Optical member resin sheet, optical member, layered body, or light-emitting device comprising optical member resin sheet, and method for manufacturing optical member resin sheet

1. An optical member resin sheet wherein the difference between the sheet edge thickness and sheet center thickness relative to total sheet thickness, in relation to the sheet width direction, is no greater than 5.0%, the thickness of the sheet center ranges from 10 to 1,000 μm and the sheet area is at least 225 mm 2 , and which is characterized in that the sheet contains at least one fluorescent substance or reflective material, wherein the optical member resin sheet comprises:

(A) one or more fluorescent substances selected from oxide phosphors, oxynitride phosphors, nitride phosphors, sulphide phosphors, fluoride phosphors, and oxysulphide phosphors;

(B) a resin-linear organopolysiloxane block copolymer having within its molecular structure an alkenyl group, siloxane units represented by the formula R A SiO 3/2 , whereas R A is an aryl group having 6 to 14 carbon atoms and a polydiorganosiloxane structure represented by the formula (R 2 SiO 2/2 ) n , whereas R is an aryl group having 6 to 14 carbon atoms or an alkyl group having 1 to 20 carbon atoms, which may be halogen-substituted, and n is a number ranging from 3 to 1,000;

an organohydrogenpolysiloxane having the formula (HR B 2 SiO 1/2 ) 0.60 (PhSiO 3/2 ) 0.4 , where each R B is methyl, and at least two silicon-bonded hydrogen atoms, wherein the resin-linear organopolysiloxane block copolymer is non-flowable at 25° C.; and

a hydrosilyilation reaction catalyst.

2. An optical member resin sheet as claimed in claim 1 , wherein the width and length of the are each 15 mm or greater and the sheet area is 400 mm 2 or greater.

3. An optical member resin sheet as claimed in claim 1 , wherein the thickness of the center of the sheet ranges from 30 to 900 μm, and the difference between the sheet edge thickness and sheet center thickness relative to total sheet thickness, in relation to the sheet width direction, is no greater than 2.5%.

4. An optical member resin sheet as claimed in claim 1 , wherein the fluorescent substance or reflective material is included in an amount ranging from 10 to 90% by mass, relative to the total weight of the sheet.

5. An optical member resin sheet as claimed in claim 1 , wherein the fluorescent substance or reflective material is dispersed in a binder resin containing at least a silicone resin.

6. An optical member resin sheet as claimed in claim 1 , which is characterized in that the sheet is heat-meltable.

7. An optical member resin sheet as claimed in claim 1 , wherein Component (A) is included in an amount ranging from 10 to 90% by mass, relative to the total weight of the sheet.

8. An optical member resin sheet as claimed in claim 1 , wherein Component (B) is a binder resin of a solid particle component which includes at least Component (A), and is furthermore an organopolysiloxane represented by the formula {(R 2 SiO 2/2 )} a {R A SiO 3/2 } 1-a (wherein R and R A are the same groups as described above and a is a number ranging from 0.8 to 0.2).

9. An optical member resin sheet as claimed in claim 1 , wherein at least part of the fluorescent substance or reflective material is surface-treated with an organosilicon compound.

10. An optical member resin sheet as claimed in claim 1 , wherein the sheet contains the reflective material and wherein the reflective material is one or more selected from titanium oxide, barium oxide, chromium oxide, iron oxide, boron nitride and titanium nitride.

11. An optical member resin sheet as claimed in claim 1 , which further contains (C) silica particles.

12. An optical member equipped with the optical member resin sheet as claimed in claim 1 .

13. A layered body equipped with the optical member resin sheet as claimed in claim 1 .

14. A layered body as claimed in claim 13 , further comprising a release layer.

15. A light-emitting device having a structure sealed with the optical member resin sheet as claimed in claim 1 .

16. A method for the production of an optical member resin sheet having the difference between the sheet edge thickness and sheet centre thickness relative to total sheet thickness, in relation to the sheet width direction, of no greater than 5.0% and having the thickness of the sheet centre in the range of from 10 to 1,000 μm and the sheet area of at least 225 mm 2 which is characterized in that an optical member resin sheet starting material is applied to a substrate using an applicator or slit coater as a sheet coating machine at a viscosity at 25° ° C. of 10 to 10,000 mPa·s and a wet film thickness of 10 to 1,000 μm, wherein the optical member resin sheet starting material includes a resin-linear organopolysiloxane block copolymer having within its molecular structure an alkenyl group, siloxane units represented by the formula R A SiO 3/2 , whereas R A is an aryl group having 6 to 14 carbon atoms and a polydiorganosiloxane structure represented by the formula (R 2 SiO 2/2 ) n , whereas R is an aryl group having 6 to 14 carbon atoms or an alkyl group having 1 to 20 carbon atoms, which may be halogen-substituted, and n is a number ranging from 3 to 1,000; an organohydrogenpolysiloxane having the formula (HR B 2 SiO 1/2 ) 0.60 (PhSiO 3/2 ) 0.4 , where each R B is methyl, and at least two silicon-bonded hydrogen atoms, wherein the resin-linear organopolysiloxane block copolymer is non-flowable at 25° C.

17. A method for the production of an optical member resin sheet claimed in claim 16 , which is characterized in that production is carried out with the hydraulic pressure build up time set to 1.0/w sec or less, with a coating speed of w (cm/sec), using a slit coater as the sheet coating machine.

18. An optical member resin sheet as claimed in claim 2 , wherein the thickness of the center of the sheet ranges from 30 to 900 μm, and the difference between the sheet edge thickness and sheet center thickness relative to total sheet thickness, in relation to the sheet width direction, is no greater than 2.5%.

19. An optical member resin sheet wherein the difference between the sheet edge thickness and sheet center thickness relative to total sheet thickness, in relation to the sheet width direction, is no greater than 5.0%, the thickness of the sheet center ranges from 10 to 1,000 μm and the sheet area is at least 225 mm 2 , and which is characterized in that it contains at least one type of fluorescent substance or reflective material, wherein the optical member resin sheet comprises:

(A) one or more fluorescent substances selected from oxide phosphors, oxynitride phosphors, nitride phosphors, sulphide phosphors, fluoride phosphors, and oxysulphide phosphors;

(B) a resin-linear organopolysiloxane block copolymer having within its molecular structure an alkenyl group, siloxane units represented by the formula R A SiO 3/2 , whereas R A is an aryl group having 6 to 14 carbon atoms and a polydiorganosiloxane structure represented by the formula (R 2 SiO 2/2 ) n , whereas R is an aryl group having 6 to 14 carbon atoms or an alkyl group having 1 to 20 carbon atoms, which may be halogen-substituted, and n is a number ranging from 3 to 1,000;

an organohydrogenpolysiloxane having the formula (HR B 2 SiO 1/2 ) x (R A SiO 3/2 ) y , where each R B is methyl and R A is an aryl group having 6 to 14 carbon atoms, x=0.6, y=0.4, and at least two silicone-bonded hydrogen atoms, wherein the resin-linear organopolysiloxane block copolymer is non-flowable at 25° C.; and

a hydrosilylation reaction catalyst.