IP Library › Granted Patent US 11,085,101
Granted Patent B2
US 11,085,101 · App. 16/618,887 · Granted Aug 10, 2021

Hot-pressed member and method for manufacturing same, and cold-rolled steel sheet for hot pressing and method for manufacturing same

Inventors: Katsutoshi Takashima (Tokyo, JP); Takashi Kobayashi (Tokyo, JP); Yoshimasa Funakawa (Tokyo, JP); Seiji Nakajima (Tokyo, JP)
Assignee: JFE STEEL CORPORATION
C21D9/46B21D22/022B32B15/012B32B15/013C21D1/18C21D6/001C21D6/002C21D6/005C21D6/008C21D8/0205C21D8/0226C21D8/0236C21D8/0263C22C38/001C22C38/002C22C38/005C22C38/008C22C38/02C22C38/04C22C38/06C22C38/08C22C38/16C22C38/26C22C38/28C22C38/32C23C2/06C23C2/12C23C2/40C21D2211/004C21D2211/008Y10T428/12799Y10T428/12958
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,085,101
App. No.
16/618,887
Granted
Aug 10, 2021
Kind
B2
Abstract

Disclosed is a hot-pressed member that can exhibit very high tensile strength after hot pressing as high as TS: 1780 MPa or more and excellent delayed fracture resistance after projection welding by properly adjusting its chemical composition and its microstructure such that at least 5 Ti-based precipitates having a grain size of 0.10 μm or less are present on average per 100 μm 2 of a cross section parallel to a thickness direction of the member within a range of 100 μm in a thickness direction from a surface of the member, a volume fraction of martensite is 95% to 100% within a depth range of 20 μm to 100 μm in the thickness direction from the surface of the member, and at least 10 cementite grains having a grain size of less than 0.20 μm are present on average in a prior austenite grain.

Claims (41)

1. A cold-rolled steel sheet for hot pressing, comprising:

a chemical composition containing, by mass %, C: 0.28% or more and less than 0.42%, Si: 1.5% or less, Mn: 1.0% or more and 2.2% or less, P: 0.05% or less, S: 0.005% or less, Al: 0.01% or more and 0.50% or less, N: 0.005% or less, and Ti: 0.005% or more and 0.15% or less, with the balance being Fe and inevitable impurities,

a microstructure in which at least 10 Ti-based precipitates having a grain size of 0.005 μm or more and 0.10 μm or less are present on average per 100 μm 2 of a cross section parallel to a thickness direction of the steel sheet within a range of 100 μm in the thickness direction from a surface of the steel sheet; and

a standard deviation of Vickers hardness of 40 or less, the Vickers hardness being measured every 200 μm in the thickness direction within a range from a depth position of 100 μm from the surface of the steel sheet to a mid-thickness part.

2. The cold-rolled steel sheet for hot pressing according to claim 1 , wherein the chemical composition further contains, by mass %, at least one selected from Nb: 0.15% or less, B: 0.0050% or less, Mo: 0.50% or less, Cr: 0.50% or less, Sb: 0.001% or more and 0.020% or less, Ca: 0.005% or less, Mg: 0.005% or less, REM: 0.005% or less, V: 0.15% or less, Cu: 0.50% or less, Ni: 0.50% or less, Sn: 0.50% or less, Zn: 0.10% or less, Co: 0.10% or less, Zr: 0.10% or less, Ta: 0.10% or less, and W: 0.10% or less.

3. The cold-rolled steel sheet for hot pressing according to claim 1 , wherein the steel sheet comprises on a surface thereof an Al or Al alloy coating or plating layer or a Zn or Zn alloy coating or plating layer.

4. The cold-rolled steel sheet for hot pressing according to claim 2 , wherein the steel sheet comprises on a surface thereof an Al or Al alloy coating or plating layer or a Zn or Zn alloy coating or plating layer.

5. A hot-pressed member comprising:

a steel chemical composition containing, by mass %, C: 0.28% or more and less than 0.42%, Si: 1.5% or less, Mn: 1.0% or more and 2.2% or less, P: 0.05% or less, S: 0.005% or less, Al: 0.01% or more and 0.50% or less, N: 0.005% or less, and Ti: 0.005% or more and 0.15% or less, with the balance being Fe and inevitable impurities;

a microstructure in which

at least 5 Ti-based precipitates having a grain size of 0.005 μm or more and 0.10 μm or less are present on average per 100 μm 2 of a cross section parallel to a thickness direction of the member within a range of 100 μm in a thickness direction from a surface of the member, a volume fraction of martensite is 95% to 100% within a depth range of 20 μm to 100 μm in the thickness direction from the surface of the member, and at least 10 cementite grains having a grain size of less than 0.20 μm are present on average in a prior austenite grain; and

a tensile strength of 1780 MPa or more.

6. The hot-pressed member according to claim 5 , wherein the steel chemical composition further contains, by mass %, at least one selected from the group consisting of Nb: 0.15% or less, B: 0.0050% or less, Mo: 0.50% or less, Cr: 0.50% or less, Sb: 0.001% or more and 0.020% or less, Ca: 0.005% or less, Mg: 0.005% or less, REM: 0.005% or less, V: 0.15% or less, Cu: 0.50% or less, Ni: 0.50% or less, Sn: 0.50% or less, Zn: 0.10% or less, Co: 0.10% or less, Zr: 0.10% or less, Ta: 0.10% or less, and W: 0.10% or less.

7. The hot-pressed member according to claim 5 , comprising, on a surface layer thereof, an Al or Al alloy coating or plating layer or a Zn or Zn alloy coating or plating layer.

8. The hot-pressed member according to claim 6 comprising, on a surface layer thereof, an Al or Al alloy coating or plating layer or a Zn or Zn alloy coating or plating layer.

9. A method for manufacturing the cold-rolled steel sheet for hot pressing as recited in claim 1 , the method comprising:

preparing a steel raw material comprising a chemical composition containing, by mass %, C: 0.28% or more and less than 0.42%, Si: 1.5% or less, Mn: 1.0% or more and 2.2% or less, P: 0.05% or less, S: 0.005% or less, Al: 0.01% or more and 0.50% or less, N: 0.005% or less, and Ti: 0.005% or more and 0.15% or less, with the balance being Fe and inevitable impurities;

hot rolling the steel raw material to obtain a hot-rolled steel sheet under a set of conditions including a rolling reduction of 12% or more at a final pass of finish rolling, a rolling reduction of 15% or more at a pass immediately before the final pass, and a finisher delivery temperature of 860° C. to 950° C.;

after the hot rolling, subjecting the hot-rolled steel sheet to primary cooling whereby the hot-rolled steel sheet is cooled to a cooling end temperature of 700° C. or lower at a first average cooling rate of 70° C./s or higher up to the cooling end temperature;

after the primary cooling, subjecting the steel sheet to secondary cooling whereby the steel sheet is coiled at a coiling temperature of 520° C. or lower at a second average cooling rate of 5° C./s to 50° C./s up to the coiling temperature;

then pickling the coiled hot-rolled steel sheet, and then subjecting the steel sheet to a first heat treatment whereby the steel sheet is heated in a temperature range of 830° C. to 930° C. for 600 seconds or shorter;

then cold rolling the steel sheet to obtain a cold-rolled steel sheet, then subjecting the cold-rolled steel sheet to a second heat treatment whereby the cold-rolled steel sheet is heated to a temperature range of 720° C. to 850° C. at an average heating rate of 5° C./s to 20° C./s and subjected to 15 seconds to 600 seconds of soaking in the temperature range of 720° C. to 850° C.; and

after the second heat treatment, subjecting the cold-rolled steel sheet to a tertiary cooling whereby the cold-rolled steel sheet is cooled to a cooling end temperature of 600° C. or lower at a third average cooling rate of 5° C./s or higher.

10. The method for manufacturing the cold-rolled steel sheet for hot pressing according to claim 9 , wherein

the chemical composition further contains, by mass %, at least one selected from the group consisting of Nb: 0.15% or less, B: 0.0050% or less, Mo: 0.50% or less, Cr: 0.50% or less, Sb: 0.001% or more and 0.020% or less, Ca: 0.005% or less, Mg: 0.005% or less, REM: 0.005% or less, V: 0.15% or less, Cu: 0.50% or less, Ni: 0.50% or less, Sn: 0.50% or less, Zn: 0.10% or less, Co: 0.10% or less, Zr: 0.10% or less, Ta: 0.10% or less, and W: 0.10% or less.

11. The method for manufacturing the cold-rolled steel sheet for hot pressing according to claim 9 , the method further comprising:

after the tertiary cooling, applying an Al or Al alloy coating or plating treatment or a Zn or Zn alloy coating or plating treatment to a surface of the cold-rolled steel sheet.

12. A method for manufacturing a hot-pressed member, comprising:

heating the cold-rolled steel sheet for hot pressing as recited in claim 1 in a temperature range of an Ac 3 transformation temperature to 1000° C.; and

then hot pressing the steel sheet.

13. The method for manufacturing the cold-rolled steel sheet for hot pressing according to claim 10 , the method further comprising:

after the tertiary cooling, applying an Al or Al alloy coating or plating treatment or a Zn or Zn alloy coating or plating treatment to a surface of the cold-rolled steel sheet.

14. A method for manufacturing a hot-pressed member, comprising:

heating the cold-rolled steel sheet for hot pressing as recited in claim 2 in a temperature range of an Ac 3 transformation temperature to 1000° C.; and

then hot pressing the steel sheet.

15. A method for manufacturing a hot-pressed member, comprising:

heating the cold-rolled steel sheet for hot pressing as recited in claim 3 in a temperature range of an Ac 3 transformation temperature to 1000° C.; and

then hot pressing the steel sheet.

16. A method for manufacturing a hot-pressed member, comprising:

heating the cold-rolled steel sheet for hot pressing as recited in claim 4 in a temperature range of an Ac 3 transformation temperature to 1000° C.; and

then hot pressing the steel sheet.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 3, 2019
From: TAKASHIMA, KATSUTOSHI; KOBAYASHI, TAKASHI; FUNAKAWA, YOSHIMASA; NAKAJIMA, SEIJI
To: JFE STEEL CORPORATION
Reel/Frame 051161/0001 →
Priority Claims (1)
WO PCT/JP2017/024261 · Jun 30, 2017 · international
Continuity (1)
Related Publication 20200131596A1 · Apr 30, 2020