IP Library Granted Patent US 11,680,221
Granted Patent B2
US 11,680,221 · App. 16/614,427 · Granted Jun 20, 2023

Lubricating oil composition for internal combustion engine

Inventors: Hiromitsu Matsuda (Toyko, JP); Koji Hoshino (Tokyo, JP)
Assignee: ENEOS CORPORATION
C10M141/12C10M101/02C10M129/54C10M135/10C10M139/00C10M145/14C10M169/044C10M2207/262C10M2209/084C10M2227/09C10M2290/02C10M2290/04C10N2020/04C10N2030/02C10N2030/04C10N2030/08C10N2030/74C10N2040/25
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Quick Facts
Patent No.
US 11,680,221
App. No.
16/614,427
Granted
Jun 20, 2023
Kind
B2
Abstract

A lubricating oil composition for an internal combustion engine, the composition including: a lubricating base oil comprising at least one mineral base oil or at least one synthetic base oil or any combination thereof, the lubricating base oil having a kinematic viscosity at 100° C. of 4.0 to 4.5 mm 2 /s and a NOACK evaporation loss at 250° C. of no more than 15 mass %; (A) a calcium-containing metallic detergent in an amount of no less than 1000 mass ppm and less than 2000 mass ppm in terms of calcium on the basis of the total mass of the composition; and optionally (C) a viscosity index improver in an amount of less than 1 mass % on the basis of the total mass of the composition.

Claims (37)

1. A lubricating oil composition for an internal combustion engine, the composition consisting of:

a lubricating base oil consisting of

at least one mineral base oil or at least one synthetic base oil or any combination thereof, the lubricating base oil having a kinematic viscosity at 100° C. of 4.0 to 4.5 mm 2 /s and a NOACK evaporation loss at 250° C. of no more than 15 mass %, and

at least one additive other than any base oil component, the at least one additive comprising:

(A) a calcium borate-containing metallic detergent in an amount of no less than 1000 mass ppm and less than 2000 mass ppm in terms of calcium on the basis of the total mass of the composition;

optionally (B) a magnesium-containing metallic detergent; and

optionally (C) a viscosity index improver in an amount of less than 1.0 mass % on the basis of the total mass of the composition;

wherein

the composition has a HTHS viscosity at 150° C. of 1.7 to 2.0 mPa·s;

each of the at least one mineral base oil is a Group II or III base oil of API base stock categories obtained by a process comprising:

(i) refining at least one raw material oil selected from the following (1) to (8) or at least one lubricating oil fraction recovered therefrom or any combination thereof, and

(ii) recovering a lubricating oil fraction from a product of the (i), wherein the refining in the (i) comprises solvent deasphalting, solvent refining, hydrocracking, hydroisomerizing, hydrorefining, hydrofinishing, dewaxing, white clay treatment, or chemical washing, or any combination thereof:

(1) a distillate obtained by atmospheric distillation of a paraffin base crude oil and/or a mixed base crude oil;

(2) a distillate obtained by vacuum distillation of residue of atmospheric distillation of a paraffin base crude oil and/or a mixed base crude oil;

(3) a wax obtained through a lubricating oil dewaxing process;

(4) a mixed oil of at least one selected from the (1) to (3), and/or a mild hydrocracked oil of the mixed oil;

(5) a mixed oil of at least two selected from the (1) to (4);

(6) a deasphalted oil of the (1), (2), (3), (4), or (5);

(7) a mild hydrocracked oil of the (6); and

(8) a mixed oil of at least two selected from the (1) to (7); and

each of the at least one synthetic base oil is a poly α-olefin or a hydrogenated product thereof, an isobutene oligomer or a hydrogenated product thereof, an alkylbenzene, an alkylnaphthalene, a diester, a polyol ester, a polyoxyalkylene glycol, a dialkyl diphenyl ether, a polyphenyl ether, or any mixture thereof.

2. The lubricating oil composition according to claim 1 ,

the at least one additive comprising the component (B).

3. The lubricating oil composition according to claim 1 ,

the component (C) comprising: (C1) a poly(meth)acrylate viscosity index improver in an amount of no less than 95 mass % on the basis of the total mass of the component (C), the component (C1) having a weight average molecular weight of no less than 100,000.

4. The lubricating oil composition according to claim 1 ,

wherein the at least one additive does not comprise the component (C).

5. The lubricating oil composition according to claim 1 ,

the at least one additive further comprising (D) a friction modifier,

the component (D) comprising a molybdenum friction modifier.

6. The lubricating oil composition according to claim 1 ,

wherein the lubricating base oil consists of at least one Group IV base oil of API base stock categories.

7. The lubricating oil composition according to claim 1 ,

wherein the composition has a HTHS viscosity at 100° C. of 3.5 to 4.4 mPa·s.

8. The lubricating oil composition according to claim 1 ,

wherein the composition has a NOACK evaporation loss at 250° C. of no more than 15 mass %.

9. The lubricating oil composition according to claim 1 , wherein the at least one synthetic base oil is a poly α-olefin or a hydrogenated product thereof, an isobutene oligomer or a hydrogenated product thereof, a diester, a polyol ester, or any mixture thereof.

Assignments (2)
CHANGE OF NAME Recorded Aug 22, 2022
From: JXTG NIPPON OIL & ENERGY CORPORATION
To: ENEOS CORPORATION
Reel/Frame 061298/0080 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 18, 2019
From: MATSUDA, HIROMITSU; HOSHINO, KOJI
To: JXTG NIPPON OIL & ENERGY CORPORATION
Reel/Frame 051036/0659 →
Priority Claims (1)
JP JP2017-100076 · May 19, 2017 · national
Continuity (1)
Related Publication 20200181524A1 · Jun 11, 2020