 0.8 wt % to ≤3.0 wt % of interference pigment and/or pearlescent pigment comprising a titanium dioxide-coated mica;
C) 0.05 wt % to ≤3 wt % of anhydride-modified α-olefin polymer, wherein the olefinic portion of the anhydride-modified α-olefin polymer has
an ethylene content of 65.0-96.0 wt %,
a propylene content of 2.0-10.0 wt % and
a 1-octene content of 2.0-25.0 wt % and
D) 0.001 wt % to 0.500 wt % of one or more phosphorus-containing thermal stabilizers.
2. The composition according to claim 1 , comprising
A) 90.0 wt % to 97.5 wt % of aromatic polycarbonate,
B) 1.0 to 2.5 wt % of interference pigment and/or pearlescent pigment comprising a titanium dioxide-coated mica,
C) 0.02 wt % to ≤1 wt % of anhydride-modified α-olefin polymer.
3. The composition according to claim 1 , comprising 1.2 to 2.0 wt % of interference pigment and/or pearlescent pigment comprising a titanium dioxide-coated mica.
4. The composition according to claim 1 , wherein component D comprises one or more phosphites as thermal stabilizer.
5. The composition according to claim 1 , wherein component D comprises
i) phosphine, phosphite and phenolic antioxidant or
ii) phosphine, phosphonite and phenolic antioxidant
as phosphorus-containing thermal stabilizers.
6. The composition according to claim 1 , wherein the thermal stabilizer present is bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite.
7. The composition according to claim 1 , wherein the anhydride-modified α-olefin polymer has an average molecular weight M w , determined by means of gel permeation chromatography in ortho-dichlorobenzene at 150° C. with polystyrene calibration, of 1000 to 15 000 g/mol and an acid number of 45 to 170 mg KOH/g, determined according to DIN ISO 17025, by means of potentiometric titration.
8. The composition according to claim 1 , wherein the composition has a melt volume flow rate (MVR) of 8 cm 3 /(10 min) or less, determined according to ISO 1133:2012-03 at a testing temperature of 300° C. with a load of 1.2 kg.
9. A moulding produced from a composition according to claim 1 .
10. The composition according to claim 1 , wherein the composition comprises
A) 90.0 wt % to 97.5 wt % of aromatic polycarbonate,
B) 1.2 wt % to 2.0 wt %, of pearlescent pigment and/or interference pigment from the group of the titanium dioxide-coated micas,
C) 0.2 wt % to ≤1 wt % of anhydride-modified α-olefin polymer, wherein the olefinic portion of the anhydride-modified α-olefin polymer has
an ethylene content of 65.0-96.0 wt %,
a propylene content of 2.0-10.0 wt % and
a 1-octene content of 2.0-25.0 wt %,
D) 0.05 to 0.270 wt % of phosphorus-containing thermal stabilizer comprising
i) phosphine, phosphite and phenolic antioxidant or
ii) phosphine, phosphonite and phenolic antioxidant,
E) up to 7% by weight of further additives selected from the group consisting of flame retardants, anti-dripping agents, thermal stabilizers other than component D), impact modifiers, fillers, antistats, colourants, pigments other than component B, carbon black, lubricants, demoulding agents, hydrolysis stabilizers, compatibilizers, UV absorbers and/or IR absorbers.
11. The composition according to claim 10 , wherein the composition consists of component A), B), C), D) and E).
12. The composition according to claim 10 , wherein further additives optionally present according to component E are solely colourants, demoulding agents, thermal stabilizers other than component D and/or pigments other than component B.
13. A composition comprising:
A) 50 wt% to 98.5 wt% of aromatic polycarbonate, having melt volume flow rate (MVR) of from 5 to 20 cm 3 /(10 min) determined according to ISO 1133:2012-03 as a testing temperature of 300° C. with a load of 1.2 kg,
B) 0.8 wt% to ≤ 3.0 wt% of interference pigment and/or pearlescent pigment comprising a titanium dioxide-coated mica;
C) 0.05 wt% to ≤ 3 wt% of anhydride-modified olefin polymer, wherein the anhydride-modified olefin polymer has been modified with maleic anhydride and is based on polypropylene,
and
0.001 wt to 0.500 wt% of one or mroe phosphorus-containing thermal stabilizers.