Lamination adhesive compositions and their applications
Two part silicone lamination adhesive compositions which cure via a condensation cure chemistry using titanium and/or zirconium based catalysts at room temperature are disclosed. The compositions comprise: (i) at least one condensation curable silyl terminated polymer having at least one hydrolysable and/or hydroxyl functional group(s) per molecule; (ii) a cross-linker; and (iii) a condensation catalyst selected from the group of titanates and zirconates. Polymer (i) is not stored in the same part as cross-linker (ii) and catalyst (iii). Catalyst (iii) is present in a molar amount which is at least 50% of the moisture present cumulatively in the parts of the composition. The molar ratio of silicon bonded hydroxyl groups in polymer (i) to hydrolysable groups in cross-linker (ii) is above 0.15. The molar ratio of the silicon bonded hydroxyl groups in polymer (i) to M-OR functions is greater than 10, where M is titanium or zirconium.
1. A multiple part condensation curable lamination adhesive composition, said composition comprising:
(i) at least one condensation curable silyl terminated polymer having at least one, optionally at least 2, hydrolysable and/or hydroxyl functional group(s) per molecule;
(ii) a cross-linker selected from the group consisting of
silanes having at least 2 hydrolysable groups, optionally at least 3 hydrolysable groups, per molecule group; and/or
silyl functional molecules having at least 2 silyl groups, each silyl group containing at least one hydrolysable group; and
(iii) a condensation catalyst selected from the group consisting of titanates and zirconates;
wherein the polymer (i), the cross-linker (ii), and the catalyst (iii) are not present in the same part;
wherein condensation catalyst (iii) is present in a molar amount which is at least 50% of the moisture present cumulatively in the parts of the composition;
wherein the molar ratio of silicon bonded hydroxyl groups in polymer (i) to hydrolysable groups in cross-linker (ii) is above 0.15; and
wherein the molar ratio of the silicon bonded hydroxyl groups in polymer (i) to titanium or zirconium in condensation catalyst (iii) is greater than 10.
2. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , consisting of components (i), (ii) and (iii) and one or more additives selected from the group consisting of pigments, dyes, adhesion promoters, light diffusing particles, siloxane resins and/or particles with fire resistant properties.
3. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , further comprising pigments and/or dyes.
4. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , further comprising light diffusing particles.
5. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , further comprising particles with fire resistance properties.
6. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , which does not contain any inorganic filler.
7. The multiple part condensation curable lamination adhesive composition in accordance with claim 1 , stored in two parts wherein said parts are divided as follows:
a) polymer(i) and cross-linker (ii) in one part and polymer (i) and catalyst (iii) in the other part; or
b) cross-linker (ii) in one part and polymer (i) and catalyst (iii) in the other part.
8. A method of making a laminated assembly comprising a lamination adhesive between a substrate and a superstrate, said method comprising:
mixing the multiple part condensation curable lamination adhesive composition in accordance with claim 1 to form a mixed composition;
applying the mixed composition onto a face of a substrate and/or superstrate;
sandwiching the mixed composition between the substrate and superstrate; and
laminating the same.
9. The method in accordance with claim 8 , wherein a dam of polyisobutylene (PIB) rubber seal, silicone hot melt material or optically clear silicone sealant is applied to a peripheral edge of the face of the substrate and/or superstrate to which the mixed composition is to be applied to form a dam to prevent loss of the mixed composition prior to lamination.
10. The method in accordance with claim 9 , wherein the dam is applied around the peripheral edge when the viscosity of the mixed composition is ≤30,000 mPa.s at 25° C.
11. A laminated assembly comprising a cured lamination adhesive formed via the multiple part condensation curable lamination adhesive composition in accordance with claim 1 , wherein the cured lamination adhesive is sandwiched between a substrate and a superstrate.
12. The laminated assembly in accordance with claim 11 , wherein the substrate and/or superstrate are selected from glass, wood, concrete, stone, plastics, composites, metals or ceramics.
13. The assembly in accordance with claim 11 , wherein the cured lamination adhesive is encapsulating one or more objects within the laminated assembly.
14. The assembly in accordance with claim 13 , wherein the one or more objects is/are selected from electrical and/or solar power related components or decorative elements.
15. The assembly in accordance with claim 11 , wherein the substrate and/or superstrate are both glass panels.
16. The assembly in accordance with claim 11 , wherein a polyisobutylene (PIB) rubber seal, silicone hot melt material or optically clear silicone sealant is provided in the assembly in a peripheral gap between the substrate and superstrate adjacent to an outer edge of the cured lamination adhesive.
17. The assembly in accordance with claim 11 , wherein a vapour barrier material is applied around and edge of the assembly.
18. The assembly in accordance with claim 11 , wherein the assembly is cold bended to create a curved glass product.