Metallo-graphene nanocomposites and methods for using metallo-graphene nanocomposites for electromagnetic energy conversion
Nanocomposites in accordance with many embodiments of the invention can be capable of converting electromagnetic radiation to an electric signal, such as signals in the form of current or voltage. In some embodiments, metallic nanostructures are integrated with graphene material to form a metallo-graphene nanocomposite. Graphene is a material that has been explored for broadband and ultrafast photodetection applications because of its distinct optical and electronic characteristics. However, the low optical absorption and the short carrier lifetime of graphene can limit its use in many applications. Nanocomposites in accordance with various embodiments of the invention integrates metallic nanostructures, such as (but not limited to) plasmonic nanoantennas and metallic nanoparticles, with a graphene-based material to form metallo-graphene nanostructures that can offer high responsivity, ultrafast temporal responses, and broadband operation in a variety of optoelectronic applications.
1. A nanocomposite for converting electromagnetic radiation to an electric signal, the nanocomposite comprising:
a photo-absorbing layer of graphene; and
a plurality of electrically-connected metallic nanostructures in contact with the photo-absorbing layer, wherein the plurality of metallic nanostructures act as contact electrodes for the nanocomposite, wherein the plurality of metallic nanostructures have a metal-to-metal spacing at the sub-micrometer level and wherein the metallic nanostructures provide a strong concentration of photo-generated carriers near the contact electrodes,
wherein the nanocomposite is characterizable in that the nanocomposite is capable of operating with responsivity levels of at least 0.6 A/W for all wavelengths ranging from 800 nanometers to 20 micrometers.
2. The nanocomposite of claim 1 , wherein the photo-absorbing layer is a multi-layered graphene layer.
3. The nanocomposite of claim 1 , wherein the photo-absorbing layer comprises graphene nanoribbons.
4. The nanocomposite of claim 1 , wherein the photo-absorbing layer is doped in order to alter the Fermi energy level of the photo-absorbing layer.
5. The nanocomposite of claim 4 , wherein the photo-absorbing layer is doped in order to increase optical absorption of infrared wavelengths of the photo-absorbing layer.
6. The nanocomposite of claim 4 , wherein:
the doping level of the photo-absorbing layer between the metallic nanostructures is different than at junctions of the metallic nanostructures.
7. The nanocomposite of claim 5 , wherein the photo-absorbing layer is initially doped.
8. The nanocomposite of claim 5 , wherein:
the photo-absorbing layer is in contact with a dielectric; and
the photo-absorbing layer is doped using a gate voltage.
9. The nanocomposite of claim 1 , further comprising a semiconductor, wherein the photo-absorbing layer is in contact with the semiconductor, wherein the nanocomposite is configured to operate as a photodetector capable of detecting a wavelength range from ultraviolet wavelengths to microwave wavelengths.
10. The nanocomposite of claim 9 , wherein the semiconductor comprises a silicon wafer having a silicon oxide layer.
11. The nanocomposite of claim 1 , wherein the nanocomposite is capable of operating without a bias voltage.
12. The nanocomposite of claim 1 , further comprising a dielectric with a backside semiconductor or conductor for gating the photo-absorbing layer and adjusting the Fermi energy level of the photo-absorbing layer.
13. The nanocomposite of claim 1 , wherein the plurality of metallic nanostructures are placed in an asymmetric pattern.
14. The nanocomposite of claim 1 , wherein the plurality of metallic nanostructures comprise a grating pattern.
15. The nanocomposite of claim 1 , wherein the nanocomposite is capable of converting thermal energy into an electric signal.
16. The nanocomposite of claim 15 , wherein the photo-absorbing layer is configured to generate carriers in response to receiving thermal energy.
17. The nanocomposite of claim 1 , wherein the nanocomposite is characterizable in that the nanocomposite is capable of operating at over 50 GHz.
18. The nanocomposite of claim 1 , wherein the nanocomposite is characterizable in that the nanocomposite is capable of operating with a responsivity of at least 0.1 A/W.
19. A nanocomposite for converting electromagnetic radiation to an electric signal, the nanocomposite comprising:
a photo-absorbing layer of graphene; and
a plurality of electrically-connected metallic nanostructures in contact with the photo-absorbing layer, wherein the plurality of metallic nanostructures act as contact electrodes for the nanocomposite, wherein the plurality of metallic nanostructures haw a metal-to-metal spacing at the sub-micrometer level and wherein the metallic nanostructures provide a strong concentration of photo-generated carriers near the contact electrodes,
wherein the nanocomposite is characterizable in that the nanocomposite is capable of operating with a responsivity of at least 0.6 A/W at all frequencies ranging from 1 kHz to 50 GHz.
20. The nanocomposite of claim 1 , wherein the photo-absorbing layer of material further comprises transition metal dichalcogenides.